6-coordinate: octahedron (OC-6)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

OSO₂Me (methylsulfonato-κO)

Summary of calculated classifications:

Pt«V⁴C⁶O^IIIE¹⁸B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

trans–[Pt(OSO₂Me-κO)(μ₂-O₂CMe)₂]₂

Formula Unicode styled:

trans–[Pt(OSO₂Me-κO)(μ₂-O₂CMe)₂]₂

Compound name(s):

bis-[bis(μ₂-Acetato)-(methanesulfonato-O)-platinum(Pt—Pt)]

Central atom:

Platinum

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Pt«V⁴C⁶O^IIIE¹⁸B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

trans–[Os{S(CH₂)₅}₂(Oep)]⊕

Formula Unicode styled:

trans–[Os{S(CH₂)₅}₂(Oep)]⊕

Compound name(s):

(Octaethylporphinato)-(pentamethylene sulfide)-osmium(1+)

Central atom:

S(CH₂)₅ (pentamethylenesulfide)

Attached groups:

Oep (octaethylporphyrin)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Os«V³C⁶O^IIIE¹⁷B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

trans–[Os(H)₄(PMe₂Ph)₂]⊖

Formula Unicode styled:

trans–[Os(H)₄(PMe₂Ph)₂]⊖

Compound name(s):

tetrahydrido-bis(dimethylphenylphosphine)-osmium(1-)

Central atom:

PMe₂Ph (dimethylphenylphosphane)

Attached groups:

H (hydrido)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Os«V³C⁶O^IIIE¹⁷B⁶Z⁰X⁴L²»^⊖

[MLXZ]𝘲 class:

[MX₄L₂]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

trans–[Os(Cl)₄(O)₂]²⊖

Formula Unicode styled:

trans–[Os(Cl)₄(O)₂]²⊖

Compound name(s):

tetrachloro-dioxo-osmium(2-)

Central atom:

Attached groups:

O (oxo X₂)

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰L⁰X⁸»^2⊖

[MLXZ]𝘲 class:

[MX₈]^2-

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

trans–[Os(Cl)(μ₂-O₂CMe)₂]₂

Formula Unicode styled:

trans–[Os(Cl)(μ₂-O₂CMe)₂]₂

Compound name(s):

bis-[chloro-bis(μ₂-acetato)-osmium(Os≡Os)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^IIIE¹⁸B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

trans–[Os(Cl)(μ₂-O₂CEt)₂]₂

Formula Unicode styled:

trans–[Os(Cl)(μ₂-O₂CEt)₂]₂

Compound name(s):

bis-[chloro-bis(μ₂-propionato)-osmium(Os≡Os)]

Central atom:

Attached groups:

O₂CEt (μ₂-propanoato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^IIIE¹⁸B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

trans–[Os(Cl)(μ₂-O₂CPrⁿ)₂]₂

Formula Unicode styled:

trans–[Os(Cl)(μ₂-O₂CPrⁿ)₂]₂

Compound name(s):

bis-[chloro-bis(μ₂-n-butyrato)-osmium(Os≡Os)]

Central atom:

Attached groups:

O₂CPrⁿ (μ₂-propionato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^IIIE¹⁸B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

trans–[Os(Cl)(CO)₄]₂

Formula Unicode styled:

trans–[Os(Cl)(CO)₄]₂

Compound name(s):

bis-[(Tetracarbonyl-chloro-osmium]

Central atom:

Attached groups:

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

trans–[Os(Cl)(C₆H₅CNO-κN,κO)₂]₂

Formula Unicode styled:

trans–[Os(Cl)(C₆H₅CNO-κN,κO)₂]₂

Compound name(s):

bis-[bis(μ₂-Benzamidato-N,O)-chloro-osmium(Os≡Os)]

Central atom:

Attached groups:

C₆H₅CNO (benzamidato-κN,κO)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^IIIE¹⁸B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

trans–[Os(Br)(C₆H₅CNO-κN,κO)₂]₂

Formula Unicode styled:

trans–[Os(Br)(C₆H₅CNO-κN,κO)₂]₂

Compound name(s):

bis-[bis(μ₂-Benzamidato-N,O)-bromo-osmium(Os≡Os)]

Central atom:

C₆H₅CNO (benzamidato-κN,κO)

Attached groups:

Br (bromo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

[16]aneN₄ (1,5,9,13-tetraazacyclohexadodecane-κ⁴N)

Summary of calculated classifications:

Os«V⁶C⁶O^IIIE¹⁸B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

trans–[Ni(NCS-κN)₂([16]aneN₄-κ⁴N)]

Formula Unicode styled:

trans–[Ni(NCS-κN)₂([16]aneN₄-κ⁴N)]

Compound name(s):

bis(Isothiocyanato)-(1,5,9,13-tetra-azacyclohexadecane)-nickel

Central atom:

Nickel

Attached groups:

NCS (isothiocyanato-κN)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

[14]aneN₄-Me₄ (tetramethyl-1,4,8,11-tetraazacyclotetradecane-κ⁴N)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 20

Summary of calculated classifications:

Ni«V²C⁶O^IIE²⁰B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

trans–[Ni(N₃)₂([14]aneN₄-Me₄-κ⁴N)]

Formula Unicode styled:

trans–[Ni(N₃)₂([14]aneN₄-Me₄-κ⁴N)]

Compound name(s):

Diazido-(2,5,9,12-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)-nickel

Central atom:

Nickel

Attached groups:

N₃ (azido)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

O₂CCF₃ (trifluoroacetato-κO)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 20

Summary of calculated classifications:

Ni«V²C⁶O^IIE²⁰B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

trans–[Mn(O₂CCF₃-κO)(N)([14]aneN₄-κ⁴N)]⊕

Formula Unicode styled:

trans–[Mn(O₂CCF₃-κO)(N)([14]aneN₄-κ⁴N)]⊕

Compound name(s):

(1,4,8,11-Tetra-azacyclotetradecane)-(trifluoroacetato-O)-nitrido-manganese(1+)

Central atom:

Manganese

Attached groups:

N (nitrido; ≡N)

[14]aneN₄ (1,4,7,10-tetraazacyclotetradecane-κ⁴N)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V⁵C⁶O^VE¹⁸B⁸Z⁰X⁴L⁴»^⊕

[MLXZ]𝘲 class:

[MX₄L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Tc(O)₂]

Formula Unicode styled:

[Tc(O)₂]

Compound name(s):

dioxo-technetium|technetium dioxide

Central atom:

Attached groups:

O (oxo X₂)

Charge on central atom:

Compound type:

Lattice

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 0

Summary of calculated classifications:

Tc«V⁴C⁶O^IV»

[MLXZ]𝘲 class:

MLXZ class (ENC, equivalent neutral class):

[Tc(CO)₃(μ₃-Dedtc)]₂

Formula Unicode styled:

[Tc(CO)₃(μ₃-Dedtc)]₂

Compound name(s):

bis-[(μ₂-Diethylcarbamodithioato-S,S,S')-tricarbonyl-technetium]

Central atom:

Dedtc (μ₃-diethyldithiocarbamato)

Attached groups:

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V¹C⁶O^IE¹⁸B⁶Z⁰X¹L⁵»

[MLXZ]𝘲 class:

[MX₁L₅]

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

[Tc(Cl)(μ₂-Cl)(CO)₂(NO)]₂

Formula Unicode styled:

[Tc(Cl)(μ₂-Cl)(CO)₂(NO)]₂

Compound name(s):

bis-[(μ₂-chloro)-chloro-dicarbonyl-nitrosyl-technetium]

Central atom:

Attached groups:

NO (nitrosyl, linear)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁶O^IE¹⁸B⁸X³L⁴Z¹»

[MLXZ]𝘲 class:

[MX₃L₄Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Tc(Cl)(μ₂-O₂CMe)₂]₂

Formula Unicode styled:

[Tc(Cl)(μ₂-O₂CMe)₂]₂

Compound name(s):

bis-[bis-(μ₂-Acetato-O,O')-chloro-technetium(Tc≣Tc)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 7

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁷C⁶O^IIIE¹⁸B⁹Z⁰X⁷L²»

[MLXZ]𝘲 class:

[MX₇L₂]

MLXZ class (ENC, equivalent neutral class):

MX₇L₂

[Tc(Cl)(N)(Tet-κ⁴N)]⊕

Formula Unicode styled:

[Tc(Cl)(N)(Tet-κ⁴N)]⊕

Compound name(s):

Chloro-nitrido-(1,5,8,12-tetra-azadodecane)-technetium(1+)

Central atom:

Attached groups:

Tet (1,5,8,12-tetraazadodecane-κ⁴N)

N (nitrido; ≡N)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁶O^VE¹⁸B⁸Z⁰X⁴L⁴»^⊕

[MLXZ]𝘲 class:

[MX₄L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Re(NCMe)₅]₂⁴⊕

Formula Unicode styled:

[Re(NCMe)₅]₂⁴⊕

Compound name(s):

bis-[penta(Acetonitrile)-rhenium(Re≡Re)(2+)]

Central atom:

Rhenium

Attached groups:

NCMe (acetonitrile)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: