Osmium

Cod (η²,η²-cycloocta-1,5-diene)

Attached groups:

Cot (η⁶-cyclooctatetraene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Os(OMe)(η⁴-Cod)(Tp-κ³N)]

Formula Unicode styled:

[Os(OMe)(η⁴-Cod)(Tp-κ³N)]

Compound name(s):

(η-1,5-Cyclo-octadienyl)-(hydrogen tris(pyrazolyl)borate)-methoxy-osmium

Central atom:

Cod (η²,η²-cycloocta-1,5-diene)

Attached groups:

OMe (methoxy)

Tp (hydrotris(pyrazolyl)borato-κ³N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Os(Cl)(=C=C=CPh₂)(PMe₃)(η⁶-C₆H₃Me₃)]²⊕

Formula Unicode styled:

[Os(Cl)(=C=C=CPh₂)(PMe₃)(η⁶-C₆H₃Me₃)]²⊕

Compound name(s):

(η-1,3,5-Trimethylbenzene)-(3,3-diphenylallenylidene)-chloro-(trimethylphosphine)-osmium(2+)

Central atom:

=C=C=CPh₂ (diphenylallenylidene)

Attached groups:

Cl (chloro)

PMe₃ (trimethylphosphane)

C₆H₃Me₃ (mesitylene)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Os«V⁵C⁶O^VE¹⁷B⁷Z⁰X³L⁴»^2⊕

[MLXZ]𝘲 class:

[MX₃L₄]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Os(CO)₂(PPh₃)(PhC≡CPh)]

Formula Unicode styled:

[Os(CO)₂(PPh₃)(PhC≡CPh)]

Compound name(s):

(η-1,2-Diphenylacetylene)-dicarbonyl-bis(triphenylphosphine)-osmium

Central atom:

PPh₃ (triphenylphosphane)

Attached groups:

CO (carbonyl)

PhC≡CPh (diphenylethyne L₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁰C⁴O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Os(Me₃CC≡CCMe₃)(PMe₃)₃]

Formula Unicode styled:

[Os(Me₃CC≡CCMe₃)(PMe₃)₃]

Compound name(s):

(η-1,2-Di-t-butylethyne)-tris(trimethylphosphine)-osmium

Central atom:

Me₃CC≡CCMe₃ (di-t-butyl-ethyne L₂)

Attached groups:

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁰C⁴O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

trans–[Os(=CPh₂)(Py)(Ttp)]

Formula Unicode styled:

trans–[Os(=CPh₂)(Py)(Ttp)]

Compound name(s):

(diphenylcarbene)-(pyridine)-(5,10,15,20-tetra-p-tolylporphyrinato)-osmium

Central atom:

=CPh₂ (diphenylmethylidene)

Attached groups:

Py (pyridine)

Ttp (tetratolylporphyrin)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁴C⁶O^IVE¹⁸B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Os(Ph)₂(N)(Tp-κ³N)]

Formula Unicode styled:

[Os(Ph)₂(N)(Tp-κ³N)]

Compound name(s):

Diphenyl-nitrido-(hydrogen tris(pyrazolyl)borate-N,N',N'')-osmium

Central atom:

Tp (hydrotris(pyrazolyl)borato-κ³N)

Attached groups:

Ph (phenyl)

N (nitrido; ≡N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

trans–[Os(OPh)₂(Tpp)]

Formula Unicode styled:

trans–[Os(OPh)₂(Tpp)]

Compound name(s):

Diphenoxy-(meso-tetraphenylporphyrinato-N,N',N'',N''')-osmium

Central atom:

Tpp (tetraphenylporphyrin)

Attached groups:

OPh (phenoxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Os«V⁴C⁶O^IVE¹⁶B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

trans–[Os(O)₂(PzH)₄]²⊕

Formula Unicode styled:

trans–[Os(O)₂(PzH)₄]²⊕

Compound name(s):

Dioxo-tetrakis(pyrazole-N)-osmium(2+_

Central atom:

Attached groups:

PzH (pyrazole)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰X⁴L⁴»^2⊕

[MLXZ]𝘲 class:

[MX₄L₄]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

trans–[Os(O)₂(PPrⁱ₃)₂]

Formula Unicode styled:

trans–[Os(O)₂(PPrⁱ₃)₂]

