Dmpe (1,2-bis-(dimethylphosphino)ethane)

C=CH₂ (vinylidene, ethynylidene)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 3

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 13

Summary of calculated classifications:

Mn«V²C³O^IIE¹³B⁴Z⁰X²L²»

[MLXZ]𝘲 class:

[MX₂L₂]

MLXZ class (ENC, equivalent neutral class):

MX₂L₂

cis,cis,trans–[Mn(H)(N₂)(Dmpe)₂]

Formula Unicode styled:

cis,cis,trans–[Mn(H)(N₂)(Dmpe)₂]

Compound name(s):

Hydrido-bis(dimethylphosphinoethane)-dinitrogen-manganese

Central atom:

Attached groups:

N₂ (dinitrogen)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V¹C⁶O^IE¹⁸B⁶Z⁰X¹L⁵»

[MLXZ]𝘲 class:

[MX₁L₅]

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

cis,cis,trans–[Mn(H)(CNXy)(Dmpe)₂]

Formula Unicode styled:

cis,cis,trans–[Mn(H)(CNXy)(Dmpe)₂]

Compound name(s):

(N-(2,6-Xylyl)-cyano)-hydrido-bis(dimethylphosphinoethane)-manganese

Central atom:

Attached groups:

CNXy (xylyl isocyanide)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V¹C⁶O^IE¹⁸B⁶Z⁰X¹L⁵»

[MLXZ]𝘲 class:

[MX₁L₅]

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

cis,cis,trans–[Mn(CO)(NCPh)(Dmpe)₂]⊕

Formula Unicode styled:

cis,cis,trans–[Mn(CO)(NCPh)(Dmpe)₂]⊕

Compound name(s):

Benzonitrile-carbonyl-bis(1,2-bis(dimethylphosphino)ethane-P,P')-manganese(1+)

Central atom:

Attached groups:

CO (carbonyl)

NCPh (benzonitrile)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V¹C⁶O^IE¹⁸B⁶Z⁰X⁰L⁶»^⊕

[MLXZ]𝘲 class:

[ML₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

cis–[Mn(H)(SiHPh₂)(Dmpe)(Cp)]

Formula Unicode styled:

cis–[Mn(H)(SiHPh₂)(Dmpe)(Cp)]

Compound name(s):

Hydrido-(η-cyclopentadienyl)-1,2-bis(dimethylphosphino)ethane-(hydridodiphenylsilyl)-manganese

Central atom:

Attached groups:

SiHPh₂ (diphenylsilyl)

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 7

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V³C⁷O^IIIE¹⁸B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

trans–[Tc(Cl)(N)(Dmpe)₂]⊕

Formula Unicode styled:

trans–[Tc(Cl)(N)(Dmpe)₂]⊕

Compound name(s):

Chloro-bis(1,2-bis(dimethylphosphino)ethane)-nitrido-technetium(1+)

Central atom:

Attached groups:

N (nitrido; ≡N)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁶O^VE¹⁸B⁸Z⁰X⁴L⁴»^⊕

[MLXZ]𝘲 class:

[MX₄L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

trans–[Tc(Cl)₂(Dmpe)₂]⊕

Formula Unicode styled:

trans–[Tc(Cl)₂(Dmpe)₂]⊕

Compound name(s):

Dichloro-(1,2-bis(dimethylphosphino)ethane)-technetium(1+)

Central atom:

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Tc«V³C⁶O^IIIE¹⁶B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

trans–[Tc(SMe)₂(Dmpe)₂]⊕

Formula Unicode styled:

trans–[Tc(SMe)₂(Dmpe)₂]⊕

Compound name(s):

bis(Methanethiolato-S)-bis(1,2-bis(dimethylphosphino)ethane-P,P')-technetium(1+)

Central atom:

Attached groups:

SMe (methylthio)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Tc«V³C⁶O^IIIE¹⁶B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

trans–[Tc(OH)(O)(Dmpe)₂]²⊕

Formula Unicode styled:

trans–[Tc(OH)(O)(Dmpe)₂]²⊕

Compound name(s):

(bis(Dimethylphosphino)ethane)-hydroxy-oxo-technetium(2+)

Central atom:

Attached groups:

OH (hydroxo)

O (oxo ⭀O X₂L)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁶O^VE¹⁸B⁸Z⁰X³L⁵»^2⊕

[MLXZ]𝘲 class:

[MX₃L₅]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

cis,cis,trans–[Tc(Cl)(N)(Dmpe)₂]⊕

Formula Unicode styled:

cis,cis,trans–[Tc(Cl)(N)(Dmpe)₂]⊕

Compound name(s):

