5-coordinate: trigonal bipyramid (TBPY-5)

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^IIE¹⁴B⁷X⁵L¹Z¹»^⊖

[MLXZ]𝘲 class:

[MX₅L₁Z₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[Cr(CO)₄(NO)]⊖

Formula Unicode styled:

[Cr(CO)₄(NO)]⊖

Compound name(s):

tetracarbonyl-nitrosyl-chromium(1-)

Central atom:

Chromium

Attached groups:

CO (carbonyl)

NO (nitrosyl, linear)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (-II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cr«V²C⁵O^-IIE¹⁸B⁷X¹L⁵Z¹»^⊖

[MLXZ]𝘲 class:

[MX₁L₅Z₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Cr(=NBuᵗ)₂(Terpy-κ³N)]²⊕

Formula Unicode styled:

[Cr(=NBuᵗ)₂(Terpy-κ³N)]²⊕

Compound name(s):

bis(t-Butylimido)-(2,2':6',2''-terpyridine)-chromium(2+)

Central atom:

Chromium

Attached groups:

=NBuᵗ (t-butylimino)

Terpy (terpyridine-κ³N)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cr«V⁶C⁵O^VIE¹⁴B⁷Z⁰X⁴L³»^2⊕

[MLXZ]𝘲 class:

[MX₄L₃]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[Mo(Br)(CH₂Buᵗ)₃(=NH)]

Formula Unicode styled:

[Mo(Br)(CH₂Buᵗ)₃(=NH)]

Compound name(s):

Bromo-tris(neopentyl)-imido-molybdenum

Central atom:

Attached groups:

Br (bromo)

CH₂Buᵗ (t-butylmethyl)

=NH (imino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁵O^VIE¹⁴B⁷Z⁰X⁶L¹»

[MLXZ]𝘲 class:

[MX₆L₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[Mo(Cl)(CH₂SiMe₃)₃(PMe₃)]

Formula Unicode styled:

[Mo(Cl)(CH₂SiMe₃)₃(PMe₃)]

Compound name(s):

Chloro-trimethylphosphine-tris(trimethylsilylmethyl)-molybdenum

Central atom:

CH₂SiMe₃ (trimethylsilylmethyl)

Attached groups:

Cl (chloro)

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 12

Summary of calculated classifications:

Mo«V⁴C⁵O^IVE¹²B⁵Z⁰X⁴L¹»

[MLXZ]𝘲 class:

[MX₄L₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₁

[Mo{OC(CF₃)₃}₄(O)]

Formula Unicode styled:

[Mo{OC(CF₃)₃}₄(O)]

Compound name(s):

tetrakis(t-Perfluorobutoxy)-oxo-molybdenum

Central atom:

OC(CF₃)₃ (perfluorobutoxy)

Attached groups:

O (oxo ⭀O X₂L)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁵O^VIE¹⁴B⁷Z⁰X⁶L¹»

[MLXZ]𝘲 class:

[MX₆L₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[Mo(SPh)₄(NO)]⊖

Formula Unicode styled:

[Mo(SPh)₄(NO)]⊖

Compound name(s):

nitrosyl-tetrakis(thiophenolato)-molybdenum(1-)

Central atom:

Attached groups:

SPh (phenylthio)

NO (nitrosyl, linear)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁵O^IIE¹⁴B⁷X⁵L¹Z¹»^⊖

[MLXZ]𝘲 class:

[MX₅L₁Z₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[Mo(SBuᵗ)₂(CNBuᵗ)₂(PhC≡CPh)]

Formula Unicode styled:

[Mo(SBuᵗ)₂(CNBuᵗ)₂(PhC≡CPh)]

Compound name(s):

(η-Diphenylacetylene)-bis(t-butylcyano)-bis(t-butylthio)-molybdenum

Central atom:

CNBuᵗ (t-butyl isocyanide)

Attached groups:

SBuᵗ (t-butylthio)

PhC≡CPh (diphenylethyne L₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V²C⁵O^IIE¹⁶B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Mo(SBuᵗ)₂(CNBuᵗ)₂(HC≡CH)]

Formula Unicode styled:

[Mo(SBuᵗ)₂(CNBuᵗ)₂(HC≡CH)]

Compound name(s):

(η-Acetylene)-bis(t-butylcyano)-bis(t-butylthio)-molybdenum

Central atom:

CNBuᵗ (t-butyl isocyanide)

Attached groups:

SBuᵗ (t-butylthio)

HC≡CH (ethyne L₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V²C⁵O^IIE¹⁶B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Mo(O)₃(CO₃-κ²O)]²⊖

Formula Unicode styled:

[Mo(O)₃(CO₃-κ²O)]²⊖

Compound name(s):

(carbonato-O,O')-trioxo-molybdenum(2-)

Central atom:

Attached groups:

O (oxo X₂)

CO₃ (carbonato-κ²O)

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁵O^VIE¹⁶B⁸Z⁰L⁰X⁸»^2⊖

[MLXZ]𝘲 class:

[MX₈]^2-

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Mo(O)(O₂)₂(Ox)]²⊖

Formula Unicode styled:

[Mo(O)(O₂)₂(Ox)]²⊖

Compound name(s):

(oxalato-O,O')-oxo-bis(peroxo-O,O')-molybdenum(2-)

Central atom:

Attached groups:

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁵O^VIE¹⁸B⁹Z⁰X⁸L¹»^2⊖

[MLXZ]𝘲 class:

[MX₈L₁]^2-

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[Mo(O)(O₂)₂(O₂CPh-κ²O)]⊖

Formula Unicode styled:

[Mo(O)(O₂)₂(O₂CPh-κ²O)]⊖

Compound name(s):

benzoato-oxo-diperoxo-molybdenum(1-)

Central atom:

Attached groups:

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁵O^VIE¹⁸B⁹Z⁰X⁷L²»^⊖

[MLXZ]𝘲 class:

[MX₇L₂]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[Mo(O)(O₂)₂(OPy)₂]

Formula Unicode styled:

[Mo(O)(O₂)₂(OPy)₂]

Compound name(s):

bis(Peroxo)-bis(pyridine-N-oxide)-oxo-molybdenum

Central atom:

Attached groups:

O (oxo ⭀O X₂L)

O₂ (peroxo)

OPy (Pyridine-N-oxide)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁵O^VIE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[Mo(MeC≡CMe)(Dppe-κ²P)₂]

Formula Unicode styled:

[Mo(MeC≡CMe)(Dppe-κ²P)₂]

Compound name(s):

(η-But-2-yne)-bis(1,2-bis(diphenylphosphino)ethane)-molybdenum

Central atom:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Attached groups:

MeC≡CMe (butyne L₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁰C⁵O^OE¹⁸B⁶Z⁰X⁰L⁶»

[MLXZ]𝘲 class:

[ML₆]

MLXZ class (ENC, equivalent neutral class):

ML₆

trans–[Nb(Cl)₂(Me)₃]

Formula Unicode styled:

trans–[Nb(Cl)₂(Me)₃]

Compound name(s):

Dichloro-trimethyl-niobium

Central atom:

Attached groups:

Cl (chloro)

Me (methyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁵O^VE¹⁰B⁵Z⁰L⁰X⁵»

[MLXZ]𝘲 class:

[MX₅]

MLXZ class (ENC, equivalent neutral class):

MX₅

trans–[Nb(Br)₂(NPh₂)₃]

Formula Unicode styled:

trans–[Nb(Br)₂(NPh₂)₃]

Compound name(s):

Dibromo-tris(diphenylamido)-niobium

Central atom:

NPh₂ (diphenylamino: planar)

Attached groups:

Br (bromo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁵O^VE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

trans–[Nb(OC₆H₃Ph₂-2,6)₃(CH₂Tol)₂]

Formula Unicode styled:

trans–[Nb(OC₆H₃Ph₂-2,6)₃(CH₂Tol)₂]

Compound name(s):

bis(4-Methylbenzyl)-tris(2,6-diphenylphenoxy)-niobium

Central atom:

OC₆H₃Ph₂-2,6 (diphenylphenoxy-2,6)

Attached groups:

CH₂Tol (tolylmethyl-κC)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

OSi(SiMe₃)₃ (tris-(trimethylsilyl)-siloxy)

Summary of calculated classifications:

Nb«V⁵C⁵O^VE¹⁰B⁵Z⁰L⁰X⁵»

[MLXZ]𝘲 class:

[MX₅]

MLXZ class (ENC, equivalent neutral class):

MX₅

[Ta{OSi(SiMe₃)₃}₃(OHEt)₂]

Formula Unicode styled:

[Ta{OSi(SiMe₃)₃}₃(OHEt)₂]

Compound name(s):

bis(ethanolato)-tris(tris(trimethylsilyl)silanolato)-tantalum

Central atom:

Tantalum

Attached groups:

OHEt (ethanol)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 12

Summary of calculated classifications:

Ta«V³C⁵O^IIIE¹²B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Nb(SXylyl)₅]

Formula Unicode styled:

[Nb(SXylyl)₅]

Compound name(s):

pentakis(2,6-Dimethylphenylthiolato)-niobium

Central atom:

Attached groups:

SXylyl (xylylthio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁵O^VE¹⁰B⁵Z⁰L⁰X⁵»

[MLXZ]𝘲 class:

[MX₅]

MLXZ class (ENC, equivalent neutral class):

MX₅

[Nb(OXylyl)₅]

Formula Unicode styled:

[Nb(OXylyl)₅]

Compound name(s):

pentakis(2,6-Dimethylphenoxide-O)-niobium

Central atom:

Attached groups:

OXylyl (xylyloxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: