Rhenium

Attached groups:

CO (carbonyl)

SMe₂ (dimethylthioether)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁶O^IE¹⁸B⁸X²L⁵Z¹»^⊕

[MLXZ]𝘲 class:

[MX₂L₅Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Re(CO)(Dedtc)₃]

Formula Unicode styled:

[Re(CO)(Dedtc)₃]

Compound name(s):

Carbonyl-tris(N,N-diethyldithiocarbamato)-rhenium

Central atom:

Dedtc (diethyldithiocarbamato-κ²S)

Attached groups:

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 7

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V³C⁷O^IIIE¹⁸B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Re(CNPh)(CO)₅]⊕

Formula Unicode styled:

[Re(CNPh)(CO)₅]⊕

Compound name(s):

Pentacarbonyl-phenylisocyano-rhenium(1+)

Central atom:

Attached groups:

CNPh (phenyl isocyanide)

CO (carbonyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V¹C⁶O^IE¹⁸B⁶Z⁰X⁰L⁶»^⊕

[MLXZ]𝘲 class:

[ML₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

[Re(CN)₅(N)]⊖

Formula Unicode styled:

[Re(CN)₅(N)]⊖

Compound name(s):

pentacyanonitrido-rhenium(1-)

Central atom:

Attached groups:

CN (cyano-κC)

N (nitrido; ≡N)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (VII)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁷C⁶O^VIIE¹⁶B⁸Z⁰L⁰X⁸»^⊖

[MLXZ]𝘲 class:

[MX₈]^-

MLXZ class (ENC, equivalent neutral class):

MX₇L₁

[Re(CHO)(PPh₃)(NO)(Cp)]

Formula Unicode styled:

[Re(CHO)(PPh₃)(NO)(Cp)]

Compound name(s):

(η⁵-Cyclopentadienyl)-formyl-nitrosyl-triphenylphosphine-rhenium

Central atom:

Attached groups:

CHO (formyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁶O^IE¹⁸B⁸X³L⁴Z¹»

[MLXZ]𝘲 class:

[MX₃L₄Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Re(CHMe=CHMe)(PPh₃)(NO)(Cp)]⊕

Formula Unicode styled:

[Re(CHMe=CHMe)(PPh₃)(NO)(Cp)]⊕

Compound name(s):

(η²-2-Butene-Z)-(η⁵-cyclopentadienyl)-nitroso-triphenylphosphine-rhenium(1+)

Central atom:

Attached groups:

CHMe=CHMe (but-2-ene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁶O^IE¹⁸B⁸X²L⁵Z¹»^⊕

[MLXZ]𝘲 class:

[MX₂L₅Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Re(CHMe=CHMe)(PPh₃)(NO)(Cp)]⊕

Formula Unicode styled:

[Re(CHMe=CHMe)(PPh₃)(NO)(Cp)]⊕

Compound name(s):

(η²-2-Butene-E)-(η⁵-cyclopentadienyl)-nitroso-triphenylphosphine-rhenium(1+)

Central atom:

Attached groups:

CHMe=CHMe (but-2-ene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁶O^IE¹⁸B⁸X²L⁵Z¹»^⊕

[MLXZ]𝘲 class:

[MX₂L₅Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Re(CH₂SiMe₃)₃(O)(PMe₃)]

Formula Unicode styled:

[Re(CH₂SiMe₃)₃(O)(PMe₃)]

Compound name(s):

Trimethylphosphine-oxo-tris(trimethylsilylmethyl)-rhenium

Central atom:

CH₂SiMe₃ (trimethylsilylmethyl)

Attached groups:

O (oxo ⭀O X₂L)

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁵O^VE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Re(CH₂SiMe₃)₃(O)(PMe₂Ph)]

Formula Unicode styled:

[Re(CH₂SiMe₃)₃(O)(PMe₂Ph)]

Compound name(s):

(Dimethylphenylphosphine)-oxo-tris(trimethylsilylmethyl)-rhenium

Central atom:

CH₂SiMe₃ (trimethylsilylmethyl)

Attached groups:

O (oxo ⭀O X₂L)

PMe₂Ph (dimethylphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁵O^VE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Re(⭀NBuᵗ)₃(NH₂Buᵗ)]⊕

Formula Unicode styled:

[Re(⭀NBuᵗ)₃(NH₂Buᵗ)]⊕

Compound name(s):

tris(t-Butylimido)-(t-butylamine)-rhenium(1+)

Central atom:

(⭀NBuᵗ)₃ (tri(⭀NBuᵗ t-butylimino) Ⓢ)

Attached groups:

NH₂Buᵗ (t-butylamine)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (VII)

Coordination Number (CN, sum of attached group denticities):

CN: 4

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁷C⁴O^VIIE¹⁸B⁹Z⁰X⁶L³»^⊕

[MLXZ]𝘲 class:

[MX₆L₃]⁺

MLXZ class (ENC, equivalent neutral class):

MX₇L₂

[Re(=CHPh)(PPh₃)(NO)(Cp)]⊕

Formula Unicode styled:

[Re(=CHPh)(PPh₃)(NO)(Cp)]⊕

Compound name(s):

Benzylidene-(η⁵-cyclopentadienyl)-nitroso-triphenylphosphine-rhenium(1+)

Central atom:

Attached groups:

=CHPh (benzylidene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁷C⁶O^IIIE¹⁸B⁹X⁴L⁴Z¹»^⊕

[MLXZ]𝘲 class:

[MX₄L₄Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₇L₂

[Re(=CH₂){P(OPh)₃}(NO)(Cp*)]⊕

Formula Unicode styled:

[Re(=CH₂){P(OPh)₃}(NO)(Cp*)]⊕

Compound name(s):

(η⁵-Pentamethyl-cyclopentadienyl)-methylidene-nitrosyl-triphenylphosphito-rhenium(1+)

Central atom:

P(OPh)₃ (triphenylphosphite)

Attached groups:

=CH₂ (methylidene)

Cp* (η⁵-pentamethylcyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁷C⁶O^IIIE¹⁸B⁹X⁴L⁴Z¹»^⊕

[MLXZ]𝘲 class:

[MX₄L₄Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₇L₂

[Re(=CH₂)(PPh₃)(NO)(Cp*)]⊕

Formula Unicode styled:

[Re(=CH₂)(PPh₃)(NO)(Cp*)]⊕

Compound name(s):

(η⁵-Pentamethyl-cyclopentadienyl)-methylidene-nitrosyl-triphenylphosphino-rhenium(1+)

Central atom:

Attached groups:

=CH₂ (methylidene)

Cp* (η⁵-pentamethylcyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁷C⁶O^IIIE¹⁸B⁹X⁴L⁴Z¹»^⊕

[MLXZ]𝘲 class:

[MX₄L₄Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₇L₂

mer,trans–[Re(I)(O)₂(PMe₂Ph)₃]

Formula Unicode styled:

mer,trans–[Re(I)(O)₂(PMe₂Ph)₃]

Compound name(s):

Dioxo-iodo-tris(dimethylphenylphosphine)-rhenium

Central atom:

PMe₂Ph (dimethylphenylphosphane)

Attached groups:

I (iodo)

O (oxo X₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁶O^VE¹⁸B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

mer,trans–[Re(Cl)₃(PPh₃)₂(NO)]

Formula Unicode styled:

mer,trans–[Re(Cl)₃(PPh₃)₂(NO)]

Compound name(s):

Nitrosyl-trichloro-bis(triphenylphosphine)-rhenium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Re«V⁶C⁶O^IIE¹⁷B⁸X⁴L³Z¹»

[MLXZ]𝘲 class:

[MX₄L₃Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

mer,trans–[Re(Cl)₃(PMe₃)₂(⭀NMe)]

Formula Unicode styled:

mer,trans–[Re(Cl)₃(PMe₃)₂(⭀NMe)]

Compound name(s):

Trichloro-ethylimido-bis(triethylphosphine)-rhenium

Central atom:

Attached groups:

PMe₃ (trimethylphosphane)

⭀NMe (⭀NMe methylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁶O^VE¹⁸B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

mer,trans–[Re(Cl)₃(PMe₃)₂(=NEt)]

Formula Unicode styled:

mer,trans–[Re(Cl)₃(PMe₃)₂(=NEt)]

Compound name(s):

Trichloro-ethylimido-bis(trimethylphosphine)-rhenium

Central atom:

Attached groups:

PMe₃ (trimethylphosphane)

=NEt (ethylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁶O^VE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

mer,trans–[Re(Cl)₃(PMe₂Ph)₂(NS)]

Formula Unicode styled:

mer,trans–[Re(Cl)₃(PMe₂Ph)₂(NS)]

Compound name(s):

bis(Dimethylphenylphosphine)-trichloro-thionitrosyl-rhenium

Central atom:

Attached groups:

PMe₂Ph (dimethylphenylphosphane)

NS (thionitrosyl, linear)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Re«V⁶C⁶O^IIE¹⁷B⁸X⁴L³Z¹»

[MLXZ]𝘲 class:

[MX₄L₃Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

mer,trans–[Re(Cl)₃(PEtPh₂)₂(⭀NMe)]

Formula Unicode styled:

mer,trans–[Re(Cl)₃(PEtPh₂)₂(⭀NMe)]

Compound name(s):

Trichloro-(methylimino)-bis(diphenylethylphosphine)-rhenium

Central atom:

Attached groups:

PEtPh₂ (ethyldiphenylphosphane)

⭀NMe (⭀NMe methylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁶O^VE¹⁸B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

mer,trans–[Re(Cl)₃(O)(PPh₃)₂]

Formula Unicode styled:

mer,trans–[Re(Cl)₃(O)(PPh₃)₂]

Compound name(s):

Trichloro-bis(triphenylphosphine)-oxo-rhenium

Central atom:

Attached groups:

O (oxo ⭀O X₂L)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: