cis,cis,trans–[Os(CO₂Me)₂(μ₂-OMe)(O)₂]₂²⊖

Formula Unicode styled:

Compound name(s):

bis-[(μ₂-methoxo)-bis-(methoxycarbonyl)-dioxo-osmium(1-)]

Central atom:

Osmium

Charge on formula unit (QN):

1–

Attached groups:

CO₂Me (methoxycarbonyl)

OMe (μ₂-methoxy)

O (oxo X₂)

Compound type:

Oligomer

DOI link to literature report:

10.1016/S0277-5387(00)83821-8

Crystal data CSD link:

kijwij

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Coordination Number (CN, sum of attached group denticities):

CN: 6

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₇L₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰X⁷L¹»^⊖

Geometry:

6-coordinate: octahedron (OC-6)

Isomer label:

cis,cis,trans

𝘥-electron configuration = 𝘮 – VN:

d²

𝘥-electron configuration = 𝘮 – ON:

d²

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d²

Attached atoms:

C₂O₄

Phase:

Solid

InChIKey (see www.inchi-trust.org):

JXMSTPMPEFUTGZ-UHFFFAOYSA-N