Iron

Attached groups:

Dppm (bis-(diphenylphosphino)methane-κ²P)

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V²C⁶O^IIE¹⁸B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Fe(NCMe)(Dppe-κ²P){η⁵-C₅H₄(COMe)}]⊕

Formula Unicode styled:

[Fe(NCMe)(Dppe-κ²P){η⁵-C₅H₄(COMe)}]⊕

Compound name(s):

Acetonitrile-(η⁵-acetyl-cyclopentadienyl)-(1,2-bis(diphenylphosphino)ethane-P,P')-iron(1+)

Central atom:

Attached groups:

C₅H₄(COMe) (η⁵-acetylcyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V²C⁶O^IIE¹⁸B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Fe(NCMe)(Dppe-κ²P)(Cp)]⊕

Formula Unicode styled:

[Fe(NCMe)(Dppe-κ²P)(Cp)]⊕

Compound name(s):

Acetonitrile-(η⁵-cyclopentadienyl)-(1,2-bis(diphenylphosphino)ethane-P,P')-iron(1+)

Central atom:

Attached groups:

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V²C⁶O^IIE¹⁸B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Fe(NCMe)(CO)(PPh₃)₂(NO)]⊕

Formula Unicode styled:

[Fe(NCMe)(CO)(PPh₃)₂(NO)]⊕

Compound name(s):

(Acetonitrile)-carbonyl-nitrosyl-bis(triphenylphosphine)-iron(1+)

Central atom:

Attached groups:

PPh₃ (triphenylphosphane)

CO (carbonyl)

NO (nitrosyl, linear)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁴C⁵O^OE¹⁸B⁷X¹L⁵Z¹»^⊕

[MLXZ]𝘲 class:

[MX₁L₅Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Fe(NCEt)(NO)₃]⊕

Formula Unicode styled:

[Fe(NCEt)(NO)₃]⊕

Compound name(s):

Ethylcyanidotrinitrosoiron(1+)

Central atom:

(NO)₃ (trinitrosyl, (N≡O)₃ tetrahedral Ⓢ)

Attached groups:

NCEt (ethylnitrile)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (-II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V²C⁴O^-IIE¹⁸B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Fe(NCBr)₆]²⊕

Formula Unicode styled:

[Fe(NCBr)₆]²⊕

Compound name(s):

Hexakis(bromocyano)iron(2+)

Central atom:

Attached groups:

NCBr (bromocyano)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V²C⁶O^IIE¹⁸B⁶Z⁰X⁰L⁶»^2⊕

[MLXZ]𝘲 class:

[ML₆]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Fe(N₃)(Tpp)]

Formula Unicode styled:

[Fe(N₃)(Tpp)]

Compound name(s):

(Triazido-N)-(5,10,15,20-tetraphenylporphyrinato)-iron

Central atom:

Tpp (tetraphenylporphyrin)

Attached groups:

N₃ (azido)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(N₂)(Depe)₂]

Formula Unicode styled:

[Fe(N₂)(Depe)₂]

Compound name(s):

bis(1,2-bis(Diethylphosphino)ethane)-dinitrogen-iron

Central atom:

Depe (1,2-bis-(diethylphosphino)ethane)

Attached groups:

N₂ (dinitrogen)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Fe(N)₃]⁶⊖

Formula Unicode styled:

[Fe(N)₃]⁶⊖

Compound name(s):

trinitridoiron(6-)

Central atom:

Attached groups:

N (nitrido; ≡N)

Charge on central atom:

Compound type:

Lattice

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 3

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 0

Summary of calculated classifications:

Fe«V³C³O^III»

[MLXZ]𝘲 class:

MLXZ class (ENC, equivalent neutral class):

[Fe(N)₂]⁴⊖

Formula Unicode styled:

[Fe(N)₂]⁴⊖

Compound name(s):

dinitridoiron(4-)

Central atom:

Attached groups:

N (nitrido; ≡N)

Charge on central atom:

-4

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 2

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V²C²O^IIE¹⁸B⁶Z⁰L⁰X⁶»^4⊖

[MLXZ]𝘲 class:

[MX₆]^4-

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Fe(Mes)(μ₂-Mes)]₂

Formula Unicode styled:

[Fe(Mes)(μ₂-Mes)]₂

Compound name(s):

bis-[(μ₂-Mesityl)-mesityl-iron]

Central atom:

Attached groups:

Mes (mesityl)

Mes (μ₂-mesityl)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 13

Summary of calculated classifications:

Fe«V³C⁴O^IIE¹³B⁴Z⁰X³L¹»

[MLXZ]𝘲 class:

[MX₃L₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

[Fe(Mes)₂(Py)₂]

Formula Unicode styled:

[Fe(Mes)₂(Py)₂]

Compound name(s):

Dipyridyl-dimesityl-iron

Central atom:

Attached groups:

Mes (mesityl)

Py (pyridine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V²C⁴O^IIE¹⁴B⁴Z⁰X²L²»

[MLXZ]𝘲 class:

[MX₂L₂]

MLXZ class (ENC, equivalent neutral class):

MX₂L₂

[Fe(Mes)₂(Dme)]

Formula Unicode styled:

[Fe(Mes)₂(Dme)]

Compound name(s):

Dimesityl-(dimethoxyethane)-iron

Central atom:

Attached groups:

Mes (mesityl)

Dme (dimethoxyethane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V²C⁴O^IIE¹⁴B⁴Z⁰X²L²»

[MLXZ]𝘲 class:

[MX₂L₂]

MLXZ class (ENC, equivalent neutral class):

MX₂L₂

[Fe(Me₃SiC≡CSiMe₃)(CO)₂(PEt₃)₂]

Formula Unicode styled:

[Fe(Me₃SiC≡CSiMe₃)(CO)₂(PEt₃)₂]

Compound name(s):

(η²-1,2-bis(Trimethylsilyl)ethyne)-dicarbonyl-bis(triethylphosphine)-iron

Central atom:

Me₃SiC≡CSiMe₃ (bistrimethylsilylethyne)

Attached groups:

CO (carbonyl)

PEt₃ (triethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Fe(Me)(Dppe-κ²P)(Cp*)]⊕

Formula Unicode styled:

[Fe(Me)(Dppe-κ²P)(Cp*)]⊕

Compound name(s):

(η⁵-Pentamethylcyclopentadienyl)-methyl-(1,2-bis(diphenylphosphino)ethane-P,P')-iron(1+)

Central atom:

Attached groups:

Me (methyl)

Cp* (η⁵-pentamethylcyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Fe«V³C⁶O^IIIE¹⁷B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Fe(=CHMe)(Dppe-κ²P)(Cp)]⊕

Formula Unicode styled:

[Fe(=CHMe)(Dppe-κ²P)(Cp)]⊕

Compound name(s):

(η⁵-Pentamethyl-cyclopentadienyl)-(bis(diphenylphosphino)ethane)-(ethylidene)-iron(1+)

Central atom:

=CHMe (methylmethylidene)

Attached groups:

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁴C⁶O^IVE¹⁸B⁷Z⁰X³L⁴»^⊕

[MLXZ]𝘲 class:

[MX₃L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Fe(I)₄]⊖

Formula Unicode styled:

[Fe(I)₄]⊖

Compound name(s):

tetraiodoiron(1-)

Central atom:

Attached groups:

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 13

Summary of calculated classifications:

Fe«V³C⁴O^IIIE¹³B⁴Z⁰L⁰X⁴»^⊖

[MLXZ]𝘲 class:

[MX₄]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

[Fe(I)₂(μ₂-I)]₂²⊖

Formula Unicode styled:

[Fe(I)₂(μ₂-I)]₂²⊖

Compound name(s):

bis-[(μ₂-iodo)-diiodo-iron(1-)]

Central atom:

Attached groups:

I (μ₂-iodo)

Charge on central atom:

-1

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V²C⁴O^IIE¹⁴B⁴Z⁰X³L¹»^⊖

[MLXZ]𝘲 class:

[MX₃L₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₂L₂

[Fe(I)₃{O=C(NMe₂)₂}]

Formula Unicode styled:

[Fe(I)₃{O=C(NMe₂)₂}]

Compound name(s):

Tri-iodo-tetramethylurea-iron

Central atom:

Attached groups:

O=C(NMe₂)₂ (tetramethylurea)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 13

Summary of calculated classifications:

Fe«V³C⁴O^IIIE¹³B⁴Z⁰X³L¹»

[MLXZ]𝘲 class:

[MX₃L₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

[Fe(I)₂{SC(NMe₂)₂}₂]

Formula Unicode styled:

[Fe(I)₂{SC(NMe₂)₂}₂]

Compound name(s):

Di-iodo-bis(1,1,3,3-tetramethylthiourea-S)-iron

Central atom:

Attached groups:

SC(NMe₂)₂ (dimethylthiourea)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: