Rhodium

mer–[Rh(C₆Cl₅)₃(CNBuᵗ)₃]

Formula Unicode styled: 
mer–[Rh(C₆Cl₅)₃(CNBuᵗ)₃]
Compound name(s): 
tris(t-butylisocyano)-tris(pentachlorophenyl)-rhodium
Central atom: 
Rhodium
Attached groups: 
C₆Cl₅ (pentachlorophenyl)
CNBuᵗ (t-butyl isocyanide)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

mer–[Rh(Br)₃(Cl)(CO)(PPh₃)]

Formula Unicode styled: 
mer–[Rh(Br)₃(Cl)(CO)(PPh₃)]
Compound name(s): 
tribromo-carbonyl-chloro-triphenylphosphine-rhodium
Central atom: 
Rhodium
Attached groups: 
Br (bromo)
Cl (chloro)
CO (carbonyl)
PPh₃ (triphenylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 17
Summary of calculated classifications: 
Rh«V4C6OIVE17B6Z0X4L2»
[MLXZ]𝘲 class: 
[MX4L2]
MLXZ class (ENC, equivalent neutral class): 
MX4L2

fac–[Rh(μ₂-O₂CMe)(NCMe)₃]₂²⊕

Formula Unicode styled: 
fac–[Rh(μ₂-O₂CMe)(NCMe)₃]₂²⊕
Compound name(s): 
bis-[(μ₂-Acetato-O,O')-tris(acetonitrile-N)-rhodium(1+)]
Central atom: 
Rhodium
Attached groups: 
O₂CMe (μ₂-acetato)
NCMe (acetonitrile)
Charge on central atom: 
1
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIE18B6Z0X2L4»⊕
[MLXZ]𝘲 class: 
[MX2L4]+
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(Tp-κ³N)([9]aneS₃-κ³S)]²⊕

Formula Unicode styled: 
fac–[Rh(Tp-κ³N)([9]aneS₃-κ³S)]²⊕
Compound name(s): 
(Hydrotris(pyrazolyl)borato)-(1,4,7-trithiacyclononane)-rhodium(2+)
Central atom: 
Rhodium
Attached groups: 
Tp (hydrotris(pyrazolyl)borato-κ³N)
[9]aneS₃ (1,4,7-trithiocyclononane-κ³S)
Charge on central atom: 
2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X1L5»2⊕
[MLXZ]𝘲 class: 
[MX1L5]2+
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(Ph)₃([9]aneN₃-κ³N)]

Formula Unicode styled: 
fac–[Rh(Ph)₃([9]aneN₃-κ³N)]
Compound name(s): 
(1,4,7-Triazacyclononane)-triphenyl-rhodium
Central atom: 
Rhodium
Attached groups: 
Ph (phenyl)
[9]aneN₃ (1,4,7-triazacyclononane-κ³N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(ONO₂-κO)(Bpy)([9]aneN₃-κ³N)]²⊕

Formula Unicode styled: 
fac–[Rh(ONO₂-κO)(Bpy)([9]aneN₃-κ³N)]²⊕
Compound name(s): 
(1,4,7-Triazacyclononane)-(2,2'-bipyridyl)-(nitrato-O)-rhodium(2+)
Central atom: 
Rhodium
Attached groups: 
NO₃ (nitrato-κO)
Bpy (bipyridine)
[9]aneN₃ (1,4,7-triazacyclononane-κ³N)
Charge on central atom: 
2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X1L5»2⊕
[MLXZ]𝘲 class: 
[MX1L5]2+
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(Me)₃(PMe₃)₃]

Formula Unicode styled: 
fac–[Rh(Me)₃(PMe₃)₃]
Compound name(s): 
Trimethyl-tris(trimethylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
Me (methyl)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(Me)₂(NCMe)([9]aneN₃-1,4,7-Me₃-κ³N)]⊕

