Atomic orbitals: 7f electron "dot-density"
This page shows representations of electron density in two ways. The first is two-dimensional electron "dot-density" diagrams - plots across an appropriate plane of each 7f orbital. These were created using a Monte Carlo computational method. The second page allows you interact (zoom, rotate) with three-dimensional electron "dot-density" models representing electron density of the various 7f atomic orbitals created by the same Monte Carlo computational method. Green represents regions for which the wave functions are positive and white represents where values are negative.
7fz3, 7fx3, and 7fy3 electron "dot-density"
The 7fz3, 7fx3, and 7fy3 orbitals are all in the cubic set of 7f. Additionally, the 7fz3 orbital appears in the general set.
7fxz2 and 7fyz2 electron "dot-density"
The 7fxz2, 7fx3, and 7fy3 orbitals are both in the general set of 7f but neither is in the cubic set.
7fxyz and 7fz(x2-y2) electron "dot-density"
The 7fxyz and 7fz(x2-y2) orbitals are both in the general set of 7f and both in the cubic set. The cubic set also contains 7fx(z2-y2) and 7fy(z2-x2) orbitals which are the same in appearance, differing only in direction.
7fy(3x2-y2) and 7fx(x2-3y2) electron "dot-density"
The 7fy(3x2-y2) and 7fx(x2-3y2) orbitals are both in the general set of 7f but neither is in the cubic set.
Using JSmol
You can use your mouse to manipulate the "orbital" in the "JSmol" image above. How you do this depends upon how you are viewing this page.
- On a computer, to rotate about the x and y directions, drag mouse around the image
- On a computer, to rotate about the z direction (which comes out of the screen towards you), hold shift and drag mouse horizontally
- To zoom, hold shift key down and drag mouse vertically
- To reset the image, hold down shift key and double click ony part of the image not containing dots
- On a mobile device experiment using one or two fingers to rotate and zoom
The OrbitronTM, a gallery of orbitals on the WWW: https://winter.group.shef.ac.uk/orbitron/
Copyright 2002-2023 Prof. Mark Winter [The University of Sheffield]. All rights reserved.