trans–[Re(Cl)₄(Py)(NO)]⊖

Formula Unicode styled:

Compound name(s):

tetrachloro-nitrosyl-pyridine-rhenium(1-)

Central atom:

Rhenium

Charge on formula unit (QN):

1–

Attached groups:

Cl (chloro)

Py (pyridine)

NO (nitrosyl, linear)

Compound type:

Molecular

DOI link to literature report:

10.1039/DT9780000798

Crystal data CSD link:

eacnpr

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Coordination Number (CN, sum of attached group denticities):

CN: 6

Oxidation Number (ON) (Roman numerals):

ON: (II)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₅L₂Z₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

Summary of calculated classifications:

Re«V⁶C⁶O^IIE¹⁷B⁸X⁵L²Z¹»^⊖

Geometry:

6-coordinate: octahedron (OC-6)

Isomer label:

trans

𝘥-electron configuration = 𝘮 – VN:

d¹

𝘥-electron configuration = 𝘮 – ON:

d⁵

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d¹

Attached atoms:

Cl₄N₂

Phase:

Solid

InChIKey (see www.inchi-trust.org):

FFEQDPUDJQZPOM-UHFFFAOYSA-N