5-coordinate: trigonal bipyramid (TBPY-5)

axial–[Ti(Me)₄(OEt₂)]

Formula Unicode styled: 
axial–[Ti(Me)₄(OEt₂)]
Compound name(s): 
Tetramethyl-(diethyl ether)-titanium
Central atom: 
Titanium
Attached groups: 
Me (methyl)
OEt₂ (diethylether)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 10
Summary of calculated classifications: 
Ti«V4C5OIVE10B5Z0X4L1»
[MLXZ]𝘲 class: 
[MX4L1]
MLXZ class (ENC, equivalent neutral class): 
MX4L1

axial–[Ti(Cl)₄(AsPh₃)]

Formula Unicode styled: 
axial–[Ti(Cl)₄(AsPh₃)]
Compound name(s): 
Tetrachloro-(triphenylarsine)-titanium
Central atom: 
Titanium
Attached groups: 
Cl (chloro)
AsPh₃ (triphenylarsane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 10
Summary of calculated classifications: 
Ti«V4C5OIVE10B5Z0X4L1»
[MLXZ]𝘲 class: 
[MX4L1]
MLXZ class (ENC, equivalent neutral class): 
MX4L1

[V(O)(S₂)₂(Bpy)]⊖

Formula Unicode styled: 
[V(O)(S₂)₂(Bpy)]⊖
Compound name(s): 
(2,2'-bipyridine-N,N')-bis(persulfide)-oxo-vanadium(1-)
Central atom: 
Vanadium
Attached groups: 
O (oxo X₂)
S₂ (disulfanediyl-κ²S)
Bpy (bipyridine)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
V«V5C7OVE16B8Z0X6L2»⊖
[MLXZ]𝘲 class: 
[MX6L2]-
MLXZ class (ENC, equivalent neutral class): 
MX5L3

[V(O)(OH₂){N(CH₂CO₂)₃-κN,κ³O}]⊖

Formula Unicode styled: 
[V(O)(OH₂){N(CH₂CO₂)₃-κN,κ³O}]⊖
Compound name(s): 
aqua-(2,2',2''-nitrilotriacetato)-oxo-vanadium(1-)
Central atom: 
Vanadium
Attached groups: 
O (oxo X₂)
OH₂ (aqua)
Nta (2,2',2''-nitrilotriacetato-κN,κ³O)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 15
Summary of calculated classifications: 
V«V4C6OIVE15B7Z0X5L2»⊖
[MLXZ]𝘲 class: 
[MX5L2]-
MLXZ class (ENC, equivalent neutral class): 
MX4L3

[V(O)(O₂)₂(Phen)]⊖

Formula Unicode styled: 
[V(O)(O₂)₂(Phen)]⊖
Compound name(s): 
oxo-bis(peroxo)-(1,10-phenanthroline)-vanadium(1-)
Central atom: 
Vanadium
Attached groups: 
O (oxo X₂)
O₂ (peroxo)
Phen (phenanthroline)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
V«V5C5OVE16B8Z0X6L2»⊖
[MLXZ]𝘲 class: 
[MX6L2]-
MLXZ class (ENC, equivalent neutral class): 
MX5L3

[V(O)(O₂)₂(Bpy)]⊖

Formula Unicode styled: 
[V(O)(O₂)₂(Bpy)]⊖
Compound name(s): 
(2,2'-bipyridine)-oxo-diperoxo-vanadium(1-)
Central atom: 
Vanadium
Attached groups: 
O (oxo X₂)
O₂ (peroxo)
Bpy (bipyridine)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
V«V5C5OVE16B8Z0X6L2»⊖
[MLXZ]𝘲 class: 
[MX6L2]-
MLXZ class (ENC, equivalent neutral class): 
MX5L3

[V(I)(PMe₃)₂(⭀NBuᵗ)₂]

Formula Unicode styled: 
[V(I)(PMe₃)₂(⭀NBuᵗ)₂]
Compound name(s): 
bis(t-butylimino)-iodo-bis(trimethylphosphine)-vanadium
Central atom: 
Vanadium
Attached groups: 
I (iodo)
PMe₃ (trimethylphosphane)
⭀NBuᵗ (⭀N t-butylimino)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
V«V5C5OVE18B9Z0X5L4»
[MLXZ]𝘲 class: 
[MX5L4]
MLXZ class (ENC, equivalent neutral class): 
MX5L4

[V(F)(O)₂(Ox)]²⊖

Formula Unicode styled: 
[V(F)(O)₂(Ox)]²⊖
Compound name(s): 
dioxofluorooxalatovanadium(2-)
Central atom: 
Vanadium
Attached groups: 
F (fluoro)
O (oxo X₂)
Ox (oxalato)
Charge on central atom: 
-2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
V«V5C5OVE14B7Z0L0X7»2⊖
[MLXZ]𝘲 class: 
[MX7]2-
MLXZ class (ENC, equivalent neutral class): 
MX5L2

[V(Cl)(O)₂(Py)₂]

Formula Unicode styled: 
[V(Cl)(O)₂(Py)₂]
Compound name(s): 
Chloro-dioxo-dipyridine-vanadium
Central atom: 
Vanadium
Attached groups: 
Cl (chloro)
O (oxo X₂)
Py (pyridine)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
V«V5C5OVE14B7Z0X5L2»
[MLXZ]𝘲 class: 
[MX5L2]
MLXZ class (ENC, equivalent neutral class): 
MX5L2

[V(Cl)₅]⊖

Formula Unicode styled: 
[V(Cl)₅]⊖
Compound name(s): 
pentachlorovanadium(1-)
Central atom: 
Vanadium
Attached groups: 
Cl (chloro)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 11
Summary of calculated classifications: 
V«V4C5OIVE11B5Z0L0X5»⊖
[MLXZ]𝘲 class: 
[MX5]-
MLXZ class (ENC, equivalent neutral class): 
MX4L1

[V(Cl)₄]²⊖

Formula Unicode styled: 
[V(Cl)₄]²⊖
Compound name(s): 
tetrachloro-oxovanadium(2-)
Central atom: 
Vanadium
Attached groups: 
Cl (chloro)
Charge on central atom: 
-2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 4
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 11
Summary of calculated classifications: 
V«V2C4OIIE11B4Z0L0X4»2⊖
[MLXZ]𝘲 class: 
[MX4]2-
MLXZ class (ENC, equivalent neutral class): 
MX2L2

[V(Cl)₂(Py)₂(N)]

Formula Unicode styled: 
[V(Cl)₂(Py)₂(N)]
Compound name(s): 
Dichloro-nitrilo-dipyridyl-vanadium
Central atom: 
Vanadium
Attached groups: 
Cl (chloro)
Py (pyridine)
N (nitrido; ≡N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
V«V5C5OVE14B7Z0X5L2»
[MLXZ]𝘲 class: 
[MX5L2]
MLXZ class (ENC, equivalent neutral class): 
MX5L2

[V(Cl)₂(O){P(SiMe₃)₃}]

Formula Unicode styled: 
[V(Cl)₂(O){P(SiMe₃)₃}]
Compound name(s): 
Dichloro-oxo-bis(tris(trimethylsilyl)phosphine)-vanadium
Central atom: 
Vanadium
Attached groups: 
Cl (chloro)
O (oxo X₂)
P(SiMe₃)₃ (tris-(trimethylsilyl)-phosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 4
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 11
Summary of calculated classifications: 
V«V4C4OIVE11B5Z0X4L1»
[MLXZ]𝘲 class: 
[MX4L1]
MLXZ class (ENC, equivalent neutral class): 
MX4L1

[V(Cl)₂(O)(NMe₃)₂]

Formula Unicode styled: 
[V(Cl)₂(O)(NMe₃)₂]
Compound name(s): 
dichloro-bis(trimethylamine)-oxo-vanadium
Central atom: 
Vanadium
Attached groups: 
Cl (chloro)
O (oxo X₂)
NMe₃ (trimethylamine)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 13
Summary of calculated classifications: 
V«V4C5OIVE13B6Z0X4L2»
[MLXZ]𝘲 class: 
[MX4L2]
MLXZ class (ENC, equivalent neutral class): 
MX4L2

[V(Cl)₂{O(CH₂CH₂S)₂}]⊖

Formula Unicode styled: 
[V(Cl)₂{O(CH₂CH₂S)₂}]⊖
Compound name(s): 
dichloro-(2,2-oxydiethanethiolato)-vanadium(1-)
Central atom: 
Vanadium
Attached groups: 
Cl (chloro)
O(CH₂CH₂S)₂ (2,2-oxydiethanethiolato)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 12
Summary of calculated classifications: 
V«V3C5OIIIE12B5Z0X4L1»⊖
[MLXZ]𝘲 class: 
[MX4L1]-
MLXZ class (ENC, equivalent neutral class): 
MX3L2

[V(Cl)(OC₆H₃Prⁱ₂-2,6)₂(Thf)₂]

Formula Unicode styled: 
[V(Cl)(OC₆H₃Prⁱ₂-2,6)₂(Thf)₂]
Compound name(s): 
Chloro-bis(2,6-di-isopropylphenoxy)-bis(tetrahydrofuran)-vanadium
Central atom: 
Vanadium
Attached groups: 
Cl (chloro)
OC₆H₃Prⁱ₂-2,6 (di-isopropylphenoxy-2,6)
Thf (tetrahydrofuran)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 12
Summary of calculated classifications: 
V«V3C5OIIIE12B5Z0X3L2»
[MLXZ]𝘲 class: 
[MX3L2]
MLXZ class (ENC, equivalent neutral class): 
MX3L2

[V(Cl)(⭀NPh)₂(PMe₃)₂]

Formula Unicode styled: 
[V(Cl)(⭀NPh)₂(PMe₃)₂]
Compound name(s): 
chloro-bis(phenylimino)-bis(trimethylphosphine)-vanadium
Central atom: 
Vanadium
Attached groups: 
Cl (chloro)
⭀NPh (phenylimino)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
V«V5C5OVE18B9Z0X5L4»
[MLXZ]𝘲 class: 
[MX5L4]
MLXZ class (ENC, equivalent neutral class): 
MX5L4

[V(Cl)(⭀NBuᵗ)₂(Py)₂]

Formula Unicode styled: 
[V(Cl)(⭀NBuᵗ)₂(Py)₂]
Compound name(s): 
bis(t-butylimino)-chloro-bis(pyridine)-vanadium
Central atom: 
Vanadium
Attached groups: 
Cl (chloro)
⭀NBuᵗ (⭀N t-butylimino)
Py (pyridine)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
V«V5C5OVE18B9Z0X5L4»
[MLXZ]𝘲 class: 
[MX5L4]
MLXZ class (ENC, equivalent neutral class): 
MX5L4

[V(Cl)(⭀NBuᵗ)₂(PMe₃)₂]

Formula Unicode styled: 
[V(Cl)(⭀NBuᵗ)₂(PMe₃)₂]
Compound name(s): 
bis(t-butylimino)-chloro-bis(trimethylphosphine)-vanadium
Central atom: 
Vanadium
Attached groups: 
Cl (chloro)
⭀NBuᵗ (⭀N t-butylimino)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
V«V5C5OVE18B9Z0X5L4»
[MLXZ]𝘲 class: 
[MX5L4]
MLXZ class (ENC, equivalent neutral class): 
MX5L4

[V(Cl)(⭀NBuᵗ)₂(PMe₂Ph)₂]

Formula Unicode styled: 
[V(Cl)(⭀NBuᵗ)₂(PMe₂Ph)₂]
Compound name(s): 
bis(t-butylimino)-chloro-bis(dimethyl(phenyl)phosphine)-vanadium
Central atom: 
Vanadium
Attached groups: 
Cl (chloro)
⭀NBuᵗ (⭀N t-butylimino)
PMe₂Ph (dimethylphenylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
V«V5C5OVE18B9Z0X5L4»
[MLXZ]𝘲 class: 
[MX5L4]
MLXZ class (ENC, equivalent neutral class): 
MX5L4