MolBase

Compound: [WCl3O]

Owner Referee Record added Record modified CAS Registry MolBase ID MolBase status
Kin Man Au Mike Morris 16 Nov 2004 19:11 16 Nov 2004 19:16 [14249-98-0] 1017 Accepted

Tungsten(V) chloride oxide

Compound formula

Central atom Formula Structural formula Isomer label Charge Formula weight Specific rotation label Absolute rotation label
tungsten (W) Cl3O1W1 [WCl3O] 0 306.198

Classification for W

This compound is regarded as an extended lattice so some entries in the next table are not computed.

Oxidation number MLXZ class Coordination number (CN) Donor set Total valence electron count VE configuration Magnetism Block
5 d1 d

Contributed properties

Geometry about W Point group Spin (only applies to some compounds of some d-block elements)Distortion type Physical state Colour Melting point
octahedral (6) solid Green not given

Notes

Structure stacked dimers - 6 coordinate W

Key references

  1. Dictionary of Inorganic Compounds ID: IC-016934

3D structure




Synthesis

Route 1: WOCl4 + Al at 100C Route 2: WCl5 + Sb2O3 Route 3: WOCl4 + C6H6 Route 4: W + WO3 + WCl6 Route 5: WO3 + WCl5 Route 5: WOCl4 + Cl2C=CCl2

Reactions

No reactions yet entered.

Other calculated properties

Element percentages

   Cl     34.74%
    O      5.23%
    W     60.04%

Isotope pattern

     301    0.18  
     302    0.00  
     303   40.29  ____________________
     304   21.68  ___________
     305   85.00  ___________________________________________
     306   20.85  __________
     307  100.00  __________________________________________________
     308    6.72  ___
     309   57.00  _____________________________
     310    0.74  
     311   14.82  _______
     312    0.01  
     313    1.44  _
     314    0.00  
     315    0.00