Chemicals

Central atom: Aluminium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Al(Cl)₃(SPPh₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), SPPh₃ (triphenylphosphane sulfide) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(SPPh₃)]
[Al(Cl)₃(TeMe₂)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), TeMe₂ (dimethyltellurane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(TeMe₂)]
[Al(Cl)₃(Thf)₂] Aluminium VN: 3 CN: 5 ON: (III) EN: 10 Cl (chloro), Thf (tetrahydrofuran) Molecular 5-coordinate: trigonal bipyramidal (p-block element, 0 lone pairs)

[Al(Cl)₃(Thf)₂]
[Al(Cl)₃(Thf)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), Thf (tetrahydrofuran) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(Thf)]
[Al(Cl)₃{N(CH₂CH₂)₃CH}] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), N(CH₂CH₂)₃CH (quinuclidine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃{N(CH₂CH₂)₃CH}]
[Al(Cl)₃{N(SnMe₃)₃}] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), N(SnMe₃)₃ (tris-(trimethylstanane)amine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃{N(SnMe₃)₃}]
[Al(Cl)₃{NH(CH₂)₂O(CH₂)₂}₂] Aluminium VN: 3 CN: 5 ON: (III) EN: 10 Cl (chloro), NH(CH₂)₂O(CH₂)₂ (morpholine) Molecular 5-coordinate: trigonal bipyramidal (p-block element, 0 lone pairs)

[Al(Cl)₃{NH(CH₂)₂O(CH₂)₂}₂]
[Al(Cl)₃{NH(CMe₂CH₂CH₂CH₂CMe₂)}] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), NH(CMe₂CH₂CH₂CH₂CMe₂) (2,2,6,6,tetramethyl-piperidine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃{NH(CMe₂CH₂CH₂CH₂CMe₂)}]
[Al(Cl)₃{NH(SiMe₃)₂}] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), NH(SiMe₃)₂ (bis(trimethylsilyl)amine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃{NH(SiMe₃)₂}]
[Al(Cl)₃{O=C(NH₂)₂}] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), O=C(NH₂)₂ (urea) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃{O=C(NH₂)₂}]
[Al(Cl)₃{P(SiMe₃)₃}] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), P(SiMe₃)₃ (tris-(trimethylsilyl)-phosphane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃{P(SiMe₃)₃}]
[Al(Cl)₃{Si(SiMe₃)₃}]⊖ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), Si(SiMe₃)₃ (tris-trimethylsilyl-silyl) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃{Si(SiMe₃)₃}]⊖
trans–[Al(Cl)₄(NH₃)₂]⊖ Aluminium VN: 3 CN: 6 ON: (III) EN: 12 Cl (chloro), NH₃ (ammine) Molecular 6-coordinate: octahedral (p-block element, 0 lone pairs)

trans–[Al(Cl)₄(NH₃)₂]⊖
[Al(Cl)₄(Py)₂]⊖ Aluminium VN: 3 CN: 6 ON: (III) EN: 12 Cl (chloro), Py (pyridine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₄(Py)₂]⊖
[Al(Cl)₄]⊖ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₄]⊖
[Al(Cl){C₆H₃(C₆H₃Prⁱ₂)₂}(μ₂-OH)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), C₆H₃(C₆H₃Prⁱ₂)₂ (2,6-di-(2,6-disopropylphenyl)-phenyl), OH (μ₂-hydroxy) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl){C₆H₃(C₆H₃Prⁱ₂)₂}(μ₂-OH)]₂
[Al(Cl){CH(SiMe₃)₂}(μ₂-Cl)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), CH(SiMe₃)₂ (bistrimethylsilylmethyl), Cl (μ₂-chloro) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl){CH(SiMe₃)₂}(μ₂-Cl)]₂
[Al(Cl){N(CMe₂CH₂CH₂CH₂CMe₂)}(μ₂-OEt)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), N(CMe₂CH₂CH₂CH₂CMe₂) (2,2,6,6,tetramethyl-piperidinato), OEt (μ₂-ethoxy) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl){N(CMe₂CH₂CH₂CH₂CMe₂)}(μ₂-OEt)]₂
[Al(Cl){N(CMe₂CH₂CH₂CH₂CMe₂)}₂] Aluminium VN: 3 CN: 3 ON: (III) EN: 6 Cl (chloro), N(CMe₂CH₂CH₂CH₂CMe₂) (2,2,6,6,tetramethyl-piperidinato) Molecular 3-coordinate: trigonal planar (p-block element, 0 lone pairs)

[Al(Cl){N(CMe₂CH₂CH₂CH₂CMe₂)}₂]
[Al(Cl){N(SiMe₃)₂}₂] Aluminium VN: 3 CN: 3 ON: (III) EN: 6 Cl (chloro), N(SiMe₃)₂ (bis(trimethylsilyl)amino) Molecular 3-coordinate: trigonal planar (p-block element, 0 lone pairs)

[Al(Cl){N(SiMe₃)₂}₂]