7-coordinate: octahedron, face monocapped (OCF-7)

[Mo(Cl)(CO)₂(Dmpe)₂]⊕

Formula Unicode styled: 
[Mo(Cl)(CO)₂(Dmpe)₂]⊕
Compound name(s): 
Dicarbonyl-chloro-bis(1,2-bis(dimethylphosphino)-ethane-P,P')-molybdenum(1+)
Central atom: 
Molybdenum
Attached groups: 
Cl (chloro)
CO (carbonyl)
Dmpe (1,2-bis-(dimethylphosphino)ethane)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Mo«V2C7OIIE18B7Z0X1L6»⊕
[MLXZ]𝘲 class: 
[MX1L6]+
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[Mo(Br)(CO)₃([9]aneN₃-κ³N)]⊕

Formula Unicode styled: 
[Mo(Br)(CO)₃([9]aneN₃-κ³N)]⊕
Compound name(s): 
Bromo-(1,4,7-triazacyclononane-N¹,N⁴,N⁷)-tricarbonyl-molybdenum(1+)
Central atom: 
Molybdenum
Attached groups: 
Br (bromo)
CO (carbonyl)
[9]aneN₃ (1,4,7-triazacyclononane-κ³N)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Mo«V2C7OIIE18B7Z0X1L6»⊕
[MLXZ]𝘲 class: 
[MX1L6]+
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[Mo(Br)₂(CO)₃(Dppe-κ²P)]

Formula Unicode styled: 
[Mo(Br)₂(CO)₃(Dppe-κ²P)]
Compound name(s): 
Dibromo-tricarbonyl-(1,2-bis(diphenylphosphino)ethane)-molybdenum
Central atom: 
Molybdenum
Attached groups: 
Br (bromo)
CO (carbonyl)
Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Mo«V2C7OIIE18B7Z0X2L5»
[MLXZ]𝘲 class: 
[MX2L5]
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[Mo(Br)₂(CO)₂(PMe₂Ph)₃]

Formula Unicode styled: 
[Mo(Br)₂(CO)₂(PMe₂Ph)₃]
Compound name(s): 
Dibromo-dicarbonyl-tris(dimethylphenylphosphine) molybdenum
Central atom: 
Molybdenum
Attached groups: 
Br (bromo)
CO (carbonyl)
PMe₂Ph (dimethylphenylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Mo«V2C7OIIE18B7Z0X2L5»
[MLXZ]𝘲 class: 
[MX2L5]
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[Mo(O₂CCF₃-κO)₂(CO)₂(PMe₃)₃]

Formula Unicode styled: 
[Mo(O₂CCF₃-κO)₂(CO)₂(PMe₃)₃]
Compound name(s): 
bis(Trifluoroacetato-O)-dicarbonyl-tris(trimethylphosphine)-molybdenum
Central atom: 
Molybdenum
Attached groups: 
O₂CCF₃ (trifluoroacetato-κO)
CO (carbonyl)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Mo«V2C7OIIE18B7Z0X2L5»
[MLXZ]𝘲 class: 
[MX2L5]
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[Mo(CNMe)₇]²⊕

Formula Unicode styled: 
[Mo(CNMe)₇]²⊕
Compound name(s): 
heptakis(Methylisocyanide)-molybdenum(2+)
Central atom: 
Molybdenum
Attached groups: 
CNMe (methyl isocyanide)
Charge on central atom: 
2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Mo«V2C7OIIE18B7Z0X0L7»2⊕
[MLXZ]𝘲 class: 
[ML7]2+
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[Nb(I)(CO)₂(Dppe-κ²P)₂]

Formula Unicode styled: 
[Nb(I)(CO)₂(Dppe-κ²P)₂]
Compound name(s): 
Iodo-dicarbonyl-bis(1,2-bis(diphenylphosphino)-ethane-P,P')-niobium
Central atom: 
Niobium
Attached groups: 
I (iodo)
CO (carbonyl)
Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Nb«V1C7OIE18B7Z0X1L6»
[MLXZ]𝘲 class: 
[MX1L6]
MLXZ class (ENC, equivalent neutral class): 
MX1L6

[Nb(I)(CO)₂(CNCy)₂(Dppe-κ²P)]

Formula Unicode styled: 
[Nb(I)(CO)₂(CNCy)₂(Dppe-κ²P)]
Compound name(s): 
bis(Cyclohexylisocyano)-(bis(diphenylphosphino)ethane)-dicarbonyl-iodo-niobium
Central atom: 
Niobium
Attached groups: 
I (iodo)
CO (carbonyl)
CNCy (cyclohexyl isocyanide)
Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Nb«V1C7OIE18B7Z0X1L6»
[MLXZ]𝘲 class: 
[MX1L6]
MLXZ class (ENC, equivalent neutral class): 
MX1L6

[Nb(Cl)₄(PMe₃)₂]

Formula Unicode styled: 
[Nb(Cl)₄(PMe₃)₂]
Compound name(s): 
Tetrachloro-tris(trimethylphosphine)-niobium
Central atom: 
Niobium
Attached groups: 
Cl (chloro)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 13
Summary of calculated classifications: 
Nb«V4C6OIVE13B6Z0X4L2»
[MLXZ]𝘲 class: 
[MX4L2]
MLXZ class (ENC, equivalent neutral class): 
MX4L2

[Nb(Cl)₃(O)(PMe₃)₃]

Formula Unicode styled: 
[Nb(Cl)₃(O)(PMe₃)₃]
Compound name(s): 
Oxo-trichloro-tris(trimethylphosphine)-niobium
Central atom: 
Niobium
Attached groups: 
Cl (chloro)
O (oxo ⭀O X₂L)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Nb«V5C7OVE18B9Z0X5L4»
[MLXZ]𝘲 class: 
[MX5L4]
MLXZ class (ENC, equivalent neutral class): 
MX5L4

[Nb(CO)₃(PMe₃)₄]⊕

Formula Unicode styled: 
[Nb(CO)₃(PMe₃)₄]⊕
Compound name(s): 
Tricarbonyl-tetrakis(trimethylphosphine)-niobium(1+)
Central atom: 
Niobium
Attached groups: 
CO (carbonyl)
PMe₃ (trimethylphosphane)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Nb«V1C7OIE18B7Z0X0L7»⊕
[MLXZ]𝘲 class: 
[ML7]+
MLXZ class (ENC, equivalent neutral class): 
MX1L6

[Yb(NCS-κN)₃(Dme)₂]

Formula Unicode styled: 
[Yb(NCS-κN)₃(Dme)₂]
Compound name(s): 
bis(1,2-bis(Methoxy)ethane)-tris(thiocyanato)-ytterbium
Central atom: 
Ytterbium
Attached groups: 
NCS (isothiocyanato-κN)
Dme (dimethoxyethane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 27
Summary of calculated classifications: 
Yb«V3C7OIIIE27B7Z0X3L4»
[MLXZ]𝘲 class: 
[MX3L4]
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[Zr(I)₄(PMe₃)₃]

Formula Unicode styled: 
[Zr(I)₄(PMe₃)₃]
Compound name(s): 
tris(Trimethylphosphine)-tetra-iodo-zirconium
Central atom: 
Zirconium
Attached groups: 
I (iodo)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Zr«V4C7OIVE14B7Z0X4L3»
[MLXZ]𝘲 class: 
[MX4L3]
MLXZ class (ENC, equivalent neutral class): 
MX4L3

cis–[Zr(OPh){CO₂(OH)-κ²O}(Tpp)]

Formula Unicode styled: 
cis–[Zr(OPh){CO₂(OH)-κ²O}(Tpp)]
Compound name(s): 
(phenolato)-(hydrogencarbonato)-(tetraphenylporphyrinato)-zirconium
Central atom: 
Zirconium
Attached groups: 
OPh (phenoxy)
CO₂(OH) (hydrogencarbonato-κ²O)
Tpp (tetraphenylporphyrin)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Zr«V4C7OIVE14B7Z0X4L3»
[MLXZ]𝘲 class: 
[MX4L3]
MLXZ class (ENC, equivalent neutral class): 
MX4L3

[Y(SO₃CF₃-κO)₃(Thf)(Tpm*-κ³N)]

Formula Unicode styled: 
[Y(SO₃CF₃-κO)₃(Thf)(Tpm*-κ³N)]
Compound name(s): 
(tris(3,5-Dimethylpyrazolyl)methane)-(tetrahydrofuran)-tris(trifluoromethanesulfonato)-yttrium
Central atom: 
Yttrium
Attached groups: 
OSO₂CF₃ (trifluoromethanesulfonato-κO)
Thf (tetrahydrofuran)
Tpm* (tris(3,5-dimethylpyrazolyl)methane-κ³N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Y«V3C7OIIIE14B7Z0X3L4»
[MLXZ]𝘲 class: 
[MX3L4]
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[Ti(SnPh₃)₂(CO)₅]²⊖

Formula Unicode styled: 
[Ti(SnPh₃)₂(CO)₅]²⊖
Compound name(s): 
pentacarbonyl-bis(triphenylstannyl)-titanium(2-)
Central atom: 
Titanium
Attached groups: 
SnPh₃ (triphenylstannyl)
CO (carbonyl)
Charge on central atom: 
-2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 0
Oxidation Number (ON) (Roman numerals): 
ON: (O)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Ti«V0C7OOE18B7Z0X2L5»2⊖
[MLXZ]𝘲 class: 
[MX2L5]2-
MLXZ class (ENC, equivalent neutral class): 
ML7

[Ti(CO)₄([9]aneN₃-κ³N)]

Formula Unicode styled: 
[Ti(CO)₄([9]aneN₃-κ³N)]
Compound name(s): 
(1,4,7-Trimethyl-1,4,7-triazacyclononane)-tetracarbonyl-titanium
Central atom: 
Titanium
Attached groups: 
CO (carbonyl)
[9]aneN₃ (1,4,7-triazacyclononane-κ³N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 0
Oxidation Number (ON) (Roman numerals): 
ON: (O)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Ti«V0C7OOE18B7Z0X0L7»
[MLXZ]𝘲 class: 
[ML7]
MLXZ class (ENC, equivalent neutral class): 
ML7

[Ti(CO)₃(Dmpe)₂]

Formula Unicode styled: 
[Ti(CO)₃(Dmpe)₂]
Compound name(s): 
bis(1,2-bis(Dimethylphosphino)-ethane)-tricarbonyl-titanium
Central atom: 
Titanium
Attached groups: 
CO (carbonyl)
Dmpe (1,2-bis-(dimethylphosphino)ethane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 0
Oxidation Number (ON) (Roman numerals): 
ON: (O)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Ti«V0C7OOE18B7Z0X0L7»
[MLXZ]𝘲 class: 
[ML7]
MLXZ class (ENC, equivalent neutral class): 
ML7

[V(Me)(CO)₂(Dmpe)₂]

Formula Unicode styled: 
[V(Me)(CO)₂(Dmpe)₂]
Compound name(s): 
Dicarbonyl-bis(bis(dimethylphosphino)ethane)-methyl-vanadium
Central atom: 
Vanadium
Attached groups: 
Me (methyl)
CO (carbonyl)
Dmpe (1,2-bis-(dimethylphosphino)ethane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
V«V1C7OIE18B7Z0X1L6»
[MLXZ]𝘲 class: 
[MX1L6]
MLXZ class (ENC, equivalent neutral class): 
MX1L6

[V{Au(PPh₃)}(CO)₆]

Formula Unicode styled: 
[V{Au(PPh₃)}(CO)₆]
Compound name(s): 
Hexacarbonyl-(triphenylphosphine-gold)-vanadium
Central atom: 
Vanadium
Attached groups: 
Au(PPh₃) (triphenylphosphinogold)
CO (carbonyl)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
V«V1C7OIE18B7Z0X1L6»
[MLXZ]𝘲 class: 
[MX1L6]
MLXZ class (ENC, equivalent neutral class): 
MX1L6