PMe₃ (trimethylphosphane)

[Rh(Br)(Ph)(PMe₃)(Cp*)]

Formula Unicode styled: 
[Rh(Br)(Ph)(PMe₃)(Cp*)]
Compound name(s): 
Bromo-(η⁵-pentamethyl-cyclopentadienyl)-phenyl-trimethylphosphine-rhodium
Central atom: 
Rhodium
Attached groups: 
Br (bromo)
Ph (phenyl)
PMe₃ (trimethylphosphane)
Cp* (η⁵-pentamethylcyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

[Rh(Br)(C₃H₅)(PMe₃)(Cp*)]

Formula Unicode styled: 
[Rh(Br)(C₃H₅)(PMe₃)(Cp*)]
Compound name(s): 
Bromo-cyclopropyl-(η⁵-pentamethyl-cyclopentadienyl)-trimethylphosphine-rhodium
Central atom: 
Rhodium
Attached groups: 
Br (bromo)
C₃H₅ (cyclopropyl)
PMe₃ (trimethylphosphane)
Cp* (η⁵-pentamethylcyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

mer,trans–[Rh(H)(SPh)₂(PMe₃)₃]

Formula Unicode styled: 
mer,trans–[Rh(H)(SPh)₂(PMe₃)₃]
Compound name(s): 
(Hydrido)-tris(trimethylphosphino)-(phenylthiolato)-rhodium
Central atom: 
Rhodium
Attached groups: 
H (hydrido)
SPh (phenylthio)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

mer,trans–[Rh(C≡CPh)₂(SnPh₃)(PMe₃)₃]

Formula Unicode styled: 
mer,trans–[Rh(C≡CPh)₂(SnPh₃)(PMe₃)₃]
Compound name(s): 
tris(Trimethylphosphine)-bis(phenylethynyl)-(triphenyl-tin)-rhodium
Central atom: 
Rhodium
Attached groups: 
C≡CPh (phenylethynyl)
SnPh₃ (triphenylstannyl)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

mer,cis–[Rh(Ph)(CO₃-κ²O)(PMe₃)₃]

Formula Unicode styled: 
mer,cis–[Rh(Ph)(CO₃-κ²O)(PMe₃)₃]
Compound name(s): 
(Carbonato-O,O')-phenyl-tris(trimethylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
Ph (phenyl)
CO₃ (carbonato-κ²O)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

mer,cis–[Rh(Cl)₂(H)(PMe₃)₃]

Formula Unicode styled: 
mer,cis–[Rh(Cl)₂(H)(PMe₃)₃]
Compound name(s): 
Dichloro-hydrido-tris(trimethylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
Cl (chloro)
H (hydrido)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

mer–[Rh(SPh)(O₂)(PMe₃)₃]

Formula Unicode styled: 
mer–[Rh(SPh)(O₂)(PMe₃)₃]
Compound name(s): 
Dioxygen-tris(trimethylphosphino)-(phenylthiolato)-rhodium
Central atom: 
Rhodium
Attached groups: 
SPh (phenylthio)
O₂ (dioxygen)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V1C5OIE18B5Z0X1L4»
[MLXZ]𝘲 class: 
[MX1L4]
MLXZ class (ENC, equivalent neutral class): 
MX1L4

mer–[Rh(H)(SPh)(SiPh₃)(PMe₃)₃]

Formula Unicode styled: 
mer–[Rh(H)(SPh)(SiPh₃)(PMe₃)₃]
Compound name(s): 
tris(Trimethylphosphine)-phenylthiolato-(triphenylsilyl)-hydrido-rhodium
Central atom: 
Rhodium
Attached groups: 
H (hydrido)
SPh (phenylthio)
SiPh₃ (triphenylsilyl)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

mer–[Rh(Cl)(H)(SPh)(PMe₃)₃]

Formula Unicode styled: 
mer–[Rh(Cl)(H)(SPh)(PMe₃)₃]
Compound name(s): 
Benzenethiolato-chloro-hydrido-tris(trimethylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
Cl (chloro)
H (hydrido)
SPh (phenylthio)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

mer–[Rh(Cl)(H)(SiPh₃)(PMe₃)₃]

Formula Unicode styled: 
mer–[Rh(Cl)(H)(SiPh₃)(PMe₃)₃]
Compound name(s): 
Chloro-hydrido-tris(trimethylphosphine)-triphenylsilyl-rhodium
Central atom: 
Rhodium
Attached groups: 
Cl (chloro)
H (hydrido)
SiPh₃ (triphenylsilyl)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

mer–[Rh(Cl)(H)(Ph)(PMe₃)₃]

Formula Unicode styled: 
mer–[Rh(Cl)(H)(Ph)(PMe₃)₃]
Compound name(s): 
Chloro-hydrido-phenyl-tris(trimethylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
Cl (chloro)
H (hydrido)
Ph (phenyl)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(Me)₃(PMe₃)₃]

Formula Unicode styled: 
fac–[Rh(Me)₃(PMe₃)₃]
Compound name(s): 
Trimethyl-tris(trimethylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
Me (methyl)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(H)(Me)(PMe₃)([9]aneN₃-1,4,7-Me₃-κ³N)]²⊕

Formula Unicode styled: 
fac–[Rh(H)(Me)(PMe₃)([9]aneN₃-1,4,7-Me₃-κ³N)]²⊕
Compound name(s): 
(1,4,7-Trimethyl-1,4,7-triazacyclononane)-hydrido-methyl-trimethylphosphine-rhodium(2+)
Central atom: 
Rhodium
Attached groups: 
H (hydrido)
Me (methyl)
PMe₃ (trimethylphosphane)
[9]aneN₃-1,4,7-Me₃ (1,4,7-trimethyl-1,4,7-triazacyclononane-κ³N)
Charge on central atom: 
2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 17
Summary of calculated classifications: 
Rh«V4C6OIVE17B6Z0X2L4»2⊕
[MLXZ]𝘲 class: 
[MX2L4]2+
MLXZ class (ENC, equivalent neutral class): 
MX4L2

fac–[Rh(COMe)(I)(PMe₃)(Tp*-κ³N)]

Formula Unicode styled: 
fac–[Rh(COMe)(I)(PMe₃)(Tp*-κ³N)]
Compound name(s): 
(Hydrogen-tris(3,5-dimethylpyrazolyl)borate)-iodo-acetyl-trimethylphosphine-rhodium
Central atom: 
Rhodium
Attached groups: 
COMe (acetyl)
I (iodo)
PMe₃ (trimethylphosphane)
Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(Cl)₂{CH₂(PMe₃)}(PMe₃)₃]⊕

Formula Unicode styled: 
fac–[Rh(Cl)₂{CH₂(PMe₃)}(PMe₃)₃]⊕
Compound name(s): 
Dichloro-(trimethylphosphino)methyl-tris(trimethylphosphine)-rhodium(1+)
Central atom: 
Rhodium
Attached groups: 
Cl (chloro)
CH₂(PMe₃) (trimethylphosphonium-ylide)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(Cl)₂(PMe₃)(Tp*-κ³N)]

Formula Unicode styled: 
fac–[Rh(Cl)₂(PMe₃)(Tp*-κ³N)]
Compound name(s): 
Dichloro-(tris(3,5-dimethylpyrazolyl)borate)-trimethylphosphine-rhodium
Central atom: 
Rhodium
Attached groups: 
Cl (chloro)
PMe₃ (trimethylphosphane)
Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

cis,cis,trans–[Rh(H)₂(PMe₃)₂(Tp*-κ²N]

Formula Unicode styled: 
cis,cis,trans–[Rh(H)₂(PMe₃)₂(Tp*-κ²N]
Compound name(s): 
Dihydrogen-(hydrotris(3,5-dimethylpyrazolyl)borato-N,N')-bis(trimethylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
H (hydrido)
PMe₃ (trimethylphosphane)
Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ²N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

cis–[Rh(μ₂-SPh)(CO)(PMe₃)]₂

Formula Unicode styled: 
cis–[Rh(μ₂-SPh)(CO)(PMe₃)]₂
Compound name(s): 
bis-[(μ-phenylthiolato)-carbonyl-trimethylphosphine-rhodium]
Central atom: 
Rhodium
Attached groups: 
SPh (μ₂-phenylthio)
CO (carbonyl)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 4
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Rh«V1C4OIE16B4Z0X1L3»
[MLXZ]𝘲 class: 
[MX1L3]
MLXZ class (ENC, equivalent neutral class): 
MX1L3

cis–[Rh(H)₂(PMe₃)₄]⊕

Formula Unicode styled: 
cis–[Rh(H)₂(PMe₃)₄]⊕
Compound name(s): 
Dihydrido-tetrakis(trimethylphosphine)-rhodium(1+)
Central atom: 
Rhodium
Attached groups: 
H (hydrido)
PMe₃ (trimethylphosphane)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X2L4»⊕
[MLXZ]𝘲 class: 
[MX2L4]+
MLXZ class (ENC, equivalent neutral class): 
MX3L3

cis–[Rh(μ₂-Cl)(PMe₃)₂]₂

Formula Unicode styled: 
cis–[Rh(μ₂-Cl)(PMe₃)₂]₂
Compound name(s): 
bis-[(μ₂-Chloro)-bis(trimethylphosphine)-rhodium]
Central atom: 
Rhodium
Attached groups: 
Cl (μ₂-chloro)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 4
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Rh«V1C4OIE16B4Z0X1L3»
[MLXZ]𝘲 class: 
[MX1L3]
MLXZ class (ENC, equivalent neutral class): 
MX1L3