C(SMe)Me (methylthiomethylcarbene)

[Fe(CO)₂{C(SMe)Me}(Cp)]⊕

Formula Unicode styled: 
[Fe(CO)₂{C(SMe)Me}(Cp)]⊕
Compound name(s): 
Dicarbonyl-(η⁵-cyclopentadienyl)-methyl(methylthio)carbenium-iron(1+)
Central atom: 
Iron
Attached groups: 
CO (carbonyl)
C(SMe)Me (methylthiomethylcarbene)
Cp (η⁵-cyclopentadienyl)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Fe«V2C6OIIE18B6Z0X1L5»⊕
[MLXZ]𝘲 class: 
[MX1L5]+
MLXZ class (ENC, equivalent neutral class): 
MX2L4

[Ir(I){C(SMe)Me}(PPh₃)(Cp)]⊕

Formula Unicode styled: 
[Ir(I){C(SMe)Me}(PPh₃)(Cp)]⊕
Compound name(s): 
η⁵-Cyclopentadienyl-iodo-(methyl(methylthio)-carbene)-(triphenylphosphine)-iridium(1+)
Central atom: 
Iridium
Attached groups: 
I (iodo)
C(SMe)Me (methylthiomethylcarbene)
PPh₃ (triphenylphosphane)
Cp (η⁵-cyclopentadienyl)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Ir«V3C6OIIIE18B6Z0X2L4»⊕
[MLXZ]𝘲 class: 
[MX2L4]+
MLXZ class (ENC, equivalent neutral class): 
MX3L3