cis,cis,trans–[Pt(Br)(H)(C₆H₄-C₆H₄)(PEt₃)]

Formula Unicode styled:

Compound name(s):

(2,2'-Biphenyl)-bromo-hydrido-bis(triethylphosphine)-platinum

Central atom:

Platinum

Charge on formula unit (QN):

Attached groups:

Br (bromo)

H (hydrido)

C₆H₄-C₆H₄ (biphenyl-κC²)

PEt₃ (triethylphosphane)

Compound type:

Molecular

DOI link to literature report:

10.1021/ja973368d

Crystal data CSD link:

sipqud

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Coordination Number (CN, sum of attached group denticities):

CN: 5

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₄L₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₁

Summary of calculated classifications:

Pt«V⁴C⁵O^IVE¹⁶B⁵Z⁰X⁴L¹»

Geometry:

6-coordinate: octahedron (OC-6)

Isomer label:

cis,cis,trans

𝘥-electron configuration = 𝘮 – VN:

d⁶

𝘥-electron configuration = 𝘮 – ON:

d⁶

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d⁶

Attached atoms:

C₂H₁Br₁P₁

Phase:

Solid

InChIKey (see www.inchi-trust.org):

ZYXHKBAMYLHKFP-UHFFFAOYSA-M