Chloro-bis(bis(dimethylphosphino)ethane)-nitrido-technetium(1+)

Central atom:

Attached groups:

N (nitrido; ≡N)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁶O^VE¹⁸B⁸Z⁰X⁴L⁴»^⊕

[MLXZ]𝘲 class:

[MX₄L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

cis,cis,trans–[Tc(Cl)₂(PMe₂Ph)₂(Dmpe)]

Formula Unicode styled:

cis,cis,trans–[Tc(Cl)₂(PMe₂Ph)₂(Dmpe)]

Compound name(s):

Dichloro-(bis(dimethylphosphino)ethane-P,P')-bis(dimethylphenylphosphine)-technetium

Central atom:

Attached groups:

PMe₂Ph (dimethylphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Tc«V²C⁶O^IIE¹⁷B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

trans–[W(Cl)₄(Dmpe)]⊕

Formula Unicode styled:

trans–[W(Cl)₄(Dmpe)]⊕

Compound name(s):

bis(1,2-bis(Dimethylphosphino)ethane)-tetrachloro-tungsten(1+)

Central atom:

Tungsten

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 13

Summary of calculated classifications:

W«V⁵C⁶O^VE¹³B⁶Z⁰X⁴L²»^⊕

[MLXZ]𝘲 class:

[MX₄L₂]⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₁

trans–[W(Br)(O)(Dmpe)₂]

Formula Unicode styled:

trans–[W(Br)(O)(Dmpe)₂]

Compound name(s):

Bromo-bis(ethylene-bis(dimethylphosphine)-P,P')-oxo-tungsten

Central atom:

Tungsten

Attached groups:

Br (bromo)

O (oxo X₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

C≡CSiMe₃ (trimethylsilylalkynyl)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

W«V³C⁶O^IIIE¹⁷B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

trans–[Cr(C≡CSiMe₃)₂(Dmpe)₂]⊕

Formula Unicode styled:

trans–[Cr(C≡CSiMe₃)₂(Dmpe)₂]⊕

Compound name(s):

bis(1,2-bis(Dimethylphosphino)ethane-P,P')-bis(trimethylsilylethynyl)-chromium(1+)

Central atom:

Chromium

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Cr«V³C⁶O^IIIE¹⁵B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

trans–[Cr(C≡CPh)₂(Dmpe)₂]⊕

Formula Unicode styled:

trans–[Cr(C≡CPh)₂(Dmpe)₂]⊕

Compound name(s):

bis(1,2-bis(Dimethylphosphino)ethane-P,P')-bis(phenylethynyl)-chromium(1+)

Central atom:

Chromium

Attached groups:

C≡CPh (phenylethynyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Cr«V³C⁶O^IIIE¹⁵B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis–[W(NCS-κN)(CO)₂(≡CTol)(Dmpe)]

Formula Unicode styled:

cis,cis–[W(NCS-κN)(CO)₂(≡CTol)(Dmpe)]

Compound name(s):

Dicarbonyl-isothiocyanato-(p-tolylmethylidyne)-(1,2-bis(dimethylphosphino)ethane-P,P')-tungsten

Central atom:

Tungsten

Attached groups:

NCS (isothiocyanato-κN)

CO (carbonyl)

≡CTol (tolylmethylidyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁶O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

trans–[Mo(Se)(Dmpe)₂]

Formula Unicode styled:

trans–[Mo(Se)(Dmpe)₂]

Compound name(s):

bis(1,2-bis(Dimethylphosphino)ethane)-diseleno-molybdenum

Central atom:

Attached groups:

Se (seleno; ⭀Se)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V²C⁵O^IIE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

trans–[Mo(H)₃(Dmpe)(Cp)]

Formula Unicode styled:

trans–[Mo(H)₃(Dmpe)(Cp)]

Compound name(s):

(η-Cyclopentadienyl)-trihydrido-bis(dimethylphenylphosphine)-molybdenum

Central atom:

Attached groups:

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

CN: 8

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁴C⁸O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

trans–[Mo(Cl)₂(Dmpe)₂]⊕

Formula Unicode styled:

trans–[Mo(Cl)₂(Dmpe)₂]⊕

Compound name(s):

Dichloro-bis(1,2-bis(dimethylphosphino)-ethane-P,P')-molybdenum(1+)

Central atom:

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Mo«V³C⁶O^IIIE¹⁵B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

trans–[Mo(Cl)₂(Dmpe)₂]

Formula Unicode styled:

trans–[Mo(Cl)₂(Dmpe)₂]

Compound name(s):

Dichloro-bis(1,2-bis(dimethylphosphino)-ethane-P,P')-molybdenum

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):