5-coordinate: trigonal bipyramid (TBPY-5)

Attached groups:

NO₃ (nitrato-κO)

Py (pyridine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cu«V²C⁵O^IIE¹⁹B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Cu(OH₂)(Bpy)₂]²⊕

Formula Unicode styled:

[Cu(OH₂)(Bpy)₂]²⊕

Compound name(s):

Aqua-bis(2,2'-bipyridyl)-copper(2+)

Central atom:

Attached groups:

OH₂ (aqua)

Bpy (bipyridine)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cu«V²C⁵O^IIE¹⁹B⁵Z⁰X⁰L⁵»^2⊕

[MLXZ]𝘲 class:

[ML₅]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Cu(NH₃)(Bpy)₂]²⊕

Formula Unicode styled:

[Cu(NH₃)(Bpy)₂]²⊕

Compound name(s):

Ammine-bis(2,2'-bipyridyl)-copper(2+)

Central atom:

Attached groups:

NH₃ (ammine)

Bpy (bipyridine)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cu«V²C⁵O^IIE¹⁹B⁵Z⁰X⁰L⁵»^2⊕

[MLXZ]𝘲 class:

[ML₅]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Cu(NCS-κN)(Tn)₂]⊕

Formula Unicode styled:

[Cu(NCS-κN)(Tn)₂]⊕

Compound name(s):

bis(1,3-Diaminopropane)isothiocyanato copper(1+)

Central atom:

Attached groups:

NCS (isothiocyanato-κN)

Tn (1,3-diaminopropane)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cu«V²C⁵O^IIE¹⁹B⁵Z⁰X¹L⁴»^⊕

[MLXZ]𝘲 class:

[MX₁L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Cu(NCS-κN)(Tren-κ⁴N)]⊕

Formula Unicode styled:

[Cu(NCS-κN)(Tren-κ⁴N)]⊕

Compound name(s):

Isothiocyanato-(2,2',2''-triaminotriethylamine)-copper(1+)

Central atom:

Tren (tris(2-aminoethyl)amine-κ⁴N)

Attached groups:

NCS (isothiocyanato-κN)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cu«V²C⁵O^IIE¹⁹B⁵Z⁰X¹L⁴»^⊕

[MLXZ]𝘲 class:

[MX₁L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Cu(CN)(Tren-κ⁴N)]⊕

Formula Unicode styled:

[Cu(CN)(Tren-κ⁴N)]⊕

Compound name(s):

Cyano-(2,2',2''-triamino-triethylamine)-copper(1+)

Central atom:

Tren (tris(2-aminoethyl)amine-κ⁴N)

Attached groups:

CN (cyano-κC)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cu«V²C⁵O^IIE¹⁹B⁵Z⁰X¹L⁴»^⊕

[MLXZ]𝘲 class:

[MX₁L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Cu(CN)(Phen)₂]⊕

Formula Unicode styled:

[Cu(CN)(Phen)₂]⊕

Compound name(s):

Cyano-bis(1,10-phenanthroline) copper(1+)

Central atom:

Attached groups:

CN (cyano-κC)

Phen (phenanthroline)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cu«V²C⁵O^IIE¹⁹B⁵Z⁰X¹L⁴»^⊕

[MLXZ]𝘲 class:

[MX₁L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Cu(CN)(Bpy)₂]⊕

Formula Unicode styled:

[Cu(CN)(Bpy)₂]⊕

Compound name(s):

bis(2,2'-Bipyridyl)-cyano-copper(1+)

Central atom:

Attached groups:

CN (cyano-κC)

Bpy (bipyridine)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cu«V²C⁵O^IIE¹⁹B⁵Z⁰X¹L⁴»^⊕

[MLXZ]𝘲 class:

[MX₁L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Tc(Ph)₂(PPh₃)₂(N)]

Formula Unicode styled:

[Tc(Ph)₂(PPh₃)₂(N)]

Compound name(s):

Nitrido-diphenyl-bis(triphenylphosphine)-technetium

Central atom:

Technetium

Attached groups:

Ph (phenyl)

N (nitrido; ≡N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁵O^VE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Tc(Cl)(Dppe-κ²P)₂]

Formula Unicode styled:

[Tc(Cl)(Dppe-κ²P)₂]

Compound name(s):

Chloro-bis(1,2-bis(diphenylphosphino)ethane)-technetium

Central atom:

Technetium

Attached groups:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

OCH₂CH₂S (2-thio-ethanediolato-κO,κS)

Summary of calculated classifications:

Tc«V¹C⁵O^IE¹⁶B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Tc(O)(OCH₂CH₂S)₂]⊖

Formula Unicode styled:

[Tc(O)(OCH₂CH₂S)₂]⊖

Compound name(s):

bis(2-mercaptoethanolato)-oxo-technetium(1-)

Central atom:

Technetium

Attached groups:

O (oxo ⭀O X₂L)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁵O^VE¹⁶B⁷Z⁰X⁶L¹»^⊖

[MLXZ]𝘲 class:

[MX₆L₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

trans–[Os(Cl)(=CH₂)(PPh₃)₂(NO)]

Formula Unicode styled:

trans–[Os(Cl)(=CH₂)(PPh₃)₂(NO)]

Compound name(s):

Chloro-methylene-nitroso-bis(triphenylphosphine)-osmium

Central atom:

Attached groups:

=CH₂ (methylidene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁵O^IIE¹⁸B⁸X⁴L³Z¹»

[MLXZ]𝘲 class:

[MX₄L₃Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Os(Cl)(SC₆F₅)₃(PMe₂Ph)]

Formula Unicode styled:

[Os(Cl)(SC₆F₅)₃(PMe₂Ph)]

Compound name(s):

Chloro-(dimethylphenylphosphine)-tris(pentafluorobenzenethiolato-S)-osmium

Central atom:

Attached groups:

SC₆F₅ (pentafluorothiophenyl)

PMe₂Ph (dimethylphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Os«V⁴C⁵O^IVE¹⁴B⁵Z⁰X⁴L¹»

[MLXZ]𝘲 class:

[MX₄L₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₁

[Os(Cl)(PPh₃)₂(NO)₂]⊕

Formula Unicode styled:

[Os(Cl)(PPh₃)₂(NO)₂]⊕

Compound name(s):

Chloro-dinitrosyl-bis(triphenylphosphine-P)-osmium(1+)

Central atom:

Attached groups:

(NO)₂ (dinitrosyl, (N≡O)₂ TBPY-eq Ⓢ)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁴C⁵O^OE¹⁸B⁷Z⁰X³L⁴»^⊕

[MLXZ]𝘲 class:

[MX₃L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Os(CO)₂(PPh₃)₂(NO)]⊕

Formula Unicode styled:

[Os(CO)₂(PPh₃)₂(NO)]⊕

Compound name(s):

Dicarbonyl-nitrosyl-bis(triphenylphosphine)-osmium(1+)

Central atom:

Attached groups:

CO (carbonyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁴C⁵O^OE¹⁸B⁷X¹L⁵Z¹»^⊕

[MLXZ]𝘲 class:

[MX₁L₅Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Os(CO)(CNTol)(PPh₃)₂(NO)]⊕

Formula Unicode styled:

[Os(CO)(CNTol)(PPh₃)₂(NO)]⊕

Compound name(s):

Carbonyl-nitrosyl-(p-tolylisocyanide)-bis(triphenylphosphine)-osmium(1+)

Central atom:

Attached groups:

CO (carbonyl)

CNTol (tolyl isocyanide)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁴C⁵O^OE¹⁸B⁷X¹L⁵Z¹»^⊕

[MLXZ]𝘲 class:

[MX₁L₅Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

axial–[Os(SC₆F₅)₄(PPh₃)]

Formula Unicode styled:

axial–[Os(SC₆F₅)₄(PPh₃)]

Compound name(s):

tetrakis(Pentafluorobenzenethiolato-S)-(triphenylphosphine-P)-osmium

Central atom:

SC₆F₅ (pentafluorothiophenyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Os«V⁴C⁵O^IVE¹⁴B⁵Z⁰X⁴L¹»

[MLXZ]𝘲 class:

[MX₄L₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₁

trans–[Re(I)(O)₂(PPh₃)₂]

Formula Unicode styled:

trans–[Re(I)(O)₂(PPh₃)₂]

Compound name(s):

Iodo-dioxo-bis(triphenylphosphine)-rhenium

Central atom:

Rhenium

Attached groups:

I (iodo)

O (oxo X₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁵O^VE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

trans–[Re(CO)(PhC≡CPh)(NO)(PEt₃)₂]

Formula Unicode styled:

trans–[Re(CO)(PhC≡CPh)(NO)(PEt₃)₂]

Compound name(s):

(η²-Diphenylacetylene)-trans-bis(triethylphosphine)-carbonyl-nitrosyl-rhenium

Central atom:

Rhenium

Attached groups:

CO (carbonyl)

PhC≡CPh (diphenylethyne)

PEt₃ (triethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (-I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V³C⁵O^-IE¹⁸B⁷X¹L⁵Z¹»

[MLXZ]𝘲 class:

[MX₁L₅Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[W(Cl)₂(=NSiMe₃)₂(PMePh₂)]

Formula Unicode styled:

[W(Cl)₂(=NSiMe₃)₂(PMePh₂)]

Compound name(s):

Dichloro-bis(trimethylsilylimido)-diphenylmethylphosphine-tungsten

Central atom:

Tungsten

Attached groups:

=NSiMe₃ (trimethylsilylimino)

PMePh₂ (methyldiphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):