trans–[Fe(SiCl₃)(CO)₃{P(OPh)₃}]⊖

Formula Unicode styled:

Compound name(s):

tricarbonyl-trichlorosilyl-triphenylphosphite-iron)1-)

Central atom:

Iron

Charge on formula unit (QN):

1–

Attached groups:

SiCl₃ (trichlorosilyl)

CO (carbonyl)

P(OPh)₃ (triphenylphosphite)

Compound type:

Molecular

DOI link to literature report:

10.1016/S0277-5387(00)86773-X

Crystal data CSD link:

kihsoj

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Coordination Number (CN, sum of attached group denticities):

CN: 5

Oxidation Number (ON) (Roman numerals):

ON: (O)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₁L₄]^-

MLXZ class (ENC, equivalent neutral class):

ML₅

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X¹L⁴»^⊖

Geometry:

5-coordinate: trigonal bipyramid (TBPY-5)

Isomer label:

trans

𝘥-electron configuration = 𝘮 – VN:

d⁸

𝘥-electron configuration = 𝘮 – ON:

d⁸

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d⁸

Attached atoms:

C₃P₁Si₁

Phase:

Solid

InChIKey (see www.inchi-trust.org):

JFRBAOTTZHBWDZ-UHFFFAOYSA-N