Chemicals

Central atom: Aluminium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Al(Cl){OC(CF₃)₃}₃]⊖ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), OC(CF₃)₃ (perfluorobutoxy) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl){OC(CF₃)₃}₃]⊖
[Al(Cl){Si(SiMe₃)₃}(Thf)]₂ Aluminium VN: 3 CN: 4 ON: (II) EN: 8 Cl (chloro), Si(SiMe₃)₃ (tris-trimethylsilyl-silyl), Thf (tetrahydrofuran) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl){Si(SiMe₃)₃}(Thf)]₂
[Al(CN)(Me)₃]⊖ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 CN (cyano-κC), Me (methyl) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(CN)(Me)₃]⊖
[Al(Cp*)(AlBuᵗ₃)] Aluminium VN: 3 CN: 4 ON: (I) EN: 8 Cp* (η⁵-pentamethylcyclopentadienyl), AlBuᵗ₃ (tri-t-butylaluminium) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cp*)(AlBuᵗ₃)]
[(AlCp*){Co(CO)₃}]₂ Aluminium VN: 3 CN: 5 ON: (III) EN: 10 Cp* (η⁵-pentamethylcyclopentadienyl), Co group (X type) Oligomer 5-coordinate: ③-●-2 piano stool

[(AlCp*){Co(CO)₃}]₂
[Al(Cp*)(GaBu₃)] Aluminium VN: 3 CN: 4 ON: (I) EN: 8 Cp* (η⁵-pentamethylcyclopentadienyl), GaBuᵗ₃ (tri-t-butylgallane) Molecular 4-coordinate: ③-●-1 shooting stick

[Al(Cp*)(GaBu₃)]
[Al(Cp*)(μ₃-S)]₄ Aluminium VN: 3 CN: 6 ON: (III) EN: 12 Cp* (η⁵-pentamethylcyclopentadienyl), S (μ₃-thio X₂L) Oligomer 6-coordinate: ③-●-3 piano stool

[Al(Cp*)(μ₃-S)]₄
[Al(Cp*)(μ₃-Te)]₄ Aluminium VN: 3 CN: 6 ON: (III) EN: 12 Cp* (η⁵-pentamethylcyclopentadienyl), Te (μ₃-telluro X₂L) Oligomer 6-coordinate: ③-●-3 piano stool

[Al(Cp*)(μ₃-Te)]₄
[AlCp*{Ni(AlCp*)₃}] Aluminium VN: 3 CN: 4 ON: (I) EN: 8 Cp* (η⁵-pentamethylcyclopentadienyl), Ni group (Z type) Molecular 4-coordinate: ③-●-1 shooting stick

[AlCp*{Ni(AlCp*)₃}]
[Pd(AlCp*)₄] Aluminium VN: 3 CN: 4 ON: (I) EN: 8 Cp* (η⁵-pentamethylcyclopentadienyl), Pd group (Z type) Molecular 4-coordinate: ③-●-1 shooting stick

[Pd(AlCp*)₄]
[AlCp*{Y(Cp*)}₂] Aluminium VN: 3 CN: 4 ON: (I) EN: 8 Cp* (η⁵-pentamethylcyclopentadienyl), Yb group (Z type) Molecular 4-coordinate: ③-●-1 shooting stick

[AlCp*{Y(Cp*)}₂]
[Al(Cp*)₂]⊕ Aluminium VN: 3 CN: 6 ON: (III) EN: 12 Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 6-coordinate: ③-●-③ sandwich

[Al(Cp*)₂]⊕
[Al(Cp*)]₄ Aluminium VN: 3 CN: 4 ON: (I) EN: 8 Cp* (η⁵-pentamethylcyclopentadienyl) Oligomer 4-coordinate: ③-●-1 shooting stick

[Al(Cp*)]₄
[Al(Cp*){Cr(CO)₅}] Aluminium VN: 3 CN: 4 ON: (I) EN: 8 Cp* (η⁵-pentamethylcyclopentadienyl), Cr(CO)₅ (pentacarbonylchromium) Molecular 4-coordinate: ③-●-1 shooting stick

[Al(Cp*){Cr(CO)₅}]
[Al(Cp*){Cr(CO)₅}] Aluminium VN: 3 CN: 4 ON: (I) EN: 8 Cp* (η⁵-pentamethylcyclopentadienyl), Cr(CO)₅ (pentacarbonylchromium) Molecular 4-coordinate: ③-●-1 shooting stick

[Al(Cp*){Cr(CO)₅}]
[Al(Cp*){Fe(CO)₄}] Aluminium VN: 3 CN: 4 ON: (I) EN: 8 Cp* (η⁵-pentamethylcyclopentadienyl), Fe(CO)₄ (tetracarbonyliron) Molecular 4-coordinate: ③-●-1 shooting stick

[Al(Cp*){Fe(CO)₄}]
[Al(Cp-κC)(Me)(μ₂-Cl)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cp (cyclopentadienyl-κC), Me (methyl), Cl (μ₂-chloro) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cp-κC)(Me)(μ₂-Cl)]₂
[Al(Cp-κC)₂(OBuⁱ)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cp (cyclopentadienyl-κC), OBuⁱ (i-butyloxy) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cp-κC)₂(OBuⁱ)]₂
[Al(Cp-κC)₂(μ₂-OEt)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cp (cyclopentadienyl-κC), OEt (μ₂-ethoxy) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cp-κC)₂(μ₂-OEt)]₂
[Al(Cp-κC)₂(μ₂-OPrⁱ)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cp (cyclopentadienyl-κC), OPrⁱ (μ₂-isopropoxy) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cp-κC)₂(μ₂-OPrⁱ)]₂