You are at: University of Sheffield » Chemistry » Mark Winter » Orbitron (atomic orbitals and molecular orbitals) 
Chemistry books (USA)  Chemistry books (UK)  WebElements  Chemdex  Chemputer 


Atomic orbitals: 2p
The shape of the three 2p orbitals. From left to right: 2p_{z}, 2p_{x}, and 2p_{y}. For each, the blue zones are where the wave functions have negative values and the green zones denote positive values. For any atom, there are three 2p orbitals. These orbitals have the same shape but are aligned differently in space. The three 2p orbitals normally used are labelled 2p_{x}, 2p_{y}, and 2p_{z} since the functions are "aligned" along the x, y, and z axes respectively. Note that it is common to denote the shapes of 2p orbitals in books and papers as shown below. These "figureofeight" style pictures are used only for graphic convenience. These pictures make the orbitals appear much "thinner" than they are really, and also that there are sharp "points" in the region of the nucleus, which there are not. Each 2p orbital has two lobes. There is a planar node normal to the axis of the orbital (so the 2p_{x} orbital has a yz nodal plane, for instance). The higher porbitals (3p, 4p, 5p, 6p, and 7p) are more complex still since they have spherical nodes as well. The origin of the planar node becomes clear if we examine the wave equation which, for instance, includes an x term in the case of the 2p_{x} orbital. Clearly When x = 0, then we must have a node, and this by definition is the yz plane.  

The Orbitron is a gallery of orbitals on the WWW The Orbitron^{TM}, a gallery of orbitals on the WWW, URL: http://winter.group.shef.ac.uk/orbitron/Copyright 20022015 Prof Mark Winter [The University of Sheffield]. All rights reserved. Document served: Monday 11th December, 2017 