MolBase

Compound: [VCl3(NMe3)2]

Owner Referee Record added Record modified CAS Registry MolBase ID MolBase status
Lauren Povey Mike Ward 19 Feb 2004 12:12 19 Feb 2004 12:14 353 Accepted

Compound formula

Central atom Formula Structural formula Isomer label Charge Formula weight Specific rotation label Absolute rotation label
vanadium (V) C6Cl3H18N2V1 [VCl3(NMe3)2] 0 275.521

Classification for V

This compound is regarded as a discrete molecular species.

Oxidation number MLXZ class Coordination number (CN) Donor set Total valence electron count VE configuration Magnetism Block
3 ML2X3 5 Cl3N2 12 d2 diamagnetic d

Contributed properties

Geometry about V Point group Spin (only applies to some compounds of some d-block elements)Distortion type Physical state Colour Melting point
trigonal bipyramidal (5) Unknown not given

Notes

Neutral compound. Trigonal bipyramidal structure with the two trimethylamine ligands occupying the axial positions.

Key references

  1. Greenwood, N.N.; Earnshaw, A. in Chemistry of the Elements, (1984), Pergamon, page 1162 (1st edition).

3D structure




Synthesis

No synthesis notes yet entered.

Reactions

No reactions yet entered.

Other calculated properties

Element percentages

    C     26.16%
   Cl     38.60%
    H      6.58%
    N     10.17%
    V     18.49%

Isotope pattern

     273    0.25  
     274  100.00  __________________________________________________
     275    7.67  ____
     276   96.12  ________________________________________________
     277    7.21  ____
     278   30.88  _______________
     279    2.29  _
     280    3.34  __
     281    0.24  
     282    0.01  
     283    0.00