Dppm (bis-(diphenylphosphino)methane-κ²P)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 4

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Pd«V²C⁴O^IIE¹⁶B⁴Z⁰X²L²»

[MLXZ]𝘲 class:

[MX₂L₂]

MLXZ class (ENC, equivalent neutral class):

MX₂L₂

trans–[Rh(I)₂(Dppm-κ²P)₂]⊕

Formula Unicode styled:

trans–[Rh(I)₂(Dppm-κ²P)₂]⊕

Compound name(s):

Di-iodo-bis(bis(diphenylphosphino)methane-P,P')-rhodium(1+)

Central atom:

Attached groups:

I (iodo)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

trans–[Rh(Cl)(CO)(Dppm-κ²P)]₂

Formula Unicode styled:

trans–[Rh(Cl)(CO)(Dppm-κ²P)]₂

Compound name(s):

bis-[(μ2-bis(Diphenylphosphino)-methane)-chloro-carbonyl-rhodium]

Central atom:

Attached groups:

CO (carbonyl)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

CN: 4

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Rh(Cl)(PMe₃)(Dppm-κ²P)]

Formula Unicode styled:

[Rh(Cl)(PMe₃)(Dppm-κ²P)]

Compound name(s):

Chloro-trimethylphosphine-(bis(diphenylphosphino)methane)-rhodium

Central atom:

Attached groups:

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

CN: 4

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

mer,cis–[Rh(Cl)₃(PBuⁿ₃)(Dppm-κ²P)]

Formula Unicode styled:

mer,cis–[Rh(Cl)₃(PBuⁿ₃)(Dppm-κ²P)]

Compound name(s):

tris(n-Butyl)phosphine-trichloro-(bis(diphenylphosphino)methane-P,P')-rhodium

Central atom:

Attached groups:

PBuⁿ₃ (tri-n-butylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

fac–[Rh(I)₃(NCMe)(Dppm-κ²P)]

Formula Unicode styled:

fac–[Rh(I)₃(NCMe)(Dppm-κ²P)]

Compound name(s):

Acetonitrile-tri-iodo-(bis(diphenylphosphino)methane-P,P')-rhodium

Central atom:

Attached groups:

I (iodo)

NCMe (acetonitrile)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

fac–[Rh(Cl)₃(NCMe)(Dppm-κ²P)]

Formula Unicode styled:

fac–[Rh(Cl)₃(NCMe)(Dppm-κ²P)]

Compound name(s):

Acetonitrile-trichloro-(bis(diphenylphosphino)methane-P,P')-rhodium

Central atom:

Attached groups:

NCMe (acetonitrile)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

equatorial–[Rh(CO)(Dppm-κ²P)₂]⊕

Formula Unicode styled:

equatorial–[Rh(CO)(Dppm-κ²P)₂]⊕

Compound name(s):

bis(bis(Diphenylphosphino)methane)-carbonyl-rhodium(1+)

Central atom:

Attached groups:

CO (carbonyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X⁰L⁵»^⊕

[MLXZ]𝘲 class:

[ML₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

cis,cis,trans–[Rh(Cl)(H)(Dppm-κ²P)₂]⊕

Formula Unicode styled:

cis,cis,trans–[Rh(Cl)(H)(Dppm-κ²P)₂]⊕

Compound name(s):

Chloro-hydrido-bis(bis(diphenylphosphino)methane)-rhodium(1+)

Central atom:

Attached groups:

H (hydrido)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis–[Rh(COMe)(I)₂(Dppm-κ²P)]

Formula Unicode styled:

cis,cis–[Rh(COMe)(I)₂(Dppm-κ²P)]

Compound name(s):

Acetyl-bis(iodo)-(1,2-bis(diphenylphosphino)methane-P,P')-rhodium

Central atom:

Attached groups:

COMe (acetyl)

I (iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Ru(η²-H₂)(Dppm-κ²P)(Cp*)]⊕

Formula Unicode styled:

[Ru(η²-H₂)(Dppm-κ²P)(Cp*)]⊕

Compound name(s):

(η⁵-Pentamethyl-cyclopentadienyl)-dihydrogen-bis(diphenylphosphino)methane-ruthenium(1+)

Central atom:

Attached groups:

H₂ (η²-dihydrogen)

Cp* (η⁵-pentamethylcyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V²C⁶O^IIE¹⁸B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Ru(Dppm-κP)(Dppm-κ²P)(Cp)]⊕

Formula Unicode styled:

[Ru(Dppm-κP)(Dppm-κ²P)(Cp)]⊕

Compound name(s):

(η⁵-Cyclopentadienyl)-(bis(diphenylphosphino)methane-P,P')-(bis(diphenylphosphino)methane-P)-ruthenium(1+)

Central atom:

Dppm (bis-(diphenylphosphino)methane-κP)

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V²C⁶O^IIE¹⁸B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Ru(SBuᵗ)(Dppm-κ²P)(Cp)]⊕

Formula Unicode styled:

[Ru(SBuᵗ)(Dppm-κ²P)(Cp)]⊕

Compound name(s):

(η⁵-Cyclopentadienyl)-(bis(diphenylphosphino)methane-P,P')-(t-butylthiolato)-ruthenium(1+)

Central atom:

Attached groups:

SBuᵗ (t-butylthio)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Ru«V³C⁶O^IIIE¹⁷B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ru(Cl)₂(Dppm-κ²P)₂]

Formula Unicode styled:

cis,cis,trans–[Ru(Cl)₂(Dppm-κ²P)₂]

Compound name(s):

Dichloro-bis(bis(diphenylphosphino)methane-P,P')-ruthenium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

cis,cis,trans–[Ru(Cl)(=C=CH₂)(Dppm-κ²P)₂]⊕

Formula Unicode styled:

cis,cis,trans–[Ru(Cl)(=C=CH₂)(Dppm-κ²P)₂]⊕

Compound name(s):

Chloro-bis(bis(diphenylphosphino)methane)-vinylidene-ruthenium(1+)

Central atom:

Attached groups:

C=CH₂ (vinylidene, ethynylidene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁴C⁶O^IVE¹⁸B⁷Z⁰X³L⁴»^⊕

[MLXZ]𝘲 class:

[MX₃L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

cis,cis,trans–[Ru(C≡CH)(Cl)(Dppm-κ²P)₂]

Formula Unicode styled:

cis,cis,trans–[Ru(C≡CH)(Cl)(Dppm-κ²P)₂]

Compound name(s):

Acetylide-chloro-bis(bis(diphenylphosphino)methane)-ruthenium

Central atom:

Attached groups:

C≡CH (ethynyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Ru(O₂CMe)(Dppm-κ²P)₂]⊕

Formula Unicode styled:

[Ru(O₂CMe)(Dppm-κ²P)₂]⊕

Compound name(s):

(Acetato-O,O')-bis(bis(diphenylphosphino)-methane-P,P')-ruthenium(1+)

Central atom:

Attached groups:

O₂CMe (acetato-κ²O)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V²C⁶O^IIE¹⁸B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Ru(Cl)₂(Dppm-κ²P)₂]

Formula Unicode styled:

[Ru(Cl)₂(Dppm-κ²P)₂]

Compound name(s):

Dichloro-bis(bis(diphenylphosphino)methane-P,P')-ruthenium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Fe(Ph)(Dppm-κ²P)(Cp)]

Formula Unicode styled:

[Fe(Ph)(Dppm-κ²P)(Cp)]

Compound name(s):

Phenyl-(η⁵-cyclopentadienyl)-(bis(diphenylphosphino)methane-P,P')-iron

Central atom:

Iron

Attached groups:

Ph (phenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Fe(NCMe)(Dppm-κ²P)(Cp)]⊕

Formula Unicode styled:

[Fe(NCMe)(Dppm-κ²P)(Cp)]⊕

Compound name(s):

Acetonitrile-(η⁵-cyclopentadienyl)-(1,2-bis(diphenylphosphino)methane-P,P')-iron(1+)

Central atom:

Iron

Attached groups:

NCMe (acetonitrile)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: