MolBase

Compound: trans-[IrCl(CO)(PPh3)2]

Owner Referee Record added Record modified CAS Registry MolBase ID MolBase status
Zoe Bellamy Lee Brammer 18 Feb 2004 14:41 18 Feb 2004 14:42 75 Accepted

Compound formula

Central atom Formula Structural formula Isomer label Charge Formula weight Specific rotation label Absolute rotation label
iridium (Ir) C37Cl1H30Ir1O1P2 trans-[IrCl(CO)(PPh3)2] trans 0 780.251

Classification for Ir

This compound is regarded as a discrete molecular species.

Oxidation number MLXZ class Coordination number (CN) Donor set Total valence electron count VE configuration Magnetism Block
1 ML3X1 4 C1Cl1P2 16 d8 diamagnetic d

Contributed properties

Geometry about Ir Point group Spin (only applies to some compounds of some d-block elements)Distortion type Physical state Colour Melting point
square planar (4) Unknown not given

Notes

No notes yet entered.

Key references

  1. Housecroft, C.E.; Sharpe, A.G. in Inorganic Chemistry, (2001), Prentice Hall, page 606.

3D structure




Synthesis

No synthesis notes yet entered.

Reactions

No reactions yet entered.

Other calculated properties

Element percentages

    C     56.96%
   Cl      4.54%
    H      3.88%
   Ir     24.64%
    O      2.05%
    P      7.94%

Isotope pattern

     778   48.03  ________________________
     779   19.41  __________
     780  100.00  __________________________________________________
     781   39.35  ____________________
     782   33.69  _________________
     783   11.48  ______
     784    2.21  _
     785    0.29  
     786    0.03  
     787    0.00  
     788    0.00  
     789    0.00  
     790    0.00