Formula Unicode styled: 
fac–[Rh(Me)₂(NCMe)([9]aneN₃-1,4,7-Me₃-κ³N)]⊕
Compound name(s): 
(Acetonitrile-kappaN)-dimethyl-(1,4,7-trimethyl-1,4,7-triazacyclononane-κ3N)- rhodium(1+)
Central atom: 
Rhodium
Attached groups: 
Me (methyl)
NCMe (acetonitrile)
[9]aneN₃-1,4,7-Me₃ (1,4,7-trimethyl-1,4,7-triazacyclononane-κ³N)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X2L4»⊕
[MLXZ]𝘲 class: 
[MX2L4]+
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(Me)(NCMe)₂([9]aneN₃-1,4,7-Me₃-κ³N)]²⊕

Formula Unicode styled: 
fac–[Rh(Me)(NCMe)₂([9]aneN₃-1,4,7-Me₃-κ³N)]²⊕
Compound name(s): 
bis(Acetonitrile)-(1,4,7-trimethyl-1,4,7-triazacyclononane)-methyl-rhodium(2+)
Central atom: 
Rhodium
Attached groups: 
Me (methyl)
NCMe (acetonitrile)
[9]aneN₃-1,4,7-Me₃ (1,4,7-trimethyl-1,4,7-triazacyclononane-κ³N)
Charge on central atom: 
2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X1L5»2⊕
[MLXZ]𝘲 class: 
[MX1L5]2+
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(Me)(Dmso-κO)₂([9]aneN₃-1,4,7-Me₃-κ³N)]²⊕

Formula Unicode styled: 
fac–[Rh(Me)(Dmso-κO)₂([9]aneN₃-1,4,7-Me₃-κ³N)]²⊕
Compound name(s): 
bis(Dimethylsulfoxide-O)-(1,4,7-trimethyl-1,4,7-triazacyclononane)-methyl-rhodium(2+)
Central atom: 
Rhodium
Attached groups: 
Me (methyl)
Dmso (dimethylsulfoxide-κO)
[9]aneN₃-1,4,7-Me₃ (1,4,7-trimethyl-1,4,7-triazacyclononane-κ³N)
Charge on central atom: 
2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X1L5»2⊕
[MLXZ]𝘲 class: 
[MX1L5]2+
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(I)₃(NCMe)(Dppm-κ²P)]

Formula Unicode styled: 
fac–[Rh(I)₃(NCMe)(Dppm-κ²P)]
Compound name(s): 
Acetonitrile-tri-iodo-(bis(diphenylphosphino)methane-P,P')-rhodium
Central atom: 
Rhodium
Attached groups: 
I (iodo)
NCMe (acetonitrile)
Dppm (bis-(diphenylphosphino)methane-κ²P)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(I)₂(PPh₃)([9]aneS₃-κ³S)]⊕

Formula Unicode styled: 
fac–[Rh(I)₂(PPh₃)([9]aneS₃-κ³S)]⊕
Compound name(s): 
Di-iodo-(1,4,9-trithiacyclononane)-triphenylphosphine-rhodium(1+)
Central atom: 
Rhodium
Attached groups: 
I (iodo)
PPh₃ (triphenylphosphane)
[9]aneS₃ (1,4,7-trithiocyclononane-κ³S)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X2L4»⊕
[MLXZ]𝘲 class: 
[MX2L4]+
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(I)(Me)(PPh₃)(Tp-κ³N)]

Formula Unicode styled: 
fac–[Rh(I)(Me)(PPh₃)(Tp-κ³N)]
Compound name(s): 
(Hydrogen-trispyrazolylborato)-iodo-methyl-triphenylphosphine-rhodium
Central atom: 
Rhodium
Attached groups: 
I (iodo)
Me (methyl)
PPh₃ (triphenylphosphane)
Tp (hydrotris(pyrazolyl)borato-κ³N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(H)₂(SiPh₃)(PEt₃)₃]

Formula Unicode styled: 
fac–[Rh(H)₂(SiPh₃)(PEt₃)₃]
Compound name(s): 
tris(Triethylphosphine)-(triphenylsilyl)-dihydrido-rhodium
Central atom: 
Rhodium
Attached groups: 
H (hydrido)
SiPh₃ (triphenylsilyl)
PEt₃ (triethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(H)(Me)(PMe₃)([9]aneN₃-1,4,7-Me₃-κ³N)]²⊕

Formula Unicode styled: 
fac–[Rh(H)(Me)(PMe₃)([9]aneN₃-1,4,7-Me₃-κ³N)]²⊕
Compound name(s): 
(1,4,7-Trimethyl-1,4,7-triazacyclononane)-hydrido-methyl-trimethylphosphine-rhodium(2+)
Central atom: 
Rhodium
Attached groups: 
H (hydrido)
Me (methyl)
PMe₃ (trimethylphosphane)
[9]aneN₃-1,4,7-Me₃ (1,4,7-trimethyl-1,4,7-triazacyclononane-κ³N)
Charge on central atom: 
2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 17
Summary of calculated classifications: 
Rh«V4C6OIVE17B6Z0X2L4»2⊕
[MLXZ]𝘲 class: 
[MX2L4]2+
MLXZ class (ENC, equivalent neutral class): 
MX4L2

fac–[Rh(Et)₃([9]aneN₃-κ³N)]

Formula Unicode styled: 
fac–[Rh(Et)₃([9]aneN₃-κ³N)]
Compound name(s): 
(1,4,7-Triazacyclononane)-triethyl-rhodium
Central atom: 
Rhodium
Attached groups: 
Et (ethyl)
[9]aneN₃ (1,4,7-triazacyclononane-κ³N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(Et)(Ph)(CO)(Tp*-κ³N)]

Formula Unicode styled: 
fac–[Rh(Et)(Ph)(CO)(Tp*-κ³N)]
Compound name(s): 
Carbonyl-ethyl-phenyl-(tris(3,5-dimethylpyrazolyl)hydroborate-N,N',N'')-rhodium
Central atom: 
Rhodium
Attached groups: 
Et (ethyl)
Ph (phenyl)
CO (carbonyl)
Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(COMe)(I)(PMe₃)(Tp*-κ³N)]

Formula Unicode styled: 
fac–[Rh(COMe)(I)(PMe₃)(Tp*-κ³N)]
Compound name(s): 
(Hydrogen-tris(3,5-dimethylpyrazolyl)borate)-iodo-acetyl-trimethylphosphine-rhodium
Central atom: 
Rhodium
Attached groups: 
COMe (acetyl)
I (iodo)
PMe₃ (trimethylphosphane)
Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C6OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

fac–[Rh(CO)(PPh₃)(Tp*-κ³N)]⊕

Formula Unicode styled: 
fac–[Rh(CO)(PPh₃)(Tp*-κ³N)]⊕
Compound name(s): 
(Hydrogen-tris(3,5-dimethylpyrazolyl)borato-N,N',N'')-carbonyl-triphenylphosphine-rhodium(1+)
Central atom: 
Rhodium
Attached groups: 
CO (carbonyl)
PPh₃ (triphenylphosphane)
Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 17
Summary of calculated classifications: 
Rh«V2C5OIIE17B5Z0X1L4»⊕
[MLXZ]𝘲 class: 
[MX1L4]+
MLXZ class (ENC, equivalent neutral class): 
MX2L3

fac–[Rh(CO)(PPh₃)(Tp*-κ³N)]

Formula Unicode styled: 
fac–[Rh(CO)(PPh₃)(Tp*-κ³N)]
Compound name(s): 
(Hydrogen-tris(3,5-dimethylpyrazolyl)borato-N,N',N'')-carbonyl-triphenylphosphine-rhodium
Central atom: 
Rhodium
Attached groups: 
CO (carbonyl)
PPh₃ (triphenylphosphane)
Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V1C5OIE18B5Z0X1L4»
[MLXZ]𝘲 class: 
[MX1L4]
MLXZ class (ENC, equivalent neutral class): 
MX1L4