5-coordinate: trigonal bipyramid (TBPY-5)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Os(CO)₄(SbPh₃)]

Formula Unicode styled:

[Os(CO)₄(SbPh₃)]

Compound name(s):

Tetracarbonyl-triphenylstibine-osmium

Central atom:

Attached groups:

SbPh₃ (triphenylstibane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Os(CO)₄(PPh₃)]

Formula Unicode styled:

[Os(CO)₄(PPh₃)]

Compound name(s):

tetracarbonyl-(triphenylphosphine)-osmium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Os(CO)₄(C₂H₄)]

Formula Unicode styled:

[Os(CO)₄(C₂H₄)]

Compound name(s):

Tetracarbonyl-(ets-ethenyl)-osmium

Central atom:

Attached groups:

C₂H₄ (ethene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Os(CO)₄(Me₃SiC≡CSiMe₃)]

Formula Unicode styled:

[Os(CO)₄(Me₃SiC≡CSiMe₃)]

Compound name(s):

Tetracarbonyl-(etajedpox-bis(trimethylsilyl)acetylene)-osmium

Central atom:

Attached groups:

Me₃SiC≡CSiMe₃ (bistrimethylsilylethyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Os(O)₄{NMe(CH₂)₂O(CH₂)₂}]

Formula Unicode styled:

[Os(O)₄{NMe(CH₂)₂O(CH₂)₂}]

Compound name(s):

(N-Methylmorpholine)-tetraoxo-osmium

Central atom:

NMe(CH₂)₂O(CH₂)₂ (N-methyl-morpholine)

Attached groups:

O (oxo X₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 8

Oxidation Number (ON) (Roman numerals):

ON: (VIII)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁸C⁵O^VIIIE¹⁸B⁹Z⁰X⁸L¹»

[MLXZ]𝘲 class:

[MX₈L₁]

MLXZ class (ENC, equivalent neutral class):

MX₈L₁

[Os(F)(O)₄]⊖

Formula Unicode styled:

[Os(F)(O)₄]⊖

Compound name(s):

fluorotetraoxoosmium(1-)

Central atom:

Attached groups:

F (fluoro)

O (oxo X₂)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 8

Oxidation Number (ON) (Roman numerals):

ON: (VIII)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁸C⁵O^VIIIE¹⁸B⁹Z⁰L⁰X⁹»^⊖

[MLXZ]𝘲 class:

[MX₉]^-

MLXZ class (ENC, equivalent neutral class):

MX₈L₁

[Os(H)(=C=CH₂)(HC≡CH)(PPrⁱ₃)₂]⊕

Formula Unicode styled:

[Os(H)(=C=CH₂)(HC≡CH)(PPrⁱ₃)₂]⊕

Compound name(s):

(η-Ethyne)-hydrido-bis(triisopropylphosphine)-(vinylidene)-osmium(1+)

Central atom:

C=CH₂ (vinylidene, ethynylidene)

Attached groups:

H (hydrido)

HC≡CH (ethyne)

PPrⁱ₃ (triisopropylphosphane)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁴C⁵O^IVE¹⁶B⁶Z⁰X³L³»^⊕

[MLXZ]𝘲 class:

[MX₃L₃]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

[Os(CO)₄(CF₃C≡CCF₃)]

Formula Unicode styled:

[Os(CO)₄(CF₃C≡CCF₃)]

Compound name(s):

(η-bis(Trifluoromethyl)acetylene)-tetracarbonyl-osmium

Central atom:

Attached groups:

CF₃C≡CCF₃ (bis(trifluoromethyl)ethyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Os(CO)₂(PPh₃)(PhC≡CPh)]

Formula Unicode styled:

[Os(CO)₂(PPh₃)(PhC≡CPh)]

Compound name(s):

(η-1,2-Diphenylacetylene)-dicarbonyl-bis(triphenylphosphine)-osmium

Central atom:

Attached groups:

PhC≡CPh (diphenylethyne L₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 4

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁰C⁴O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

trans–[Os(Cl)₂(PPh₃)₃]

Formula Unicode styled:

trans–[Os(Cl)₂(PPh₃)₃]

Compound name(s):

Dichloro-tris(triphenylphosphine)-osmium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁵O^IIE¹⁶B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Os(Cl)(O)₄]⊖

Formula Unicode styled:

[Os(Cl)(O)₄]⊖

Compound name(s):

chloro-tetra-oxo-osmium(1-)

Central atom:

Attached groups:

O (oxo X₂)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 8

Oxidation Number (ON) (Roman numerals):

ON: (VIII)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁸C⁵O^VIIIE¹⁸B⁹Z⁰L⁰X⁹»^⊖

[MLXZ]𝘲 class:

[MX₉]^-

MLXZ class (ENC, equivalent neutral class):

MX₈L₁

[Os(Cl)(Dppe-κ²P)₂]⊕

Formula Unicode styled:

[Os(Cl)(Dppe-κ²P)₂]⊕

Compound name(s):

Chloro-bis(1,2-bis-(diphenylphosphino)ethane-P,P')-osmium(1+)

Central atom:

Attached groups:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁵O^IIE¹⁶B⁵Z⁰X¹L⁴»^⊕

[MLXZ]𝘲 class:

[MX₁L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Os(Cl)(CO)(≡CTol)(PPh₃)₂]

Formula Unicode styled:

[Os(Cl)(CO)(≡CTol)(PPh₃)₂]

Compound name(s):

Carbonyl-chloro-bis(triphenylphosphine)-p-tolylmethylidyne-osmium

Central atom:

Attached groups:

≡CTol (tolylmethylidyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁴C⁵O^IVE¹⁸B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Os(CO)(C₂H₄)₂(PMe₃)₂]

Formula Unicode styled:

[Os(CO)(C₂H₄)₂(PMe₃)₂]

Compound name(s):

Carbonyl-bis(η-ethylene)-bis(trimethylphosphine)-osmium

Central atom:

Attached groups:

PMe₃ (trimethylphosphane)

C₂H₄ (ethene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Os(CO)(C₆H₁₀)(η⁶-C₆H₃Me₃)]

Formula Unicode styled:

[Os(CO)(C₆H₁₀)(η⁶-C₆H₃Me₃)]

Compound name(s):

Carbonyl-(η-cyclohexene)-(η-mesitylene)-osmium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

cis–[Os(Mes)(ONO₂-κO)₂(O)₂]⊖

Formula Unicode styled:

cis–[Os(Mes)(ONO₂-κO)₂(O)₂]⊖

Compound name(s):

bis(nitrato-O)-dioxo-(2,4,6-trimethylphenyl)-osmium(1-)

Central atom:

Attached groups:

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

PBuᵗ₂Me (methyl-di-t-butylphosphane)

Summary of calculated classifications:

Os«V⁶C⁵O^VIE¹⁶B⁷Z⁰L⁰X⁷»^⊖

[MLXZ]𝘲 class:

[MX₇]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

trans–[Os(H)(OH)(CO)(PBuᵗ₂Me)₂]

Formula Unicode styled:

trans–[Os(H)(OH)(CO)(PBuᵗ₂Me)₂]

Compound name(s):

bis(Di-t-butyl-methylphosphine)-carbonyl-hydrido-hydroxy-osmium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁵O^IIE¹⁶B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Os(Se₂)(CO)₂(PPh₃)₂]

Formula Unicode styled:

[Os(Se₂)(CO)₂(PPh₃)₂]

Compound name(s):

bis(Carbonyl)-di-selenium-bis(triphenylphosphine)-osmium

Central atom:

Attached groups:

Se₂ (perseleno-κ²Se)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 6

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

trans–[Os(Br)₂(PPh₃)₂(O₂CMe)]

Formula Unicode styled:

trans–[Os(Br)₂(PPh₃)₂(O₂CMe)]

Compound name(s):

(Acetato-O,O')-dibromo-bis(triphenylphosphine)-osmium

Central atom:

Attached groups:

Br (bromo)

O₂CMe (acetato-κ²O)

Charge on central atom:

0

Compound type: