5-coordinate: ③-●-2 piano stool

[Al(I)(Cp*)]₂

Formula Unicode styled: 
[Al(I)(Cp*)]₂
Compound name(s): 
bis-[iodo-(η⁵-pentamethylcyclopentadienyl)-aluminium] (Al—Al)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Al«V3C5OIIE10B5Z0X3L2»
[MLXZ]𝘲 class: 
[MX3L2]
MLXZ class (ENC, equivalent neutral class): 
MX3L2

trans–[Li₂(μ₂-C₈H₆)(Dme)₂]

Formula Unicode styled: 
trans–[Li₂(μ₂-C₈H₆)(Dme)₂]
Compound name(s): 
(μ₂-η⁵,η⁵-pentalene)-bis((dimethoxyethane)-lithium)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Li«V1C5OIE10B5Z0X1L4»
[MLXZ]𝘲 class: 
[MX1L4]
MLXZ class (ENC, equivalent neutral class): 
MX1L4

[(AlCp*){Co(CO)₃}]₂

Formula Unicode styled: 
[(AlCp*){Co(CO)₃}]₂
Compound name(s): 
bis-[(η⁵-Pentamethyl-cyclopentadienyl-aluminium)-bis(tricarbonyl-cobalt]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Al«V3C5OIIIE10B5Z0X3L2»
[MLXZ]𝘲 class: 
[MX3L2]
MLXZ class (ENC, equivalent neutral class): 
MX3L2

[Co(CO)₃(GaCp*)]₂

Formula Unicode styled: 
[Co(CO)₃(GaCp*)]₂
Compound name(s): 
bis-[(η⁵-Pentamethyl-cyclopentadienyl-gallium)-bis(tricarbonyl-cobalt]
Central atom: 
Charge on central atom: 
1
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Ga«V3C5OIIIE8B4Z0X2L2»
[MLXZ]𝘲 class: 
[MX2L2]+
MLXZ class (ENC, equivalent neutral class): 
MX3L1

trans–[Cr(μ₂-Br)(η⁵-C₅HMe₄)]₂

Formula Unicode styled: 
trans–[Cr(μ₂-Br)(η⁵-C₅HMe₄)]₂
Compound name(s): 
bis-[(μ-bromo)-(tetramethyl-cyclopentadienyl)-chromium]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Cr«V2C5OIIE14B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Ni(PEt₃)(Cp)]₂

Formula Unicode styled: 
[Ni(PEt₃)(Cp)]₂
Compound name(s): 
bis-[(η⁵-Cyclopentadienyl)-triethylphosphine-nickel]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Ni«V2C5OIE18B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Ni(μ₂-CO){η⁵-C₅H₂(Buᵗ)₃}]₂

Formula Unicode styled: 
[Ni(μ₂-CO){η⁵-C₅H₂(Buᵗ)₃}]₂
Compound name(s): 
bis-[(μ₂-Carbonyl)-(η⁵-1,2,4-tri-t-butylcyclopentadienyl)-nickel]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Ni«V2C5OIE18B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Cr(μ₂-OPh){η⁵-C₅H₂(Buᵗ)₃}]₂

Formula Unicode styled: 
[Cr(μ₂-OPh){η⁵-C₅H₂(Buᵗ)₃}]₂
Compound name(s): 
bis-[(μ₂-phenoxo)-(1,2,4-tri-t-butyl-cyclopentadienyl)-chromium]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Cr«V2C5OIIE14B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Cr(μ₂-I){η⁵-C₅H₂(Buᵗ)₃}]₂

Formula Unicode styled: 
[Cr(μ₂-I){η⁵-C₅H₂(Buᵗ)₃}]₂
Compound name(s): 
bis-[(μ₂-Iodo)-bis(η⁵-cyclopentadienyl)-chromium]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Cr«V2C5OIIE14B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Cr(μ₂-I)(Cp)]₂

Formula Unicode styled: 
[Cr(μ₂-I)(Cp)]₂
Compound name(s): 
bis-[(μ-iodo)-(1,2,4-tri-t-butyl-cyclopentadienyl)-chromium]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Cr«V2C5OIIE14B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Cr(μ₂-Br){η⁵-C₅H₂(Buᵗ)₃}]₂

Formula Unicode styled: 
[Cr(μ₂-Br){η⁵-C₅H₂(Buᵗ)₃}]₂
Compound name(s): 
bis-[(μ-bromo)-(1,2,4-tri-t-butyl-cyclopentadienyl)-chromium]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Cr«V2C5OIIE14B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Li(TMEDA-κ²N){η⁵-C₅H₄(SiMe₃)}]

Formula Unicode styled: 
[Li(TMEDA-κ²N){η⁵-C₅H₄(SiMe₃)}]
Compound name(s): 
Tetramethylethylenediamine-(η-trimethylsilyl-cyclopentadienyl)-lithium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Li«V1C5OIE10B5Z0X1L4»
[MLXZ]𝘲 class: 
[MX1L4]
MLXZ class (ENC, equivalent neutral class): 
MX1L4

[Li(TMEDA-κ²N){η⁵-C₅H₂(SiMe₃)₃}]

Formula Unicode styled: 
[Li(TMEDA-κ²N){η⁵-C₅H₂(SiMe₃)₃}]
Compound name(s): 
(η⁵-1,2,4-tris(Trimethylsilyl)cyclopentadienyl)-(tetramethylethylenediamine-N,N')-lithium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Li«V1C5OIE10B5Z0X1L4»
[MLXZ]𝘲 class: 
[MX1L4]
MLXZ class (ENC, equivalent neutral class): 
MX1L4

[Sm{N(SiMe₃)₂}₂(Cp*)]

Formula Unicode styled: 
[Sm{N(SiMe₃)₂}₂(Cp*)]
Compound name(s): 
bis(bis(Trimethylsilyl)amide)-(η⁵-pentamethyl-cyclopentadienyl)-samarium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Sm«V3C5OIIIE19B7Z0X3L4»
[MLXZ]𝘲 class: 
[MX3L4]
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[Pd(SbPh₃)₂(Cp)]⊕

Formula Unicode styled: 
[Pd(SbPh₃)₂(Cp)]⊕
Compound name(s): 
(η⁵-Cyclopentadienyl)-bis(triphenylstibine)-palladium(1+)
Central atom: 
Charge on central atom: 
1
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Pd«V2C5OIIE18B5Z0X1L4»
[MLXZ]𝘲 class: 
[MX1L4]+
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Pd(PMe₂Ph)₂(Cp)]⊕

Formula Unicode styled: 
[Pd(PMe₂Ph)₂(Cp)]⊕
Compound name(s): 
(η⁵-Cyclopentadienyl)-bis(dimethylphenylphosphine)-palladium(1+)
Central atom: 
Charge on central atom: 
1
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Pd«V2C5OIIE18B5Z0X1L4»
[MLXZ]𝘲 class: 
[MX1L4]+
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Pd(Ph)(PPh₃)(Cp)]

Formula Unicode styled: 
[Pd(Ph)(PPh₃)(Cp)]
Compound name(s): 
(η⁵-Cyclopentadienyl)-phenyl-triphenylphosphine-palladium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Pd«V2C5OIIE18B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Pd(Dppe-κ²P)(Cp)]⊕

Formula Unicode styled: 
[Pd(Dppe-κ²P)(Cp)]⊕
Compound name(s): 
(η⁵-Cyclopentadienyl)-(1,2-bis(diphenylphosphino)ethane-P,P')-palladium(1+)
Central atom: 
Charge on central atom: 
1
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Pd«V2C5OIIE18B5Z0X1L4»
[MLXZ]𝘲 class: 
[MX1L4]+
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Pd(Cp-κC)(PPrⁱ₃)(Cp)]

Formula Unicode styled: 
[Pd(Cp-κC)(PPrⁱ₃)(Cp)]
Compound name(s): 
(σ1-Cyclopentadienyl)-(η5-cyclopentadienyl)-(tris(isopropyl)phosphine)-palladium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Pd«V2C5OIIE18B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Pd(Cl)(PPrⁱ₃)(Cp*)]

Formula Unicode styled: 
[Pd(Cl)(PPrⁱ₃)(Cp*)]
Compound name(s): 
Chloro-(η⁵-pentamethylcyclopentadienyl)-tri-isopropylphosphine-palladium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Pd«V2C5OIIE18B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3