S (thio; ⭀S)

mer,cis–[Ta(Cl)₃(S)(NCMe)₂]

Formula Unicode styled: 
mer,cis–[Ta(Cl)₃(S)(NCMe)₂]
Compound name(s): 
bis(acetonitrile)-trichloro-sulfanylidene-tantalum
Central atom: 
Tantalum
Attached groups: 
Cl (chloro)
S (thio; ⭀S)
NCMe (acetonitrile)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Ta«V5C6OVE16B8Z0X5L3»
[MLXZ]𝘲 class: 
[MX5L3]
MLXZ class (ENC, equivalent neutral class): 
MX5L3

mer,cis–[Nb(Cl)₃(S){S(Me)CH₂CH₂SMe}]

Formula Unicode styled: 
mer,cis–[Nb(Cl)₃(S){S(Me)CH₂CH₂SMe}]
Compound name(s): 
(1,2-bis(methylsulfanyl)ethane)-trichloro-sulfanylidene-niobium
Central atom: 
Niobium
Attached groups: 
Cl (chloro)
S (thio; ⭀S)
S(Me)CH₂CH₂SMe (2,5-dithiahexane-κ²S)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Nb«V5C6OVE16B8Z0X5L3»
[MLXZ]𝘲 class: 
[MX5L3]
MLXZ class (ENC, equivalent neutral class): 
MX5L3

mer,cis–[Nb(Br)₃(S)(Tht)₂]

Formula Unicode styled: 
mer,cis–[Nb(Br)₃(S)(Tht)₂]
Compound name(s): 
Tribromo-sulfido-bis(tetrahydrothiophene-S)-niobium
Central atom: 
Niobium
Attached groups: 
Br (bromo)
S (thio; ⭀S)
Tht (tetrahydrothiophene)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Nb«V5C6OVE16B8Z0X5L3»
[MLXZ]𝘲 class: 
[MX5L3]
MLXZ class (ENC, equivalent neutral class): 
MX5L3

[Ti(Cl)₄(S)]²⊖

Formula Unicode styled: 
[Ti(Cl)₄(S)]²⊖
Compound name(s): 
tetrachloro-thio-titanium(2-)
Central atom: 
Titanium
Attached groups: 
Cl (chloro)
S (thio; ⭀S)
Charge on central atom: 
-2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Ti«V4C5OIVE14B7Z0X6L1»2⊖
[MLXZ]𝘲 class: 
[MX6L1]2-
MLXZ class (ENC, equivalent neutral class): 
MX4L3

[V(SPh)(S)₂(S₂)]²⊖

Formula Unicode styled: 
[V(SPh)(S)₂(S₂)]²⊖
Compound name(s): 
phenylthiolato-(persulfido-S,S')-disulfido-vanadium(2-)
Central atom: 
Vanadium
Attached groups: 
SPh (phenylthio)
S (thio; ⭀S)
S₂ (disulfanediyl-κ²S)
Charge on central atom: 
-2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
V«V5C5OVE18B9Z0X7L2»2⊖
[MLXZ]𝘲 class: 
[MX7L2]2-
MLXZ class (ENC, equivalent neutral class): 
MX5L4

[V(SCH₂CH₂S)₂(S)]²⊖

Formula Unicode styled: 
[V(SCH₂CH₂S)₂(S)]²⊖
Compound name(s): 
bis(ethane-1,2-dithiolato)-thio-vanadium(2-)
Central atom: 
Vanadium
Attached groups: 
SCH₂CH₂S (ethanedithiolato-κ²S)
S (thio; ⭀S)
Charge on central atom: 
-2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 15
Summary of calculated classifications: 
V«V4C5OIVE15B7Z0X6L1»2⊖
[MLXZ]𝘲 class: 
[MX6L1]2-
MLXZ class (ENC, equivalent neutral class): 
MX4L3

[Ta(S)(Dedtc)₃]

