cis,trans–[W₂(Cl)₄(Dme)₂(PhC≡CPh)₂(N₂)]

Formula Unicode styled:

Compound name(s):

(μ₂-dinitrogen)-bis(dichloro-(1,2-dimethoxyethane-O,O')-(η²-diphenylacetylene)-tungsten)

Central atom:

Tungsten

Charge on formula unit (QN):

Attached groups:

Cl (chloro)

Dme (dimethoxyethane)

PhC≡CPh (diphenylethyne)

N₂ (dinitrogen)

Compound type:

Molecular

DOI link to literature report:

10.1021/ic00194a015

Crystal data CSD link:

cutjac

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Coordination Number (CN, sum of attached group denticities):

CN: 6

Oxidation Number (ON) (Roman numerals):

ON: (II)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

Summary of calculated classifications:

W«V²C⁶O^IIE¹⁶B⁶Z⁰X²L⁴»

Geometry:

6-coordinate: octahedron (OC-6)

Isomer label:

cis,trans

𝘥-electron configuration = 𝘮 – VN:

d⁴

𝘥-electron configuration = 𝘮 – ON:

d⁴

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d⁴

Attached atoms:

Phase:

Solid

InChIKey (see www.inchi-trust.org):

JNZZDNKYGLRPHP-UHFFFAOYSA-J