8-coordinate: ③₂-●-2 bent metallocene

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf(H)(PHPh)(Cp*)₂]

Formula Unicode styled:

[Hf(H)(PHPh)(Cp*)₂]

Compound name(s):

Hydrido-bis(η-pentamethyl-cyclopentadienyl)-phenylphosphido-hafnium

Central atom:

Attached groups:

PHPh (phenylphosphanyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf(H)(NHMe)(Cp*)₂]

Formula Unicode styled:

[Hf(H)(NHMe)(Cp*)₂]

Compound name(s):

bis(η-Pentamethyl-cyclopentadienyl)-hydrido-(methylamino-N)-hafnium

Central atom:

Attached groups:

NHMe (methylamino: planar)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁸B⁹Z⁰X⁴L⁵»

[MLXZ]𝘲 class:

[MX₄L₅]

MLXZ class (ENC, equivalent neutral class):

MX₄L₅

[Hf(F)(H)(Cp*)₂]

Formula Unicode styled:

[Hf(F)(H)(Cp*)₂]

Compound name(s):

Fluoro-hydrido-bis(η-pentamethylcyclopentadienyl)-hafnium

Central atom:

Attached groups:

F (fluoro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf(F)₂(Cp*)₂]

Formula Unicode styled:

[Hf(F)₂(Cp*)₂]

Compound name(s):

Difluoro-bis(η-pentamethylcyclopentadienyl)-hafnium

Central atom:

Attached groups:

F (fluoro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf(Et){CH(PPh₃)}(Cp)₂]

Formula Unicode styled:

[Hf(Et){CH(PPh₃)}(Cp)₂]

Compound name(s):

bis(η-Cyclopentadienyl)-ethyl-(triphenylphosphinylidene-methyl)-hafnium

Central atom:

CH(PPh₃) (triphenylphosphinylidene-methyl)

Attached groups:

Et (ethyl)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁸B⁹Z⁰X⁵L⁴»^⊖

[MLXZ]𝘲 class:

[MX₅L₄]^-

MLXZ class (ENC, equivalent neutral class):

MX₄L₅

[Hf(Cl)₂(Cp)(Cp*)]

Formula Unicode styled:

[Hf(Cl)₂(Cp)(Cp*)]

Compound name(s):

(η-Cyclopentadienyl)-(η-pentamethyl-cyclopentadienyl)-dichloro-hafnium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf(Cl)₂(η⁵-C₅H₄Me)₂]

Formula Unicode styled:

[Hf(Cl)₂(η⁵-C₅H₄Me)₂]

Compound name(s):

Dichloro-bis(η-methyl-cyclopentadienyl)-hafnium

Central atom:

Attached groups:

C₅H₄Me (η⁵-methylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf(Cl){As(SiMe₃)₂}(η⁵-C₅H₄Me)₂]

Formula Unicode styled:

[Hf(Cl){As(SiMe₃)₂}(η⁵-C₅H₄Me)₂]

Compound name(s):

bis(η-Methylcyclopentadienyl)-chloro-(bis(trimethylsilyl)arsenido)-hafnium

Central atom:

Attached groups:

As(SiMe₃)₂ (bistrimethylsilylarsanyl)

C₅H₄Me (η⁵-methylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf(Cl)(OSiPh₃)(Cp)₂]

Formula Unicode styled:

[Hf(Cl)(OSiPh₃)(Cp)₂]

Compound name(s):

Chloro-(triphenylsiloxy)-hafnocene

Central atom:

Attached groups:

OSiPh₃ (triphenylsiloxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf(Bz)₃(Cp*)]

Formula Unicode styled:

[Hf(Bz)₃(Cp*)]

Compound name(s):

Tribenzyl-(η-pentamethylcyclopentadienyl)-hafnium

Central atom:

Attached groups:

Bz (phenylmethanido-κC)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 6

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 12

Summary of calculated classifications:

Hf«V⁴C⁶O^IVE¹²B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

[Hf(Bz)₂(Cp)₂]

Formula Unicode styled:

[Hf(Bz)₂(Cp)₂]

Compound name(s):

dibenzyl-bis(η-cyclopentadienyl)-hafnium

Central atom:

Attached groups:

Bz (phenylmethanido-κC)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf(Buⁿ)₂(Cp*)₂]

Formula Unicode styled:

[Hf(Buⁿ)₂(Cp*)₂]

Compound name(s):

bis(n-Butyl)-bis(η-pentamethyl-cyclopentadienyl)-hafnium

Central atom:

Attached groups:

Buⁿ (butyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf(Br)₂(Cp)₂]

Formula Unicode styled:

[Hf(Br)₂(Cp)₂]

Compound name(s):

bis(η-Cyclopentadienyl)-dibromo-hafnium

Central atom:

Attached groups:

Br (bromo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf(Br)₂(Cp*)₂]

Formula Unicode styled:

[Hf(Br)₂(Cp*)₂]

Compound name(s):

bis(η-Pentamethyl-cyclopentadienyl)-dibromo-hafnium

Central atom:

Attached groups:

Br (bromo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf{Si(SiMe₃)₃}₂(Cp)₂]

Formula Unicode styled:

[Hf{Si(SiMe₃)₃}₂(Cp)₂]

Compound name(s):

bis(tris(trimethylsilyl)silyl)-hafnocene

Central atom:

Si(SiMe₃)₃ (tris-trimethylsilyl-silyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf{P(SiMe₃)₂}₂(Cp)₂]

Formula Unicode styled:

[Hf{P(SiMe₃)₂}₂(Cp)₂]

Compound name(s):

bis(η-Cyclopentadienyl)-bis(bis(trimethylsilyl)phosphido-P)-hafnium

Central atom:

P(SiMe₃)₂ (bis(trimethylsilyl)phosphanyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf(η⁴-C₄H₄Me₂)(Cp)₂]

Formula Unicode styled:

[Hf(η⁴-C₄H₄Me₂)(Cp)₂]

Compound name(s):

(η-s-cis-2,3-Dimethylbutadiene)-hafnocene

Central atom:

C₄H₄Me₂ (η⁴-dimethylbutadiene)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V²C⁸O^IIE¹⁸B⁸Z⁰X²L⁶»

[MLXZ]𝘲 class:

[MX₂L₆]

MLXZ class (ENC, equivalent neutral class):

MX₂L₆

[Hf(SPh)₂(Cp*)₂]

Formula Unicode styled:

[Hf(SPh)₂(Cp*)₂]

Compound name(s):

bis-(η-Pentamethyl-cyclopentadienyl)-bis-(phenylsulfido)-hafnium

Central atom:

Attached groups:

SPh (phenylthio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf(SnMe₃)₂(η⁶-C₇H₈)₂]

Formula Unicode styled:

[Hf(SnMe₃)₂(η⁶-C₇H₈)₂]

Compound name(s):

bis(Trimethyl-tin)-bis(η-toluene)-hafnium

Central atom:

Attached groups:

SnMe₃ (trimethylstannyl)

C₇H₈ (toluene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: