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Introduction
Assumptions
Geomtries
Geometry prediction
Examples
CH
4
NH
3
OH
2
BF
3
H
3
N-BF
3
[PF
6
]
-
[AsPh
4
]
+
Propene
SF
3
N
Isomers
ClF
3
Multiple bonds
[ClO
4
]
-
[MeCO
2
]
-
Unpaired electrons
NO
2
Beyond six electron pairs
d-block systems
Exercises
Online VSEPR calculator
The University of Sheffield
Department of Chemistry
VSEPR
VSEPR calculation for ethanoate (acetate), Me
C
O
2
-
Ethanoate (acetate), Me
C
O
2
-
Lewis structure:
Central atom
carbon
Valence electrons on central atom:
4
1 Me group contributes 1 electron:
1
2 terminal oxygens each contribute 1 electron in the two σ bonds:
2
Subtract two for the two electrons contributed by
C
to the two π bonds
-2
Add one for the negative charge located on
C
1
Total:
6
Divide by 2 to give electron pairs
3
3 electron pairs:
trigonal
geometry for the three shape-determining electron pairs
The geometry of ethanoate (acetate), Me
C
O
2
-
. You can use your mouse to manipulate the molecule in the right hand "Jmol" image.
A VSEPR tutorial on the WWW
VSEPR tutorial on the WWW, URL:
http://winter.group.shef.ac.uk/vsepr/
Copyright 1996-2015
Prof Mark Winter
[
The University of Sheffield
]. All rights reserved.
Document served: Thursday 5th December, 2024