Compound name(s):

Dioxo-bis(tri-isopropylphosphine)-osmium

Central atom:

Attached groups:

PPrⁱ₃ (triisopropylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Os«V⁴C⁴O^IVE¹⁶B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

trans–[Os(C₆F₅)₂(O)₂(Py)₂]

Formula Unicode styled:

trans–[Os(C₆F₅)₂(O)₂(Py)₂]

Compound name(s):

Dioxo-bis(pentafluorophenyl)-dipyridyl-osmium

Central atom:

Attached groups:

C₆F₅ (pentafluorophenyl)

Py (pyridine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

trans–[Os(O)₂(Ox)₂]²⊖

Formula Unicode styled:

trans–[Os(O)₂(Ox)₂]²⊖

Compound name(s):

dioxo-bis(oxalato)-osmium(2-)

Central atom:

Attached groups:

Ox (oxalato)

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰L⁰X⁸»^2⊖

[MLXZ]𝘲 class:

[MX₈]^2-

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

trans–[Os(O)₂(En)₂]²⊕

Formula Unicode styled:

trans–[Os(O)₂(En)₂]²⊕

Compound name(s):

Dioxo-bis(ethylenediamine) osmium(2+)

Central atom:

Attached groups:

En (ethylenediamine)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰X⁴L⁴»^2⊕

[MLXZ]𝘲 class:

[MX₄L₄]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

trans–[Os(O)₂(Ttp)]

Formula Unicode styled:

trans–[Os(O)₂(Ttp)]

Compound name(s):

Dioxo-(meso-tetra-p-tolylporphyrin)-osmium

Central atom:

Attached groups:

Ttp (tetratolylporphyrin)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Os(NO)₂(PPh₃)₂]

Formula Unicode styled:

[Os(NO)₂(PPh₃)₂]

Compound name(s):

Dinitrosyl-bis(triphenylphosphine) osmium

Central atom:

(NO)₂ (dinitrosyl, (N≡O)₂ tetrahedral Ⓢ)

Attached groups:

PPh₃ (triphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (-II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁴O^-IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

cis–[Os(Me)₂(CH₂Buᵗ)₂(O)]

Formula Unicode styled:

cis–[Os(Me)₂(CH₂Buᵗ)₂(O)]

Compound name(s):

Dimethyl-dineopentyl-oxo-osmium

Central atom:

Attached groups:

Me (methyl)

CH₂Buᵗ (t-butylmethyl)

O (oxo ⭀O X₂L)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Os«V⁶C⁵O^VIE¹⁶B⁷Z⁰X⁶L¹»

[MLXZ]𝘲 class:

[MX₆L₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[Os(Mes)₂(O)₂]

Formula Unicode styled:

[Os(Mes)₂(O)₂]

Compound name(s):

Dimesityl-dioxo-osmium

Central atom:

Attached groups:

Mes (mesityl)

(O)₂ (dioxo C₂ᵥ X₄L₂ Ⓢ)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁴O^VIE¹⁸B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Os(Mes)₂(O)₂(TMEDA-κ²N)]

Formula Unicode styled:

[Os(Mes)₂(O)₂(TMEDA-κ²N)]

Compound name(s):

Dimesityl-dioxo-(tetramethylethylenediamine)-osmium

Central atom:

Attached groups:

Mes (mesityl)

TMEDA (tetramethylethylenediamine-κ²N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Os(Mes)₂(O)₂(Phen)]

Formula Unicode styled:

[Os(Mes)₂(O)₂(Phen)]

Compound name(s):

Dimesityl-dioxo-(phenanthrene)-osmium

Central atom:

Attached groups:

Mes (mesityl)

Phen (phenanthroline)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Os(H)₂(η²-H₂)(AsPh₃)(Cp*)]⊕

Formula Unicode styled:

[Os(H)₂(η²-H₂)(AsPh₃)(Cp*)]⊕

Compound name(s):

(Dihydrogen)-cis-dihydrido-(η-pentamethylcyclopentadienyl)-(triphenylarsine)-osmium(1+)

Central atom:

Cp* (η⁵-pentamethylcyclopentadienyl)

Attached groups:

H (hydrido)

H₂ (η²-dihydrogen)

AsPh₃ (triphenylarsane)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 7

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: