Technetium

Attached groups:

N (nitrido; ≡N)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁶O^VE¹⁸B⁸Z⁰X⁴L⁴»^⊕

[MLXZ]𝘲 class:

[MX₄L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Tc(Cl)(O)(OCH₂CH₂O)(Phen)]⊕

Formula Unicode styled:

[Tc(Cl)(O)(OCH₂CH₂O)(Phen)]⊕

Compound name(s):

Chloro-(1,2-ethanediolato-O,O')-oxo-(1,10-phenanthroline-N,N')-technetium(1+)

Central atom:

Attached groups:

OCH₂CH₂O (ethanediolato-κO,κO)

O (oxo ⭀O X₂L)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁶C⁶O^VIE¹⁷B⁸Z⁰X⁵L³»^⊕

[MLXZ]𝘲 class:

[MX₅L₃]⁺

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Tc(S₂C₆H₄-κ²S)₃]⊖

Formula Unicode styled:

[Tc(S₂C₆H₄-κ²S)₃]⊖

Compound name(s):

tris(benzene-1,2-dithiolato-S,S')-technetium(1-)

Central atom:

S₂C₆H₄ (benzene-1,2-dithiolato-κ²S)

Attached groups:

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Tc«V⁵C⁶O^VE¹⁴B⁶Z⁰L⁰X⁶»^⊖

[MLXZ]𝘲 class:

[MX₆]^-

MLXZ class (ENC, equivalent neutral class):

MX₅L₁

[Tc(Dppe-κ²P)₂(Dmdtc)]⊕

Formula Unicode styled:

[Tc(Dppe-κ²P)₂(Dmdtc)]⊕

Compound name(s):

bis(1,2-bis(Diphenylphosphino)ethane-P,P')-(N,N-dimethyldithiocarbamato-S,S')-technetium(1+)

Central atom:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Attached groups:

Dmdtc (dimethyldithiocarbamato-κ²S)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V²C⁶O^IIE¹⁷B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Tc(Depe)₂(Dmdtc)]⊕

Formula Unicode styled:

[Tc(Depe)₂(Dmdtc)]⊕

Compound name(s):

bis(1,2-bis(Diethylphosphino)ethane)-(dimethyldithiocarbamato)-technetium(1+)

Central atom:

Depe (1,2-bis-(diethylphosphino)ethane)

Attached groups:

Dmdtc (dimethyldithiocarbamato-κ²S)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V²C⁶O^IIE¹⁷B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Tc(Bpy)₃]²⊕

Formula Unicode styled:

[Tc(Bpy)₃]²⊕

Compound name(s):

tris(2,2-Bipyridyl)-technetium(2+)

Central atom:

Attached groups:

Bpy (bipyridine)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V²C⁶O^IIE¹⁷B⁶Z⁰X⁰L⁶»^2⊕

[MLXZ]𝘲 class:

[ML₆]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Tc(Acac)₃]

Formula Unicode styled:

[Tc(Acac)₃]

Compound name(s):

tris(Acetylacetonato-O,O')-technetium

Central atom:

Attached groups:

Acac (acetylacetonato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Tc«V³C⁶O^IIIE¹⁶B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis–[Tc(Br)(N)(Bpy)₂]⊕

Formula Unicode styled:

cis,cis–[Tc(Br)(N)(Bpy)₂]⊕

Compound name(s):

bis(cis-bis(2,2'-Bipyridyl)-bromo-nitrido-technetium(v)) tetrabromo-technetium(1+)

Central atom:

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁶O^VE¹⁸B⁸Z⁰X⁴L⁴»^⊕

[MLXZ]𝘲 class:

[MX₄L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

cis–[Tc(μ₂-I)(CO)₄]₂

Formula Unicode styled:

cis–[Tc(μ₂-I)(CO)₄]₂

Compound name(s):

bis(μ₂-Iodo)-bis(tetracarbonyl-technetium)

Central atom:

Attached groups:

I (μ₂-iodo)

CO (carbonyl)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V¹C⁶O^IE¹⁸B⁶Z⁰X¹L⁵»

[MLXZ]𝘲 class:

[MX₁L₅]

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

catena–3D-cis–[Tc(F)₂(μ₂-F)(O)₂]

Formula Unicode styled:

catena–3D-cis–[Tc(F)₂(μ₂-F)(O)₂]

Compound name(s):

catena-dioxo-trifluoro-technetium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Catena-3D

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 7

Oxidation Number (ON) (Roman numerals):

ON: (VII)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Tc«V⁷C⁶O^VIIE¹⁶B⁸Z⁰X⁷L¹»

[MLXZ]𝘲 class:

[MX₇L₁]

MLXZ class (ENC, equivalent neutral class):

MX₇L₁

catena–2D-cis–[Tc(F)(SbF₆)(O)₂(μ₂-F)]

Formula Unicode styled:

catena–2D-cis–[Tc(F)(SbF₆)(O)₂(μ₂-F)]

Compound name(s):

di-fluoro-hexafluoroantimonato-di-oxo-technetium

Central atom:

FSbF₅ (hexafluoroantimonato)

Attached groups:

F (fluoro)

O (oxo X₂)

F (μ₂-fluoro)

Charge on central atom:

1

Compound type:

Catena-2D

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 7

Oxidation Number (ON) (Roman numerals):

ON: (VII)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Tc«V⁷C⁶O^VIIE¹⁶B⁸Z⁰X⁶L²»^⊕

[MLXZ]𝘲 class:

[MX₆L₂]⁺

MLXZ class (ENC, equivalent neutral class):

MX₇L₁

cis–[Tc(Cl)₄(Thf)₂]

Formula Unicode styled:

cis–[Tc(Cl)₄(Thf)₂]

Compound name(s):

Tetrachloro-bis(tetrahydrofuran)-technetium

Central atom:

Attached groups:

Thf (tetrahydrofuran)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁴C⁶O^IVE¹⁵B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

cis–[Tc(Cl)₄(PPh₃)₂]

Formula Unicode styled:

cis–[Tc(Cl)₄(PPh₃)₂]

Compound name(s):

Tetrachloro-bis(triphenylphosphine oxide)-technetium

Central atom:

Attached groups:

PPh₃ (triphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁴C⁶O^IVE¹⁵B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

cis–[Tc(Cl)₄(OH₂)₂]

Formula Unicode styled:

cis–[Tc(Cl)₄(OH₂)₂]

Compound name(s):

Diaquatetrachlorotechnetium

Central atom:

Attached groups:

OH₂ (aqua)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁴C⁶O^IVE¹⁵B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

cis–[Tc(Cl)₄(NCMe)₂]

Formula Unicode styled:

cis–[Tc(Cl)₄(NCMe)₂]

Compound name(s):

bis(acetonitrile)-tetrachloro-technetium

Central atom:

Attached groups:

NCMe (acetonitrile)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁴C⁶O^IVE¹⁵B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

cis–[Tc(Cl)(NS)(Phen)₂]⊕

Formula Unicode styled:

cis–[Tc(Cl)(NS)(Phen)₂]⊕

Compound name(s):

Chloro-bis(1,10-phenanthroline)-thionitrosyl-technetium(1+)

Central atom:

Attached groups:

NS (thionitrosyl, linear)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁶O^IE¹⁸B⁸X²L⁵Z¹»^⊕

[MLXZ]𝘲 class:

[MX₂L₅Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

cis–[Tc(PMe₂Ph)(Dedtc)₂(N)]

Formula Unicode styled:

cis–[Tc(PMe₂Ph)(Dedtc)₂(N)]

Compound name(s):

bis(N,N-Diethyldithiocarbamato-S,S')-(dimethylphenylphosphine)-nitrido-technetium

Central atom:

PMe₂Ph (dimethylphenylphosphane)

Attached groups:

Dedtc (diethyldithiocarbamato-κ²S)

N (nitrido; ≡N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁶O^VE¹⁸B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

cis–[Tc(NH₃)(NO)(Phen)₂]²⊕

Formula Unicode styled:

cis–[Tc(NH₃)(NO)(Phen)₂]²⊕

Compound name(s):

Ammine-nitrosyl-bis(1,10-phenanthroline)-technetium(2+)

Central atom:

Attached groups:

NH₃ (ammine)

NO (nitrosyl, linear)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁶O^IE¹⁸B⁸X¹L⁶Z¹»^2⊕

[MLXZ]𝘲 class:

[MX₁L₆Z₁]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

cis–[Tc(CO)₂{PPh(OEt)₂}₄]⊕

Formula Unicode styled:

cis–[Tc(CO)₂{PPh(OEt)₂}₄]⊕

Compound name(s):

Dicarbonyl-tetrakis(diethyl-phenyl-phosphonite) technetium(1+)

Central atom:

PPh(OEt)₂ (diethyl-phenyl-phosphonito)

Attached groups:

CO (carbonyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V¹C⁶O^IE¹⁸B⁶Z⁰X⁰L⁶»^⊕

[MLXZ]𝘲 class:

[ML₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

cis–[Tc(CNBuᵗ)₄(Bpy)]⊕

Formula Unicode styled:

cis–[Tc(CNBuᵗ)₄(Bpy)]⊕

Compound name(s):

(2,2'-Bipyridyl)-tetrakis(t-butylisocyanido)-technetium(1+)

Central atom:

CNBuᵗ (t-butyl isocyanide)

Attached groups:

Bpy (bipyridine)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: