7-coordinate: edge-capped octahedral

Attached groups:

H (μ₂-hydrido)

CO (carbonyl)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

CN: 6

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁰C⁶O^OE¹⁸B⁶Z⁰X¹L⁵»^⊖

[MLXZ]𝘲 class:

[MX₁L₅]^-

MLXZ class (ENC, equivalent neutral class):

ML₆

[W(Cl)₃(μ₂-SPh)(SMe₂)]₂

Formula Unicode styled:

[W(Cl)₃(μ₂-SPh)(SMe₂)]₂

Compound name(s):

bis-[μ₂-Phenylthiolato)-trichloro-(dimethylsulfide)-tungsten(W—W)]

Central atom:

Attached groups:

SPh (μ₂-phenylthio)

SMe₂ (dimethylthioether)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

W«V⁵C⁷O^IVE¹⁵B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[W(Cl)₂(μ₂-Cl)(PMe₃)₂]₂

Formula Unicode styled:

[W(Cl)₂(μ₂-Cl)(PMe₃)₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-dichloro-bis(trimethylphosphine)-tungsten(W—W)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁷O^IIIE¹⁶B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[W(Cl)₂(μ₂-Cl)(PEt₃)₂]₂

Formula Unicode styled:

[W(Cl)₂(μ₂-Cl)(PEt₃)₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-dichloro-bis(triethylphosphine)-tungsten(W—W)]

Central atom:

Attached groups:

PEt₃ (triethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁷O^IIIE¹⁶B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[W(Cl)₂(OMe)(μ₂-OMe)(OHMe)]₂

Formula Unicode styled:

[W(Cl)₂(OMe)(μ₂-OMe)(OHMe)]₂

Compound name(s):

bis-[(μ₂-methoxy)-dichloro-(methanol)-methoxy-tungsten(W=W)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁷O^IVE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(Cl)₂(OEt)(μ₂-OEt)(OHEt)]₂

Formula Unicode styled:

[W(Cl)₂(OEt)(μ₂-OEt)(OHEt)]₂

Compound name(s):

bis-[(μ₂-Ethoxy)-dichloro-(ethanol)-ethoxy-tungsten(W=W)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁷O^IVE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(Cl)(O)(μ₂-S)(Bpy)]₂

Formula Unicode styled:

[W(Cl)(O)(μ₂-S)(Bpy)]₂

Compound name(s):

bis-[chloro-(μ₂-sulfido)-(2,2'-biyridyl)-oxo-tungsten(W—W)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

PPh₃ (triphenylphosphane)

Summary of calculated classifications:

W«V⁶C⁷O^VE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[W(Cl)(μ₂-H)(μ₂-O₂CPh)(PPh₃)]₂

Formula Unicode styled:

[W(Cl)(μ₂-H)(μ₂-O₂CPh)(PPh₃)]₂

Compound name(s):

bis-[(μ₂-Benzoato)-(μ₂-hydrido)-chloro-(triphenylphosphine)-tungsten(W≡W)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁷O^IIIE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[W(Br)(O)(μ₂-S)(Bpy)]₂

Formula Unicode styled:

[W(Br)(O)(μ₂-S)(Bpy)]₂

Compound name(s):

bis-[bromo-(μ₂-sulfido)-(2,2'-biyridyl)-oxo-tungsten(W—W)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁷O^VE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[W(μ₂-AsPh₂)(CO)₄]₂

Formula Unicode styled:

[W(μ₂-AsPh₂)(CO)₄]₂

Compound name(s):

bis-[(μ₂-Diphenylarsine)-tetrarbonyl-tungsten(W—W)]

Central atom:

AsPh₂ (μ₂-diphenylarsanyl)

Attached groups:

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

PMe₂ (μ₂-dimethylphosphanyl)

Summary of calculated classifications:

W«V²C⁷O^IE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[V(μ₂-PMe₂)(CO)₄]₂

Formula Unicode styled:

[V(μ₂-PMe₂)(CO)₄]₂

Compound name(s):

bis-[μ₂-Dimethylphosphido)-bis(tetracarbonyl-vanadium(V=V)]

Central atom:

Vanadium

Attached groups:

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

V«V³C⁷O^IE¹⁸B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ta(Cl)₂(μ₂-Cl)(TMEDA-κ²N)]₂

Formula Unicode styled:

[Ta(Cl)₂(μ₂-Cl)(TMEDA-κ²N)]₂

Compound name(s):

bis-[(μ₂-Chloro)-dichloro-(N,N,N',N'-tetraethylethylenediamine-N,N')-di-tantalum(Ta=Ta)]

Central atom:

Attached groups:

TMEDA (tetramethylethylenediamine-κ²N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ta«V⁵C⁷O^IIIE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Ta(Cl)₃(μ₂-SPh)(SMe₂)]₂

Formula Unicode styled:

[Ta(Cl)₃(μ₂-SPh)(SMe₂)]₂

Compound name(s):

bis-[(μ₂-Phenylthiolato)-trichloro-dimethylthiolato-tantalum(Ta—Ta)]

Central atom:

Attached groups:

SPh (μ₂-phenylthio)

SMe₂ (dimethylthioether)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Ta«V⁵C⁷O^IVE¹⁴B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Ta(Cl)₂(μ₂-Cl)(SMe₂)₂]₂

Formula Unicode styled:

[Ta(Cl)₂(μ₂-Cl)(SMe₂)₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-dichloro-(dimethylthio)-tantalum(Ta—Ta)]

Central atom:

Attached groups:

SMe₂ (dimethylthioether)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Ta«V⁴C⁷O^IIIE¹⁵B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Ta(Cl)₂(μ₂-Cl)(PMe₃)₂]₂

Formula Unicode styled:

[Ta(Cl)₂(μ₂-Cl)(PMe₃)₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-dichloro-bis(trimethylphosphine)-tantalum(Ta=Ta)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ta«V⁵C⁷O^IIIE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Ta(Cl)₂(μ₂-Cl)(Depe)]₂

Formula Unicode styled:

[Ta(Cl)₂(μ₂-Cl)(Depe)]₂

Compound name(s):

bis-[(μ₂-Chloro)-dichloro-(bis(diethylphosphino)ethane-P,P')-tantalum(Ta=Ta)]

Central atom:

Attached groups:

Depe (1,2-bis-(diethylphosphino)ethane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ta«V⁵C⁷O^IIIE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Ta(Cl)₂(μ₂-S)(PMe₃)₂]₂

Formula Unicode styled:

[Ta(Cl)₂(μ₂-S)(PMe₃)₂]₂

Compound name(s):

bis-[(μ₂-Sulfido)-dichloro-bis(trimethylphosphino)-tantalum(Ta—Ta)]

Central atom:

Attached groups:

S (μ₂-thio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ta«V⁵C⁷O^IVE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Ta(Cl)₂(μ₂-S)(PMe₂Ph)₂]₂

Formula Unicode styled:

[Ta(Cl)₂(μ₂-S)(PMe₂Ph)₂]₂

Compound name(s):

bis-[(μ₂-Sulfido)-dichloro-bis(dimethylphenylphosphino)-tantalum(Ta—Ta)]

Central atom:

Attached groups:

PMe₂Ph (dimethylphenylphosphane)

S (μ₂-thio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ta«V⁵C⁷O^IVE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Ta(Cl)₂(μ₂-H)(PMe₃)₂]₂

Formula Unicode styled:

[Ta(Cl)₂(μ₂-H)(PMe₃)₂]₂

Compound name(s):

bis-[(μ₂-Hydrido)-dichloro-bis(trimethylphosphine)-tantalum(Ta—Ta)]

Central atom:

Attached groups:

H (μ₂-hydrido)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Ta«V⁴C⁷O^IIIE¹⁵B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Nb(Se₂)(Acac)₂]₂

Formula Unicode styled:

[Nb(Se₂)(Acac)₂]₂

Compound name(s):

bis-[(μ₂-Diselenido)-bis(acetylacetonato)-niobium(Nb—Nb)]

Central atom:

Niobium

Attached groups:

Se₂ (perseleno-κ²Se)

Acac (acetylacetonato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):