6-coordinate: ③-●-3 piano stool

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Os(Cl)(Acac)(η⁶-C₆H₆)]

Formula Unicode styled:

[Os(Cl)(Acac)(η⁶-C₆H₆)]

Compound name(s):

(Acetylacetonato)-(η-benzene)-chloro-osmium

Central atom:

Osmium

Attached groups:

Acac (acetylacetonato)

C₆H₆ (benzene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Os(H)(Dppe-κ²P)(Cp*)]

Formula Unicode styled:

[Os(H)(Dppe-κ²P)(Cp*)]

Compound name(s):

(1,2-bis(Diphenylphosphino)ethane)-hydrido-(η-pentamethylcyclopentadienyl)-osmium

Central atom:

Osmium

Attached groups:

H (hydrido)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[W(I)₂(NO)(Cp*)]

Formula Unicode styled:

[W(I)₂(NO)(Cp*)]

Compound name(s):

Di-iodo-(η-pentamethyl-cyclopentadienyl)-nitrosyl-tungsten

Central atom:

Attached groups:

I (iodo)

NO (nitrosyl, linear)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^IIE¹⁶B⁸X⁴L³Z¹»

[MLXZ]𝘲 class:

[MX₄L₃Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(Cl)(NO)₂(Cp)]

Formula Unicode styled:

[W(Cl)(NO)₂(Cp)]

Compound name(s):

(η-Cyclopentadienyl)-chloro-dinitrosyl-tungsten

Central atom:

Attached groups:

(NO)₂ (dinitrosyl, (N≡O)₂ cis-octahedral Ⓢ)

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^OE¹⁸B⁹X⁴L⁴Z¹»

[MLXZ]𝘲 class:

[MX₄L₄Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[W(F)(H)(Dmpe)(η⁶-C₇H₈)]

Formula Unicode styled:

[W(F)(H)(Dmpe)(η⁶-C₇H₈)]

Compound name(s):

(η-Toluene)-fluoro-hydrido-(1,2-bis(dimethylphosphino)ethane)-tungsten

Central atom:

Dmpe (1,2-bis-(dimethylphosphino)ethane)

Attached groups:

F (fluoro)

H (hydrido)

C₇H₈ (toluene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 7

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V²C⁷O^IIE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[W(Cl)(CF₃C≡CCF₃)₂(Cp)]

Formula Unicode styled:

[W(Cl)(CF₃C≡CCF₃)₂(Cp)]

Compound name(s):

Chloro-(η-cyclopentadienyl)-bis(di(trifluoromethyl)acetylene) tungsten

Central atom:

Attached groups:

CF₃C≡CCF₃ (bis(trifluoromethyl)ethyne)

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V²C⁶O^IIE¹⁶B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[W(Cl)(O)(O₂)(Cp*)]

Formula Unicode styled:

[W(Cl)(O)(O₂)(Cp*)]

Compound name(s):

Chloro-oxo-(η-pentamethyl-cyclopentadienyl)-peroxo-tungsten

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^VIE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[W(CH₂Buᵗ)₂(NO)(Cp*)]

Formula Unicode styled:

[W(CH₂Buᵗ)₂(NO)(Cp*)]

Compound name(s):

(η-Pentamethyl-cyclopentadienyl)-nitrosyl-bis(neopentyl)-tungsten

Central atom:

Attached groups:

CH₂Buᵗ (t-butylmethyl)

NO (nitrosyl, linear)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^IIE¹⁶B⁸X⁴L³Z¹»

[MLXZ]𝘲 class:

[MX₄L₃Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(CH₂SiMe₃)(=NTol)₂(Cp*)]

Formula Unicode styled:

[W(CH₂SiMe₃)(=NTol)₂(Cp*)]

Compound name(s):

(η-Pentamethyl-cyclopentadienyl)-bis(p-tolylimido)-(trimethylsilylmethyl)-tungsten

Central atom:

CH₂SiMe₃ (trimethylsilylmethyl)

Attached groups:

=NTol (tolylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^VIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(Cl)₂(⭀NBuᵗ)(Cp*)]

Formula Unicode styled:

[W(Cl)₂(⭀NBuᵗ)(Cp*)]

Compound name(s):

(t-Butylimido)-dichloro-(η-pentamethyl-cyclopentadienyl)-tungsten

Central atom:

Attached groups:

⭀NBuᵗ (⭀N t-butylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

W«V⁵C⁶O^VE¹⁷B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[W(Ph)(O)(PhC≡CPh)(Cp)]

Formula Unicode styled:

[W(Ph)(O)(PhC≡CPh)(Cp)]

Compound name(s):

Oxo-(η-cyclopentadienyl)-(etapacpow10-diphenylacetylene)-phenyl-tungsten

Central atom:

Attached groups:

Ph (phenyl)

O (oxo ⭀O X₂L)

PhC≡CPh (diphenylethyne)

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁶O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[W(Cl)(S)₂(Cp*)]

Formula Unicode styled:

[W(Cl)(S)₂(Cp*)]

Compound name(s):

chloro-dithio-(η-Pentamethyl-cyclopentadienyl)-tungsten

Central atom:

Attached groups:

S (thio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^VIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(I)(CO)₃(η⁶-C₆H₃Me₃)]⊕

Formula Unicode styled:

[W(I)(CO)₃(η⁶-C₆H₃Me₃)]⊕

Compound name(s):

Tricarbonyl-iodo-(η-mesitylene)-tungsten(1+)

Central atom:

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 7

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V²C⁷O^IIE¹⁸B⁷Z⁰X¹L⁶»^⊕

[MLXZ]𝘲 class:

[MX₁L₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[W(Cl)₃(Tp-κ³N)]⊖

Formula Unicode styled:

[W(Cl)₃(Tp-κ³N)]⊖

Compound name(s):

trichloro-(hydro-tris(pyrazolyl)-borato)-tungsten(1-)

Central atom:

Attached groups:

Tp (hydrotris(pyrazolyl)borato-κ³N)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

W«V³C⁶O^IIIE¹⁵B⁶Z⁰X⁴L²»^⊖

[MLXZ]𝘲 class:

[MX₄L₂]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[W(S)₃(Cp*)]⊖

Formula Unicode styled:

[W(S)₃(Cp*)]⊖

Compound name(s):

(η-pentamethyl-cyclopentadienyl)-trithioxo-tungsten(1-)

Central atom:

Attached groups:

S (thio)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: