Rhenium

S₄ (tetrasulfanediyl-κ²S)

Attached groups:

S (thio; ⭀S)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Re«V⁵C⁵O^VE¹⁶B⁷Z⁰X⁶L¹»^⊖

[MLXZ]𝘲 class:

[MX₆L₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Re(S₃)(S₄)(Cp*)]

Formula Unicode styled:

[Re(S₃)(S₄)(Cp*)]

Compound name(s):

(eta-Pentamethyl-cylcopentadienyl)-(tetrasulfido-S,S')-(trisulfido-S,S')-rhenium

Central atom:

S₄ (tetrasulfanediyl-κ²S)

Attached groups:

S₃ (trisulfanediyl-κ²S)

Cp* (η⁵-pentamethylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 7

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Re«V⁵C⁷O^VE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Re(PPh₃)(S₂CPh)₃]

Formula Unicode styled:

[Re(PPh₃)(S₂CPh)₃]

Compound name(s):

tris(Dithiobenzoato)-triphenylphosphine-rhenium

Central atom:

PPh₃ (triphenylphosphane)

Attached groups:

S₂CPh (dithiobenzoato-κ²S)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 7

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V³C⁷O^IIIE¹⁸B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Re(PPh₂)(⭀NBuᵗ)₃]

Formula Unicode styled:

[Re(PPh₂)(⭀NBuᵗ)₃]

Compound name(s):

tris(t-Butylimido)-(diphenylphosphido)-rhenium

Central atom:

PPh₂ (diphenylphosphanyl)

Attached groups:

(⭀NBuᵗ)₃ (tri(⭀NBuᵗ t-butylimino) Ⓢ)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁷C⁴O^VIIE¹⁸B⁹Z⁰X⁷L²»

[MLXZ]𝘲 class:

[MX₇L₂]

MLXZ class (ENC, equivalent neutral class):

MX₇L₂

[Re(OSiMe₃){(O)₃}]

Formula Unicode styled:

[Re(OSiMe₃){(O)₃}]

Compound name(s):

(Trimethylsiloxy)-trioxo-rhenium

Central atom:

Attached groups:

OSiMe₃ (trimethylsiloxy)

(O)₃ (trioxo X₆L₂ Ⓢ)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁷C⁴O^VIIE¹⁸B⁹Z⁰X⁷L²»

[MLXZ]𝘲 class:

[MX₇L₂]

MLXZ class (ENC, equivalent neutral class):

MX₇L₂

[Re(OSiMe₃)(MeC≡CMe)₃]

Formula Unicode styled:

[Re(OSiMe₃)(MeC≡CMe)₃]

Compound name(s):

tris(But-2-yne)-(trimethylsilyloxy)-rhenium

Central atom:

(MeC≡CMe)₃ (tris-(dimethylethyne) Ⓢ)

Attached groups:

OSiMe₃ (trimethylsiloxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V¹C⁴O^IE¹⁸B⁶Z⁰X¹L⁵»

[MLXZ]𝘲 class:

[MX₁L₅]

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

[Re(OSiBuᵗ₃)₃(CO)]

Formula Unicode styled:

[Re(OSiBuᵗ₃)₃(CO)]

Compound name(s):

Carbonyl-tris(tri-t-butylsiloxy)-rhenium

Central atom:

OSiBuᵗ₃ (tri-t-butylsiloxy)

Attached groups:

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 12

Summary of calculated classifications:

Re«V³C⁴O^IIIE¹²B⁴Z⁰X³L¹»

[MLXZ]𝘲 class:

[MX₃L₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

[Re(OPh)(O)(MeC≡CMe)₂]

Formula Unicode styled:

[Re(OPh)(O)(MeC≡CMe)₂]

Compound name(s):

bis(dimethylacetylene)-oxo-phenoxy-rhenium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V³C⁴O^IIIE¹⁸B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Re(ONO-κO)(CO)₃(Bpy)]

Formula Unicode styled:

[Re(ONO-κO)(CO)₃(Bpy)]

Compound name(s):

(2,2'-bipyridine)-tricarbonyl-nitrito-rhenium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Summary of calculated classifications:

Re«V¹C⁶O^IE¹⁸B⁶Z⁰X¹L⁵»

[MLXZ]𝘲 class:

[MX₁L₅]

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

[Re(OMe)(Ox)(O)(Dppe-κ²P)]

Formula Unicode styled:

[Re(OMe)(Ox)(O)(Dppe-κ²P)]

Compound name(s):

(1,2-bis(Diphenylphosphino)ethane)-methoxy-(oxalato-O,O')-oxo-rhenium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁶O^VE¹⁸B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Re(OMe)(Ox)(O)(Bpy)]

Formula Unicode styled:

[Re(OMe)(Ox)(O)(Bpy)]

Compound name(s):

(2,2'-Bipyridyl)-methoxy-(oxalato-O,O')-oxo-rhenium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁶O^VE¹⁸B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Re(OMe)(CO)₃(Bpy)]

Formula Unicode styled:

[Re(OMe)(CO)₃(Bpy)]

Compound name(s):

(2,2'-Bipyridyl)-methoxy-tricarbonyl-rhenium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V¹C⁶O^IE¹⁸B⁶Z⁰X¹L⁵»

[MLXZ]𝘲 class:

[MX₁L₅]

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

[Re(OH){(O)₃}]

Formula Unicode styled:

[Re(OH){(O)₃}]

Compound name(s):

perrhenate(vii) acid

Central atom:

Attached groups:

OH (hydroxo)

(O)₃ (trioxo X₆L₂ Ⓢ)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁷C⁴O^VIIE¹⁸B⁹Z⁰X⁷L²»

[MLXZ]𝘲 class:

[MX₇L₂]

MLXZ class (ENC, equivalent neutral class):

MX₇L₂

[Re(OH)(EtC≡CEt)₃]

Formula Unicode styled:

[Re(OH)(EtC≡CEt)₃]

Compound name(s):

Hydroxy-tris(etapesdas-hex-3-yne)-rhenium

Central atom:

(EtC≡CEt)₃ (tris-(diethylethyne) Ⓢ)

Attached groups:

OH (hydroxo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V¹C⁴O^IE¹⁸B⁶Z⁰X¹L⁵»

[MLXZ]𝘲 class:

[MX₁L₅]

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

[Re(ClO₄-κO)(CO)₅]

Formula Unicode styled:

[Re(ClO₄-κO)(CO)₅]

Compound name(s):

Pentacarbonyl-(perchlorato)-rhenium

Central atom:

Attached groups:

ClO₄ (perchlorato-κO)

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V¹C⁶O^IE¹⁸B⁶Z⁰X¹L⁵»

[MLXZ]𝘲 class:

[MX₁L₅]

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

[Re(O₂CH₆H₄)₂(O)]⊖

Formula Unicode styled:

[Re(O₂C₆H₄)₂(O)]⊖

Compound name(s):

bis(catecholato-O,O')-oxo-rhenium(1-)

Central atom:

O₂C₆H₄-o (catecholato-κ²O)

Attached groups:

O (oxo ⭀O X₂L)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Re«V⁵C⁵O^VE¹⁶B⁷Z⁰X⁶L¹»^⊖

[MLXZ]𝘲 class:

[MX₆L₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Re(NMes₂){(O)₃}]

Formula Unicode styled:

[Re(NMes₂){(O)₃}]

Compound name(s):

bis(2,4,6-Trimethylphenyl)amido-trioxo-rhenium

Central atom:

Attached groups:

NMes₂ (dimesitylamino)

(O)₃ (trioxo X₆L₂ Ⓢ)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁷C⁴O^VIIE¹⁸B⁹Z⁰X⁷L²»

[MLXZ]𝘲 class:

[MX₇L₂]

MLXZ class (ENC, equivalent neutral class):

MX₇L₂

[Re(NHPh)(PMe₃)₃(η⁴-C₄H₆)]

Formula Unicode styled:

[Re(NHPh)(PMe₃)₃(η⁴-C₄H₆)]

Compound name(s):

Phenylamido-(eta-buta-1,3-diene)-tris(trimethylphosphine)-rhenium

Central atom:

PMe₃ (trimethylphosphane)

Attached groups:

NHPh (phenylamino)

C₄H₆ (η⁴-butadiene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V¹C⁶O^IE¹⁸B⁶Z⁰X¹L⁵»

[MLXZ]𝘲 class:

[MX₁L₅]

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

[Re(NEt₂H)₂(η³-C₃H₅)(Cp*)]⊕

Formula Unicode styled:

[Re(NEt₂H)₂(η³-C₃H₅)(Cp*)]⊕

Compound name(s):

endo-(eta-Pentamethyl-cyclopentadienyl)-(eta-allyl)-bis(ethylamino)-rhenium(1+)

Central atom:

Cp* (η⁵-pentamethylcyclopentadienyl)

Attached groups:

NEt₂H (diethylamine)

C₃H₅ (η³-allyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 7

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V³C⁷O^IIIE¹⁸B⁷Z⁰X²L⁵»^⊕

[MLXZ]𝘲 class:

[MX₂L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Re(NCS-κN)₆]²⊖

Formula Unicode styled:

[Re(NCS-κN)₆]²⊖

Compound name(s):

hexakis(isothiocyanato)-rhenium(2-)

Central atom:

Attached groups:

NCS (isothiocyanato-κN)

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):