6-coordinate: octahedron (OC-6)

[Cr(SH)(μ₃-S)(En)]₄

Formula Unicode styled: 
[Cr(SH)(μ₃-S)(En)]₄
Compound name(s): 
tetrakis-[(hydrogen-sulfido)-(μ-sulfido)-(ethane-1,2-diamine)-chromium]
Central atom: 
Chromium
Attached groups: 
SH (hydrothio)
S (μ₃-thio X₂L)
En (ethylenediamine)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 15
Summary of calculated classifications: 
Cr«V3C6OIIIE15B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

trans–[Cr(μ₂-O₂CMe)₂(Thf)]₂

Formula Unicode styled: 
trans–[Cr(μ₂-O₂CMe)₂(Thf)]₂
Compound name(s): 
bis-[di(μ₂-acetato)-(tetrahydrofuran)-chromium (Cr≣Cr)
Central atom: 
Chromium
Attached groups: 
O₂CMe (μ₂-acetato)
Thf (tetrahydrofuran)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Cr«V6C6OIIE18B9Z0X6L3»
[MLXZ]𝘲 class: 
[MX6L3]
MLXZ class (ENC, equivalent neutral class): 
MX6L3

trans,trans–[W(Cl)₂(OSiPh₃)₂(⭀NPh)(OEt₂)]

Formula Unicode styled: 
trans,trans–[W(Cl)₂(OSiPh₃)₂(⭀NPh)(OEt₂)]
Compound name(s): 
dichloro-bis(triphenylsilanolato)-phenylimino)-(diethyl ether)-(tungsten
Central atom: 
Tungsten
Attached groups: 
Cl (chloro)
OSiPh₃ (triphenylsiloxy)
⭀NPh (phenylimino)
OEt₂ (diethylether)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
W«V6C6OVIE16B8Z0X6L2»
[MLXZ]𝘲 class: 
[MX6L2]
MLXZ class (ENC, equivalent neutral class): 
MX6L2

cis–[W(H)₂(CO)₄]²⊖

Formula Unicode styled: 
cis–[W(H)₂(CO)₄]²⊖
Compound name(s): 
dihydryl-tetracarbonyl-tungsten(2-)
Central atom: 
Tungsten
Attached groups: 
H (hydrido)
CO (carbonyl)
Charge on central atom: 
-2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 0
Oxidation Number (ON) (Roman numerals): 
ON: (O)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
W«V0C6OOE18B6Z0X2L4»2⊖
[MLXZ]𝘲 class: 
[MX2L4]2-
MLXZ class (ENC, equivalent neutral class): 
ML6

cis,cis,trans–[Mo(Cl)₂{OC(Buᵗ)CHC(Buᵗ)O}₂]

Formula Unicode styled: 
cis,cis,trans–[Mo(Cl)₂{OC(Buᵗ)CHC(Buᵗ)O}₂]
Compound name(s): 
dichloro-bis(2,2,6,6-tetramethylheptane-3,5-dionato)-molybdenum
Central atom: 
Molybdenum
Attached groups: 
Cl (chloro)
OC(Buᵗ)CHC(Buᵗ)O (tetramethylheptane-3,5-dionato)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Mo«V4C6OIVE14B6Z0X4L2»
[MLXZ]𝘲 class: 
[MX4L2]
MLXZ class (ENC, equivalent neutral class): 
MX4L2

cis,cis,cis–[Mo(SO₃CF₃-κO)₂{OC(Buᵗ)CHC(Buᵗ)O}₂]

Formula Unicode styled: 
cis,cis,cis–[Mo(SO₃CF₃-κO)₂{OC(Buᵗ)CHC(Buᵗ)O}₂]
Compound name(s): 
bis(trifluoromethanesulfonato)-bis(2,2,6,6-tetramethylheptane-3,5-dionato)-molybdenum
Central atom: 
Molybdenum
Attached groups: 
OSO₂CF₃ (trifluoromethanesulfonato-κO)
OC(Buᵗ)CHC(Buᵗ)O (tetramethylheptane-3,5-dionato)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Mo«V4C6OIVE14B6Z0X4L2»
[MLXZ]𝘲 class: 
[MX4L2]
MLXZ class (ENC, equivalent neutral class): 
MX4L2

cis,cis,cis–[Mo(SO₃CF₃-κO)₂(Acac)₂]

Formula Unicode styled: 
cis,cis,cis–[Mo(SO₃CF₃-κO)₂(Acac)₂]
Compound name(s): 
bis(trifluoromethanesulfonato)-bis(acetylacetonato)-molybdenum
Central atom: 
Molybdenum
Attached groups: 
OSO₂CF₃ (trifluoromethanesulfonato-κO)
Acac (acetylacetonato)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Mo«V4C6OIVE14B6Z0X4L2»
[MLXZ]𝘲 class: 
[MX4L2]
MLXZ class (ENC, equivalent neutral class): 
MX4L2

cis,cis,trans–[Mo(OPh)₂(O)₂(Bpy)]

Formula Unicode styled: 
cis,cis,trans–[Mo(OPh)₂(O)₂(Bpy)]
Compound name(s): 
bis(phenolato)-dioxo-(2,2'-bipyridine)-molybdenum
Central atom: 
Molybdenum
Attached groups: 
OPh (phenoxy)
(O)₂ (dioxo-cis X₄L Ⓢ)
Bpy (bipyridine)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Mo«V6C6OVIE18B9Z0X6L3»
[MLXZ]𝘲 class: 
[MX6L3]
MLXZ class (ENC, equivalent neutral class): 
MX6L3

cis,cis,trans–[Mo(Cl)₂(⭀NBuᵗ)₂(Dme)]

Formula Unicode styled: 
cis,cis,trans–[Mo(Cl)₂(⭀NBuᵗ)₂(Dme)]
Compound name(s): 
dichloro-bis(t-butylimido)-(1,2-bis(methoxy)ethane)-molybdenum
Central atom: 
Molybdenum
Attached groups: 
Cl (chloro)
(⭀NBuᵗ)₂ (di(⭀NBuᵗ t-butylimino)-cis X₄L Ⓢ)
Dme (dimethoxyethane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Mo«V6C6OVIE18B9Z0X6L3»
[MLXZ]𝘲 class: 
[MX6L3]
MLXZ class (ENC, equivalent neutral class): 
MX6L3

cis,cis,trans–[Mo{OC(CF₃)₃}₂(O)₂(Dme)]

Formula Unicode styled: 
cis,cis,trans–[Mo{OC(CF₃)₃}₂(O)₂(Dme)]
Compound name(s): 
(1,2-bis(methoxy)ethane)-{bis-(trifluoromethyl)propan-2-olato}-bis(oxido)-molybdenum
Central atom: 
Molybdenum
Attached groups: 
OC(CF₃)₃ (perfluorobutoxy)
(O)₂ (dioxo-cis X₄L Ⓢ)
Dme (dimethoxyethane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Mo«V6C6OVIE18B9Z0X6L3»
[MLXZ]𝘲 class: 
[MX6L3]
MLXZ class (ENC, equivalent neutral class): 
MX6L3

network–[Bi₂(μ₆-Te)₃]

Formula Unicode styled: 
network–[Bi₂(μ₆-Te)₃]
Compound name(s): 
tritellurido-dibismuth
Central atom: 
Bismuth
Attached groups: 
Te (μ₆-telluro X₂L₄)
Charge on central atom: 
0
Compound type: 
Network
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 9
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 20
Summary of calculated classifications: 
Bi«V3C9OIIIE20B9Z0X3L6»
[MLXZ]𝘲 class: 
[MX3L6]
MLXZ class (ENC, equivalent neutral class): 
MX3L6

catena–1D-trans–[Hg(μ₂-Cl)₂(NC₅H₃Me₂)₂]

Formula Unicode styled: 
catena–1D-trans–[Hg(μ₂-Cl)₂(NC₅H₃Me₂)₂]
Compound name(s): 
catena-]bis(μ₂-chloro)-bis(3,5-dimethylpyridine)-mercury]
Central atom: 
Mercury
Attached groups: 
Cl (μ₂-chloro)
NC₅H₃Me₂ (2,6-dimethylpyridine)
Charge on central atom: 
0
Compound type: 
Catena-1D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 12
Summary of calculated classifications: 
Hg«V2C6OIIE12B6Z0X2L4»
[MLXZ]𝘲 class: 
[MX2L4]
MLXZ class (ENC, equivalent neutral class): 
MX2L4

catena–2D-trans–[Hg(Cl)₂(μ₂-Diox)₂]

Formula Unicode styled: 
catena–2D-trans–[Hg(Cl)₂(μ₂-Diox)₂]
Compound name(s): 
catena-[(trans-dichloro-bis(μ₂-1,4-dioxane)-mercury]
Central atom: 
Mercury
Attached groups: 
Cl (chloro)
Diox (μ₂-dioxane)
Charge on central atom: 
0
Compound type: 
Catena-2D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 12
Summary of calculated classifications: 
Hg«V2C6OIIE12B6Z0X2L4»
[MLXZ]𝘲 class: 
[MX2L4]
MLXZ class (ENC, equivalent neutral class): 
MX2L4

catena–2D-trans–[Hg(μ₂-Br)₂{μ₂-N(CH)₄N}]

Formula Unicode styled: 
catena–2D-trans–[Hg(μ₂-Br)₂{μ₂-N(CH)₄N}]
Compound name(s): 
catena-(bis(μ₂-Bromo)-(μ₂-pyrazine-N,N')-mercury
Central atom: 
Mercury
Attached groups: 
Br (μ₂-bromo)
Pyz (μ₂-pyrazine)
Charge on central atom: 
0
Compound type: 
Catena-2D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 12
Summary of calculated classifications: 
Hg«V2C6OIIE12B6Z0X2L4»
[MLXZ]𝘲 class: 
[MX2L4]
MLXZ class (ENC, equivalent neutral class): 
MX2L4

catena–3D-[Hg(μ₂-F)₃]⊖

Formula Unicode styled: 
catena–3D-[Hg(μ₂-F)₃]⊖
Compound name(s): 
catena-3D-trifluoromercury(1-)
Central atom: 
Mercury
Attached groups: 
F (μ₂-fluoro)
Charge on central atom: 
-1
Compound type: 
Catena-3D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 12
Summary of calculated classifications: 
Hg«V2C6OIIE12B6Z0X3L3»⊖
[MLXZ]𝘲 class: 
[MX3L3]-
MLXZ class (ENC, equivalent neutral class): 
MX2L4

trans–[Mo(Cl)₂(Acac)₂]

Formula Unicode styled: 
trans–[Mo(Cl)₂(Acac)₂]
Compound name(s): 
bis(chloro)-bis(acetylacetonato)-molybdenum
Central atom: 
Molybdenum
Attached groups: 
Cl (chloro)
Acac (acetylacetonato)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Mo«V4C6OIVE14B6Z0X4L2»
[MLXZ]𝘲 class: 
[MX4L2]
MLXZ class (ENC, equivalent neutral class): 
MX4L2

catena–2D-trans–[Hg(Br)₂(μ₂-Diox)₂]

Formula Unicode styled: 
catena–2D-trans–[Hg(Br)₂(μ₂-Diox)₂]
Compound name(s): 
catena-[bis(μ-1,4-dioxane)-dibromo-mercury]
Central atom: 
Mercury
Attached groups: 
Br (bromo)
Diox (μ₂-dioxane)
Charge on central atom: 
0
Compound type: 
Catena-2D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 12
Summary of calculated classifications: 
Hg«V2C6OIIE12B6Z0X2L4»
[MLXZ]𝘲 class: 
[MX2L4]
MLXZ class (ENC, equivalent neutral class): 
MX2L4

trans–[U(Cl)₂{(O)₂}(OPCy₃)₂]

Formula Unicode styled: 
trans–[U(Cl)₂{(O)₂}(OPCy₃)₂]
Compound name(s): 
trans-Dichloro-dioxo-bis(tricyclohexylphosphine oxide)-uranium
Central atom: 
Uranium
Attached groups: 
Cl (chloro)
(O)₂ (di{oxo ⭀O X₂L} trans Ⓢ)
OPCy₃ (tricyclohexylphosphane oxide)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 20
Summary of calculated classifications: 
U«V6C6OVIE20B10Z0X6L4»
[MLXZ]𝘲 class: 
[MX6L4]
MLXZ class (ENC, equivalent neutral class): 
MX6L4

[Cs(H)]

Formula Unicode styled: 
[Cs(H)]
Compound name(s): 
caesium monohydride
hydrido-caesium
Central atom: 
Hydrogen
Attached groups: 
Cs (caesio)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (-I)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 2
Summary of calculated classifications: 
H«V1C6O-IE2B1Z0L0X1»
[MLXZ]𝘲 class: 
[MX1]
MLXZ class (ENC, equivalent neutral class): 
MX1

[Rb(H)]

Formula Unicode styled: 
[Rb(H)]
Compound name(s): 
rubidium hydride
hydrido-rubidium
Central atom: 
Hydrogen
Attached groups: 
Rb group (X type)
Charge on central atom: 
Compound type: 
Lattice
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (-I)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 0
Summary of calculated classifications: 
H«V1C6O-I»
[MLXZ]𝘲 class: 
MLXZ class (ENC, equivalent neutral class):