MolBase

Compound: cis-[IrCl(CO)(PMePh2)2]

Owner Referee Record added Record modified CAS Registry MolBase ID MolBase status
Sarah Spinks Mark Winter 24 Feb 2004 17:38 24 Feb 2004 17:38 764 Accepted

Compound formula

Central atom Formula Structural formula Isomer label Charge Formula weight Specific rotation label Absolute rotation label
iridium (Ir) C27Cl1H26Ir1O1P2 cis-[IrCl(CO)(PMePh2)2] cis 0 656.112

Classification for Ir

This compound is regarded as a discrete molecular species.

Oxidation number MLXZ class Coordination number (CN) Donor set Total valence electron count VE configuration Magnetism Block
1 ML3X1 4 C1Cl1P2 16 d8 diamagnetic d

Contributed properties

Geometry about Ir Point group Spin (only applies to some compounds of some d-block elements)Distortion type Physical state Colour Melting point
unknown (4) Unknown not given

Notes

No notes yet entered.

Key references

  1. Henderson, R.A. in The mechanisms of reactions at transition metal chemistry, (1993), Oxford University Press, page 66.

3D structure




Synthesis

No synthesis notes yet entered.

Reactions

No reactions yet entered.

Other calculated properties

Element percentages

    C     49.43%
   Cl      5.40%
    H      3.99%
   Ir     29.30%
    O      2.44%
    P      9.44%

Isotope pattern

     654   48.91  ________________________
     655   14.45  _______
     656  100.00  __________________________________________________
     657   29.12  _______________
     658   30.61  _______________
     659    8.20  ____
     660    1.19  _
     661    0.12  
     662    0.01  
     663    0.00  
     664    0.00  
     665    0.00  
     666    0.00