Formula Unicode styled: 
[Ta(S)(Dedtc)₃]
Compound name(s): 
Sulfido-tris(N,N-diethyldithiocarbamato)-tantalum
Central atom: 
Tantalum
Attached groups: 
S (thio; ⭀S)
Dedtc (diethyldithiocarbamato-κ²S)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Ta«V5C7OVE18B9Z0X5L4»
[MLXZ]𝘲 class: 
[MX5L4]
MLXZ class (ENC, equivalent neutral class): 
MX5L4

[W(Cl)₄(S)]

Formula Unicode styled: 
[W(Cl)₄(S)]
Compound name(s): 
Tetrachloro-sulfido-tungsten
Central atom: 
Tungsten
Attached groups: 
Cl (chloro)
S (thio; ⭀S)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
W«V6C5OVIE14B7Z0X6L1»
[MLXZ]𝘲 class: 
[MX6L1]
MLXZ class (ENC, equivalent neutral class): 
MX6L1

[W(F)₄(NCMe)(S)]

Formula Unicode styled: 
[W(F)₄(NCMe)(S)]
Compound name(s): 
Acetonitrile-tetrafluoro-thio-tungsten
Central atom: 
Tungsten
Attached groups: 
F (fluoro)
NCMe (acetonitrile)
S (thio; ⭀S)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
W«V6C6OVIE16B8Z0X6L2»
[MLXZ]𝘲 class: 
[MX6L2]
MLXZ class (ENC, equivalent neutral class): 
MX6L2

[W(OBuᵗ)₄(S)]

Formula Unicode styled: 
[W(OBuᵗ)₄(S)]
Compound name(s): 
tetrakis(t-Butoxy)-sulfoxo-tungsten
Central atom: 
Tungsten
Attached groups: 
OBuᵗ (t-butyloxy)
S (thio; ⭀S)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
W«V6C5OVIE14B7Z0X6L1»
[MLXZ]𝘲 class: 
[MX6L1]
MLXZ class (ENC, equivalent neutral class): 
MX6L1

[W(Cl)₅(S)]⊖

Formula Unicode styled: 
[W(Cl)₅(S)]⊖
Compound name(s): 
pentachlorosulfido-tungsten(1-)
Central atom: 
Tungsten
Attached groups: 
Cl (chloro)
S (thio; ⭀S)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
W«V6C6OVIE16B8Z0X7L1»⊖
[MLXZ]𝘲 class: 
[MX7L1]-
MLXZ class (ENC, equivalent neutral class): 
MX6L2

[Re(SCH₂CH₂S)₂(S)]⊖

Formula Unicode styled: 
[Re(SCH₂CH₂S)₂(S)]⊖
Compound name(s): 
bis(1,2-ethanedithiolato-S,S')-sulfido-rhenium
Central atom: 
Rhenium
Attached groups: 
SCH₂CH₂S (ethanedithiolato-κ²S)
S (thio; ⭀S)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Re«V5C5OVE16B7Z0X6L1»⊖
[MLXZ]𝘲 class: 
[MX6L1]-
MLXZ class (ENC, equivalent neutral class): 
MX5L2

[Re(SCH₂CH₂S)(S₄)(S)]⊖

Formula Unicode styled: 
[Re(SCH₂CH₂S)(S₄)(S)]⊖
Compound name(s): 
(ethane-1,2-dithiolato)-sulfido-tetrasulfido-rhenium(1-)
Central atom: 
Rhenium
Attached groups: 
SCH₂CH₂S (ethanedithiolato-κ²S)
S₄ (tetrasulfanediyl-κ²S)
S (thio; ⭀S)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Re«V5C5OVE16B7Z0X6L1»⊖
[MLXZ]𝘲 class: 
[MX6L1]-
MLXZ class (ENC, equivalent neutral class): 
MX5L2

[Re(S₄)₂(S)]⊖

Formula Unicode styled: 
[Re(S₄)₂(S)]⊖
Compound name(s): 
bis(tetrasulfido-S,S')-thioxo-rhenium(1-)
Central atom: 
Rhenium
Attached groups: 
S₄ (tetrasulfanediyl-κ²S)
S (thio; ⭀S)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Re«V5C5OVE16B7Z0X6L1»⊖
[MLXZ]𝘲 class: 
[MX6L1]-
MLXZ class (ENC, equivalent neutral class): 
MX5L2