5-coordinate: trigonal bipyramid (TBPY-5)

Attached groups:

O=C(NHMe)₂ (dimethylurea)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V²C⁵O^IIE¹⁵B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Mn(Br)₂(Mes)(PMe₃)₂]

Formula Unicode styled:

[Mn(Br)₂(Mes)(PMe₃)₂]

Compound name(s):

Dibromo-mesityl-bis(trimethylphosphine)-manganese

Central atom:

Attached groups:

PMe₃ (trimethylphosphane)

Mes (mesityl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Mn«V³C⁵O^IIIE¹⁴B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Mn(Br)(Tren-Me₆-κ⁴N)]⊕

Formula Unicode styled:

[Mn(Br)(Tren-Me₆-κ⁴N)]⊕

Compound name(s):

Bromo-tris(2-dimethylaminoethyl)amine-manganese(1+)

Central atom:

Attached groups:

Tren-Me₆ (tris(2-dimethylaminoethyl)amine-κ⁴N)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V²C⁵O^IIE¹⁵B⁵Z⁰X¹L⁴»^⊕

[MLXZ]𝘲 class:

[MX₁L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Mn{PPh(OMe)₂}₃(NO)₂]⊕

Formula Unicode styled:

[Mn{PPh(OMe)₂}₃(NO)₂]⊕

Compound name(s):

Dinitrosyl-tris(dimethylphenylphosphonito)-manganese(1+)

Central atom:

PPh(OMe)₂ (dimethyl-phenyl-phosphonito)

Attached groups:

(NO)₂ (dinitrosyl, (N≡O)₂ TBPY-eq Ⓢ)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V³C⁵O^-IE¹⁸B⁷Z⁰X²L⁵»^⊕

[MLXZ]𝘲 class:

[MX₂L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Mn(Se₅)(Terpy-κ³N)]

Formula Unicode styled:

[Mn(Se₅)(Terpy-κ³N)]

Compound name(s):

(2,2':6',2''-Terpyridyl)-(pentaselenide-Se,Se'''')-manganese

Central atom:

Attached groups:

Se₅ (pentaseleno-κ²Se)

Terpy (terpyridine-κ³N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V²C⁵O^IIE¹⁵B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Mn(NCS-κN)₅]³⊖

Formula Unicode styled:

[Mn(NCS-κN)₅]³⊖

Compound name(s):

pentakis(isothiocyanato)-manganese(3-)

Central atom:

Attached groups:

NCS (isothiocyanato-κN)

Charge on central atom:

-3

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V²C⁵O^IIE¹⁵B⁵Z⁰L⁰X⁵»^3⊖

[MLXZ]𝘲 class:

[MX₅]^3-

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Mn(NCS-κN)₂(Terpy-κ³N)]

Formula Unicode styled:

[Mn(NCS-κN)₂(Terpy-κ³N)]

Compound name(s):

bis(Isothiocyanato)-(2,2':6',2''-terpyridyl)-manganese

Central atom:

Attached groups:

NCS (isothiocyanato-κN)

Terpy (terpyridine-κ³N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V²C⁵O^IIE¹⁵B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Mn(CO)₅]⊖

Formula Unicode styled:

[Mn(CO)₅]⊖

Compound name(s):

pentacarbonyl-manganese(1-)

Central atom:

(CO)₅ (pentacarbonyl, (C≡O)₅ trigonal bipyramidal Ⓢ)

Attached groups:

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V³C⁵O^-IE¹⁸B⁷X⁰L⁵Z²»^⊖

[MLXZ]𝘲 class:

[ML₅Z₂]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Mn(CO)₄(NO)]

Formula Unicode styled:

[Mn(CO)₄(NO)]

Compound name(s):

Tetracarbonylnitrosylmanganese

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V³C⁵O^-IE¹⁸B⁷X¹L⁵Z¹»

[MLXZ]𝘲 class:

[MX₁L₅Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Mn(CO)₃(PPh₃)(NO)]

Formula Unicode styled:

[Mn(CO)₃(PPh₃)(NO)]

Compound name(s):

Nitrosyl-tricarbonyl-triphenylphosphine-manganese

Central atom:

Attached groups:

PPh₃ (triphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V³C⁵O^-IE¹⁸B⁷X¹L⁵Z¹»

[MLXZ]𝘲 class:

[MX₁L₅Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Mn(CO)₂(PPh₃)₂(NO)]

Formula Unicode styled:

[Mn(CO)₂(PPh₃)₂(NO)]

Compound name(s):

Nitrosyldicarbonyl-bis(triphenylphosphine)-manganese

Central atom:

Attached groups:

PPh₃ (triphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V³C⁵O^-IE¹⁸B⁷X¹L⁵Z¹»

[MLXZ]𝘲 class:

[MX₁L₅Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Mn(CO)₂(PHPh₂)₂(NO)]

Formula Unicode styled:

[Mn(CO)₂(PHPh₂)₂(NO)]

Compound name(s):

Dicarbonyl-nitrosyl-bis(diphenylphosphino)-manganese

Central atom:

Attached groups:

PHPh₂ (diphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V³C⁵O^-IE¹⁸B⁷X¹L⁵Z¹»

[MLXZ]𝘲 class:

[MX₁L₅Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

catena–1D-[Mn(μ₂-I)₂(PMe₂Ph)]

Formula Unicode styled:

catena–1D-[Mn(μ₂-I)₂(PMe₂Ph)]

Compound name(s):

catena-[bis(μ₂-Iodo)-dimethylphenylphosphino-manganese]

Central atom:

PMe₂Ph (dimethylphenylphosphane)

Attached groups:

I (μ₂-iodo)

Charge on central atom:

0

Compound type:

Catena-1D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V²C⁵O^IIE¹⁵B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

axial–[Mn(CO)₄(PPh₃)]⊖

Formula Unicode styled:

axial–[Mn(CO)₄(PPh₃)]⊖

Compound name(s):

tetracarbonyl-triphenylphosphine-manganese(1-)

Central atom:

(CO)₄ (tetracarbonyl, (C≡O)₄ trigonal bipyramidal C3v Ⓢ)

Attached groups:

PPh₃ (triphenylphosphane)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V³C⁵O^-IE¹⁸B⁷X⁰L⁵Z²»^⊖

[MLXZ]𝘲 class:

[ML₅Z₂]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

axial–[Mn(CO)₄(PEt₃)]⊖

Formula Unicode styled:

axial–[Mn(CO)₄(PEt₃)]⊖

Compound name(s):

tetracarbonyl-triethylphosphine-manganese(1-)

Central atom:

(CO)₄ (tetracarbonyl, (C≡O)₄ trigonal bipyramidal C3v Ⓢ)

Attached groups:

PEt₃ (triethylphosphane)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mn«V³C⁵O^-IE¹⁸B⁷X⁰L⁵Z²»^⊖

[MLXZ]𝘲 class:

[ML₅Z₂]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Hg(Cl)₅]³⊖

Formula Unicode styled:

[Hg(Cl)₅]³⊖

Compound name(s):

pentachloro-mercury(3-)

Central atom:

Mercury

Attached groups:

Cl (chloro)

Charge on central atom:

-3

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hg«V²C⁵O^IIE¹⁰B⁵Z⁰L⁰X⁵»^3⊖

[MLXZ]𝘲 class:

[MX₅]^3-

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Cd(I)₂(OH₂)₂(Thf)]

Formula Unicode styled:

[Cd(I)₂(OH₂)₂(Thf)]

Compound name(s):

Diaqua-di-iodo-(tetrahydrofuran)-cadmium

Central atom:

Cadmium

Attached groups:

I (iodo)

OH₂ (aqua)

Thf (tetrahydrofuran)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cd«V²C⁵O^IIE¹⁰B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Cd(Cl)₅]³⊖

Formula Unicode styled:

[Cd(Cl)₅]³⊖

Compound name(s):

pentachlorocadmium(3-)

Central atom:

Cadmium

Attached groups:

Cl (chloro)

Charge on central atom:

-3

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cd«V²C⁵O^IIE¹⁰B⁵Z⁰L⁰X⁵»^3⊖

[MLXZ]𝘲 class:

[MX₅]^3-

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Cd(NCS-κN)₂(Terpy-κ³N)]

Formula Unicode styled:

[Cd(NCS-κN)₂(Terpy-κ³N)]

Compound name(s):

bis(Isothiocyanato)-(2,2':6',2''-terpyridine)-cadmium

Central atom:

Cadmium

Attached groups:

NCS (isothiocyanato-κN)

Terpy (terpyridine-κ³N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cd«V²C⁵O^IIE¹⁰B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

catena–1D-[Hg(Br)₂(μ₃-Br)]⊖

Formula Unicode styled:

catena–1D-[Hg(Br)₂(μ₃-Br)]⊖

Compound name(s):

catena(tribromo-mercury(1-)

Central atom:

Mercury

Attached groups:

Br (μ₃-bromo)

Charge on central atom:

-1

Compound type:

Catena-1D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: