3-coordinate: trigonal plane (TP-3)

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Fe«V³C³O^IIIE¹⁷B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Fe(N)₃]⁶⊖

Formula Unicode styled:

[Fe(N)₃]⁶⊖

Compound name(s):

trinitridoiron(6-)

Central atom:

Iron

Attached groups:

N (nitrido; ≡N)

Charge on central atom:

Compound type:

Lattice

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Si(SiMe₃)₃ (tris-trimethylsilyl-silyl)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 0

Summary of calculated classifications:

Fe«V³C³O^III»

[MLXZ]𝘲 class:

MLXZ class (ENC, equivalent neutral class):

[Fe(Cl){Si(SiMe₃)₃}₂]⊖

Formula Unicode styled:

[Fe(Cl){Si(SiMe₃)₃}₂]⊖

Compound name(s):

chloro-bis(tris(trimethylsilyl)silyl)-iron(1-)

Central atom:

Iron

Attached groups:

Cl (chloro)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 12

Summary of calculated classifications:

Fe«V²C³O^IIE¹²B³Z⁰L⁰X³»^⊖

[MLXZ]𝘲 class:

[MX₃]^-

MLXZ class (ENC, equivalent neutral class):

MX₂L₁

[Ni(Cl)(PPh₃)₂]

Formula Unicode styled:

[Ni(Cl)(PPh₃)₂]

Compound name(s):

Chloro-bis(triphenylphosphine)nickel

Central atom:

Attached groups:

Cl (chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Ni«V¹C³O^IE¹⁵B³Z⁰X¹L²»

[MLXZ]𝘲 class:

[MX₁L₂]

MLXZ class (ENC, equivalent neutral class):

MX₁L₂

[Ni(MeO₂C)C≡C(CO₂Me)(PPh₃)₂]

Formula Unicode styled:

[Ni(MeO₂C)C≡C(CO₂Me)(PPh₃)₂]

Compound name(s):

(η²-Acetylenedimethyldicarboxylate)-bis(triphenylphosphine)-nickel

Central atom:

(MeO₂C)C≡C(CO₂Me) (dimethylacetylenedicarboxylate)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ni«V⁰C³O^OE¹⁶B³Z⁰X⁰L³»

[MLXZ]𝘲 class:

[ML₃]

MLXZ class (ENC, equivalent neutral class):

ML₃

[Ni(η²,η²,η²-C₁₂H₁₈)]

Formula Unicode styled:

[Ni(η²,η²,η²-C₁₂H₁₈)]

Compound name(s):

1,5,9-Cyclododecatriene-nickel

Central atom:

η²,η²,η²-C₁₂H₁₈ (η²,η²,η²-cyclododecatriene)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ni«V⁰C³O^OE¹⁶B³Z⁰X⁰L³»

[MLXZ]𝘲 class:

[ML₃]

MLXZ class (ENC, equivalent neutral class):

ML₃

[Ni(η²-C₇H₁₀)(PCy₃)₂]

Formula Unicode styled:

[Ni(η²-C₇H₁₀)(PCy₃)₂]

Compound name(s):

bis(tris(Cyclohexyl)phosphine)-(η²-1-norbornene)-nickel

Central atom:

PCy₃ (tricyclohexylphosphane)

Attached groups:

C₇H₁₀ (η²-norbornene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ni«V⁰C³O^OE¹⁶B³Z⁰X⁰L³»

[MLXZ]𝘲 class:

[ML₃]

MLXZ class (ENC, equivalent neutral class):

ML₃

[Ni(η²-Cot)(PBuᵗ₂C₂H₄PBuᵗ₂)]

Formula Unicode styled:

[Ni(η²-Cot)(PBuᵗ₂C₂H₄PBuᵗ₂)]

Compound name(s):

(η²-Cyclo-octatetraene)-(bis(di-t-butylphosphino)ethane)-nickel

Central atom:

Cot (η²-cyclooctatetraene)

Attached groups:

PBuᵗ₂C₂H₄PBuᵗ₂ (1,2-bis-(di-t-butylphosphino)ethane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ni«V⁰C³O^OE¹⁶B³Z⁰X⁰L³»

[MLXZ]𝘲 class:

[ML₃]

MLXZ class (ENC, equivalent neutral class):

ML₃

[Ni(PPh₃)₃]

Formula Unicode styled:

[Ni(PPh₃)₃]

Compound name(s):

tris(Triphenylphosphine)-nickel

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ni«V⁰C³O^OE¹⁶B³Z⁰X⁰L³»

[MLXZ]𝘲 class:

[ML₃]

MLXZ class (ENC, equivalent neutral class):

ML₃

[Ni(PPh₃)₂{OC(CF₃)₂}]

Formula Unicode styled:

[Ni(PPh₃)₂{OC(CF₃)₂}]

Compound name(s):

bis(Triphenylphosphine)hexafluoroacetone-nickel

Central atom:

Attached groups:

O=C(CF₃)₂ (hexafluoroacetone)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ni«V⁰C³O^OE¹⁶B³Z⁰X⁰L³»

[MLXZ]𝘲 class:

[ML₃]

MLXZ class (ENC, equivalent neutral class):

ML₃

[Ni(PPh₃)₂(PhNNPh)]

Formula Unicode styled:

[Ni(PPh₃)₂(PhNNPh)]

Compound name(s):

(azobenzene)-bis(triphenylphosphine)-nickel

Central atom:

Attached groups:

PhNNPh (diphenyldiazene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 4

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Ni«V⁰C⁴O^OE¹⁸B⁴Z⁰X⁰L⁴»

[MLXZ]𝘲 class:

[ML₄]

MLXZ class (ENC, equivalent neutral class):

ML₄

[Ni(PPh₃)₂(MeOCH₂C≡CCH₂OMe)]

Formula Unicode styled:

[Ni(PPh₃)₂(MeOCH₂C≡CCH₂OMe)]

Compound name(s):

(η²-(1,4-Dimethoxybut-2-yne))-bis(triphenylphosphine)-nickel

Central atom:

Attached groups:

MeOCH₂C≡CCH₂OMe (1,4-dimethoxybut-2-yne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ni«V⁰C³O^OE¹⁶B³Z⁰X⁰L³»

[MLXZ]𝘲 class:

[ML₃]

MLXZ class (ENC, equivalent neutral class):

ML₃

[Ni(PPh₃)₂(Me₃SiC≡CPh)]

Formula Unicode styled:

[Ni(PPh₃)₂(Me₃SiC≡CPh)]

Compound name(s):

(η²-Phenyl(trimethylsilyl)acetylene)-bis(triphenylphosphine)-nickel

Central atom:

Attached groups:

Me₃SiC≡CPh (trimethylsilyl-phenyl-ethyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ni«V⁰C³O^OE¹⁶B³Z⁰X⁰L³»

[MLXZ]𝘲 class:

[ML₃]

MLXZ class (ENC, equivalent neutral class):

ML₃

[Ni(PhC≡CPh)(η⁴-Cod)]

Formula Unicode styled:

[Ni(PhC≡CPh)(η⁴-Cod)]

Compound name(s):

(η⁴-Cyclo-octa-1,5-diene)-(η²-diphenylethyne)-nickel

Central atom:

Cod (η²,η²-cycloocta-1,5-diene)

Attached groups:

PhC≡CPh (diphenylethyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ni«V⁰C³O^OE¹⁶B³Z⁰X⁰L³»

[MLXZ]𝘲 class:

[ML₃]

MLXZ class (ENC, equivalent neutral class):

ML₃

[Ni(PhC≡CPh)(Dmpe)]

Formula Unicode styled:

[Ni(PhC≡CPh)(Dmpe)]

Compound name(s):

(1,2-bis(Dimethylphosphino)-ethane-P,P')-(η²-diphenylacetylene)-nickel

Central atom:

Dmpe (1,2-bis-(dimethylphosphino)ethane)

Attached groups:

PhC≡CPh (diphenylethyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ni«V⁰C³O^OE¹⁶B³Z⁰X⁰L³»

[MLXZ]𝘲 class:

[ML₃]

MLXZ class (ENC, equivalent neutral class):

ML₃

[Ni(O=CPh₂)(PEt₃)₂]

Formula Unicode styled:

[Ni(O=CPh₂)(PEt₃)₂]

Compound name(s):

(Benzophenone)-bis(triethylphosphine)-nickel

Central atom:

Attached groups:

O=CPh₂ (dibenzophenone)

PEt₃ (triethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ni«V⁰C³O^OE¹⁶B³Z⁰X⁰L³»

[MLXZ]𝘲 class:

[ML₃]

MLXZ class (ENC, equivalent neutral class):

ML₃

[Ni(NPh₂)₃]⊖

Formula Unicode styled:

[Ni(NPh₂)₃]⊖

Compound name(s):

tris(diphenylamino)-nickel(1-)

Central atom:

Attached groups:

NPh₂ (diphenylamino)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Ni«V²C³O^IIE¹⁴B³Z⁰L⁰X³»^⊖

[MLXZ]𝘲 class:

[MX₃]^-

MLXZ class (ENC, equivalent neutral class):

MX₂L₁

[Ni(Me₃SiC≡CSiMe₃)(PPh₃)₂]

Formula Unicode styled:

[Ni(Me₃SiC≡CSiMe₃)(PPh₃)₂]

Compound name(s):

(η²-bis(Trimethylsilyl)acetylene)-bis(triphenylphosphine)-nickel

Central atom:

Me₃SiC≡CSiMe₃ (bistrimethylsilylethyne)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ni«V⁰C³O^OE¹⁶B³Z⁰X⁰L³»

[MLXZ]𝘲 class:

[ML₃]

MLXZ class (ENC, equivalent neutral class):

ML₃

[Ni(Me₃SiC≡CSiMe₃)(PBuᵗ₂CH₂PBuᵗ₂)]

Formula Unicode styled:

[Ni(Me₃SiC≡CSiMe₃)(PBuᵗ₂CH₂PBuᵗ₂)]

Compound name(s):

(η²-bis(Trimethylsilyl)acetylene)-(bis(di-t-butylphosphino)methane)-nickel

Central atom:

Me₃SiC≡CSiMe₃ (bistrimethylsilylethyne)

Attached groups:

PBuᵗ₂CH₂PBuᵗ₂ (1,2-bis-(di-t-butylphosphino)methane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ni«V⁰C³O^OE¹⁶B³Z⁰X⁰L³»

[MLXZ]𝘲 class:

[ML₃]

MLXZ class (ENC, equivalent neutral class):

ML₃

[Ni(HOCH₂C≡CCH₂OH)(PPrⁱ₃)₂]

Formula Unicode styled:

[Ni(HOCH₂C≡CCH₂OH)(PPrⁱ₃)₂]

Compound name(s):

(η²-2-Butyne-1,4-diol)-bis(tri-isopropylphosphine)-nickel

Central atom:

HOCH₂C≡CCH₂OH (2-butyne-1,4-diol)

Attached groups:

PPrⁱ₃ (triisopropylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: