MolBase

Compound: [WF4S]

Owner Referee Record added Record modified CAS Registry MolBase ID MolBase status
Sarah Spinks Mark Winter 24 Nov 2004 17:44 24 Nov 2004 17:48 [41831-80-5] 1261 Submitted

Tungsten fluoride sulfide

Compound formula

Central atom Formula Structural formula Isomer label Charge Formula weight Specific rotation label Absolute rotation label
tungsten (W) F4S1W1 [WF4S] 0 291.899

Classification for W

This compound is regarded as a discrete molecular species.

Oxidation number MLXZ class Coordination number (CN) Donor set Total valence electron count VE configuration Magnetism Block
6 MX6 5 F4S1 12 d0 diamagnetic d

Contributed properties

Geometry about W Point group Spin (only applies to some compounds of some d-block elements)Distortion type Physical state Colour Melting point
trigonal bipyramidal (5) C4v Yellow/cream 89-90 °C

Notes

Mass 291.9

Key references

  1. Dictionary of Inorganic Compounds ID: IC- 018463

3D structure




Synthesis

Prepared from WF6 + Sb2S3, B2S3 or S

Reactions

No reactions yet entered.

Other calculated properties

Element percentages

    F     26.03%
    S     10.98%
    W     62.98%

Isotope pattern

     288    0.38  
     289    0.00  
     290   82.95  _________________________________________
     291   45.45  _______________________
     292  100.00  __________________________________________________
     293    2.79  _
     294   93.33  _______________________________________________
     295    0.72  
     296    4.04  __
     297    0.00  
     298    0.02