Chemicals

Central atom: Aluminium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Al(Cl)₃(NH₂Buᵗ)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), NH₂Buᵗ (t-butylamine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(NH₂Buᵗ)]
[Al(Cl)₃(NH₂Prⁱ)₂] Aluminium VN: 3 CN: 5 ON: (III) EN: 10 Cl (chloro), NH₂Prⁱ (isopropylamine) Molecular 5-coordinate: trigonal bipyramidal (p-block element, 0 lone pairs)

[Al(Cl)₃(NH₂Prⁱ)₂]
[Al(Cl)₃(NHMe₂)₂] Aluminium VN: 3 CN: 5 ON: (III) EN: 10 Cl (chloro), NHMe₂ (dimethylamine) Molecular 5-coordinate: trigonal bipyramidal (p-block element, 0 lone pairs)

[Al(Cl)₃(NHMe₂)₂]
[Al(Cl)₃(NHMe₂)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), NHMe₂ (dimethylamine) Molecular 5-coordinate: trigonal bipyramidal (p-block element, 0 lone pairs)

[Al(Cl)₃(NHMe₂)]
[Al(Cl)₃(NHPh₂)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), NHPh₂ (diphenylamine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(NHPh₂)]
[Al(Cl)₃(NMe₃)₂] Aluminium VN: 3 CN: 5 ON: (III) EN: 10 Cl (chloro), NMe₃ (trimethylamine) Molecular 5-coordinate: trigonal bipyramidal (p-block element, 0 lone pairs)

[Al(Cl)₃(NMe₃)₂]
[Al(Cl)₃(NMe₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), NMe₃ (trimethylamine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(NMe₃)]
[Al(Cl)₃(O₂NMe-κO)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), O₂NMe (methylnitrito-κO) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(O₂NMe-κO)]
[Al(Cl)₃(O₂NPh-κO)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), O₂NPh (phenylnitrito-κO) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(O₂NPh-κO)]
[Al(Cl)₃(OEt₂)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), OEt₂ (diethylether) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(OEt₂)]
[Al(Cl)₃(OPPh₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), OPPh₃ (triphenylphosphane oxide) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(OPPh₃)]
[Al(Cl)₃(Pip)₂] Aluminium VN: 3 CN: 5 ON: (III) EN: 10 Cl (chloro), Pip (piperidine) Molecular 5-coordinate: trigonal bipyramidal (p-block element, 0 lone pairs)

[Al(Cl)₃(Pip)₂]
[Al(Cl)₃(PMe₃)₂] Aluminium VN: 3 CN: 5 ON: (III) EN: 10 Cl (chloro), PMe₃ (trimethylphosphane) Molecular 5-coordinate: trigonal bipyramidal (p-block element, 0 lone pairs)

[Al(Cl)₃(PMe₃)₂]
[Al(Cl)₃(PMe₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), PMe₃ (trimethylphosphane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(PMe₃)]
[Al(Cl)₃(PMes₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), PMes₃ (trimesitylphosphane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(PMes₃)]
[Al(Cl)₃(PPh₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), PPh₃ (triphenylphosphane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(PPh₃)]
mer–[Al(Cl)₃(Py)₃] Aluminium VN: 3 CN: 6 ON: (III) EN: 12 Cl (chloro), Py (pyridine) Molecular 6-coordinate: octahedral (p-block element, 0 lone pairs)

mer–[Al(Cl)₃(Py)₃]
[Al(Cl)₃(Py)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), Py (pyridine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(Py)]
[Al(Cl)₃(SeMe₂)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), SeMe₂ (dimethylselane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(SeMe₂)]
[Al(Cl)₃(SePPh₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Cl (chloro), SePPh₃ (triphenylphosphane selenide) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Cl)₃(SePPh₃)]