7-coordinate: edge-capped octahedral

Attached groups:

S₂ (disulfanediyl-κ²S)

OH₂ (aqua)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁷O^IVE¹⁴B⁷Z⁰X³L⁴»^2⊕

[MLXZ]𝘲 class:

[MX₃L₄]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Nb(S₂)(Acac)₂]₂

Formula Unicode styled:

[Nb(S₂)(Acac)₂]₂

Compound name(s):

bis-[(μ₂-Disulfido)-bis(acetylacetonato-O,O')-niobium(Nb—Nb)]

Central atom:

Attached groups:

S₂ (disulfanediyl-κ²S)

Acac (acetylacetonato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁷O^IVE¹⁴B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Nb(μ₃–O)₂]

Formula Unicode styled:

[Nb(μ₃–O)₂]

Compound name(s):

dioxo-niobium(Nb-Nb)|niobium dioxide

Central atom:

Attached groups:

O (μ₃–oxo X₂L)

Charge on central atom:

Compound type:

Lattice

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 0

Summary of calculated classifications:

Nb«V⁵C⁷O^IV»

[MLXZ]𝘲 class:

MLXZ class (ENC, equivalent neutral class):

[Nb(Cl)₃(μ₂-Cl)(SMe₂)]₂

Formula Unicode styled:

[Nb(Cl)₃(μ₂-Cl)(SMe₂)]₂

Compound name(s):

bis-[(μ₂-chloro)-trichloro-(dimethyl sulfide)-niobium(Nb—Nb)]

Central atom:

Attached groups:

SMe₂ (dimethylthioether)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁷O^IVE¹⁴B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Nb(Cl)₂(μ₂-Cl)₂(PMe₃)₂]₂

Formula Unicode styled:

[Nb(Cl)₂(μ₂-Cl)₂(PMe₃)₂]₂

Compound name(s):

bis-[bis(μ₂-Chloro)-dichloro-bis(trimethylphosphine)-niobium(Nb—Nb)]

Central atom:

Attached groups:

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁷O^IVE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Nb(Cl)₂(μ₂-Cl)₂(PH₂Ph)₂]₂

Formula Unicode styled:

[Nb(Cl)₂(μ₂-Cl)₂(PH₂Ph)₂]₂

Compound name(s):

bis-[bis(μ₂-Chloro)-dichloro-di(phenylphosphine)-niobium(Nb—Nb)]

Central atom:

Attached groups:

PH₂Ph (phenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁷O^IVE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Nb(Cl)₂(μ₂-Cl)(TMEDA-κ²N)]₂

Formula Unicode styled:

[Nb(Cl)₂(μ₂-Cl)(TMEDA-κ²N)]₂

Compound name(s):

bis-[(μ₂-Chloro)-dichloro-(N,N,N',N'-tetraethylethylenediamine-N,N')-niobium(Nb=Nb)]

Central atom:

Attached groups:

TMEDA (tetramethylethylenediamine-κ²N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁷O^IIIE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Nb(Cl)₂(μ₂-Cl)(SMe₂)₂]₂

Formula Unicode styled:

[Nb(Cl)₂(μ₂-Cl)(SMe₂)₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-dichloro-bis-(dimethylsulfide)-niobium(Nb—Nb)]

Central atom:

Attached groups:

SMe₂ (dimethylthioether)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Nb«V⁴C⁷O^IIIE¹⁵B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Nb(Cl)₂(μ₂-Cl)(Dmpm-κ²P)]₂

Formula Unicode styled:

[Nb(Cl)₂(μ₂-Cl)(Dmpm-κ²P)]₂

Compound name(s):

bis-[(μ₂-chloro)-dichloro-(μ₂-dimethylphosphinomethane)-niobium(Nb=Nb)]

Central atom:

Attached groups:

Dmpm (1,2-bis-(dimethylphosphino)methane-κ²P)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁷O^IIIE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Nb(Cl)₂(μ₂-Cl)(Dppm-κ²P)]₂

Formula Unicode styled:

[Nb(Cl)₂(μ₂-Cl)(Dppm-κ²P)]₂

Compound name(s):

bis-[(μ₂-chloro)-dichloro-(diphenylphosphinomethane)-niobium(Nb=Nb)]

Central atom:

Attached groups:

Dppm (bis-(diphenylphosphino)methane-κ²P)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁷O^IIIE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Nb(Cl)₂(μ₂-Cl)(Depe)]₂

Formula Unicode styled:

[Nb(Cl)₂(μ₂-Cl)(Depe)]₂

Compound name(s):

bis-[(μ₂-Chloro)-dichloro-(diethylphosphino)ethane-P,P')-niobium(Nb=Nb)]

Central atom:

Attached groups:

Depe (1,2-bis-(diethylphosphino)ethane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁷O^IIIE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Nb(Cl)₂(μ₂-S)(Tht)₂]₂

Formula Unicode styled:

[Nb(Cl)₂(μ₂-S)(Tht)₂]₂

Compound name(s):

bis-[μ₂-Thio-dichloro-di(tetrahydrothiophene)-niobium(Nb—Nb)]

Central atom:

Attached groups:

Tht (tetrahydrothiophene)

S (μ₂-thio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁷O^IVE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Nb(Cl)₂(μ₂-S)(PMe₃)₂]₂

Formula Unicode styled:

[Nb(Cl)₂(μ₂-S)(PMe₃)₂]₂

Compound name(s):

bis-[μ₂-Thio-dichloro-di(trimethylphosphine)-niobium(Nb—Nb)]

Central atom:

Attached groups:

PMe₃ (trimethylphosphane)

S (μ₂-thio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁷O^IVE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Nb(Cl)₂(μ₂-S)(NCMe)₂]₂

Formula Unicode styled:

[Nb(Cl)₂(μ₂-S)(NCMe)₂]₂

Compound name(s):

bis-[μ₂-Thio-dichloro-di(cyanomethane)-niobium(Nb—Nb)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁷O^IVE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Nb(Cl)₂(OMe)(μ₂-OMe)(OHMe)]₂

Formula Unicode styled:

[Nb(Cl)₂(OMe)(μ₂-OMe)(OHMe)]₂

Compound name(s):

bis-[(μ₂-Methoxo)-(methanol-O)-dichloro-methoxy-niobium(Nb—Nb)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁷O^IVE¹⁴B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Nb(Cl)₂(OMe)(μ₂-OMe)(NCMe)]₂

Formula Unicode styled:

[Nb(Cl)₂(OMe)(μ₂-OMe)(NCMe)]₂

Compound name(s):

bis-[(μ₂-Methoxo)-(acetonitrile-N)-dichloro-methoxy-niobium(Nb—Nb)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

PEt₂ (μ₂-diethylphosphanyl)

Summary of calculated classifications:

Nb«V⁵C⁷O^IVE¹⁴B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Mo(μ₂-PEt₂)(CO)₄]₂

Formula Unicode styled:

[Mo(μ₂-PEt₂)(CO)₄]₂

Compound name(s):

bis-[(μ₂-diethylphosphido-tetracarbonyl-molybdenum(Mo—Mo)]

Central atom:

Molybdenum

Attached groups:

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V²C⁷O^IE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

catena–1D-[Mo(μ₂-I)₃]

Formula Unicode styled:

catena–1D-[Mo(μ₂-I)₃]

Compound name(s):

catena-[triiodo-molybdenum (Mo-Mo)]

molybdenum triiodide

Central atom:

Molybdenum

Attached groups:

I (μ₂-iodo)

Charge on central atom:

0

Compound type:

Catena-1D

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁴C⁷O^IIIE¹⁶B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Mo(μ₂-I)(CO)₄]₂

Formula Unicode styled:

[Mo(μ₂-I)(CO)₄]₂

Compound name(s):

bis-[(μ₂-iodo)-tetracarbonyl-molybdenum(Mo—Mo)]

Central atom:

Molybdenum

Attached groups:

I (μ₂-iodo)

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V²C⁷O^IE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Mo(Cl)₂(OPh)₂(μ₂-OPh)]₂

Formula Unicode styled:

[Mo(Cl)₂(OPh)₂(μ₂-OPh)]₂

Compound name(s):

bis-[(μ₂-phenoxo)-dichloro-diphenoxo-molybdenum(Mo—Mo)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: